scholarly journals Effect of Mechanical Milling on the Magnetic Properties of SrFe12O19

2015 ◽  
Vol 12 (1) ◽  
pp. 28-30
Author(s):  
I Bsoul
Keyword(s):  
Particle Size ◽  
Magnetic Properties ◽  
Crystallite Size ◽  
Mechanical Milling ◽  
Single Phase ◽  
Strontium Ferrite ◽  
Single Domain ◽  
Single Domain Particle ◽  
Ferrite Sample

In this work, a single phase strontium ferrite sample was mechanically milled for 60 h. It has been found that the crystallite size reduced by 85%. A dramatic drop (from 4500 to 1600 Oe) in the coercive filed was also observed. The observed reduction in the coercivity was attributed to the reduction of the single domain particle size.

Properties of Nanosized Ferrite Powders and Sintered Materials Prepared by the Co-Precipitation Technology, Combined with the Spray-Drying Method

2016 ◽  
Vol 721 ◽  
pp. 295-299 ◽  
Author(s):  
Ilmārs Zālīte ◽  
Gundega Heidemane ◽  
Eriks Palcevskis ◽  
Mikhail Maiorov
Keyword(s):  
Particle Size ◽  
Magnetic Properties ◽  
Crystallite Size ◽  
Spray Drying ◽  
Single Phase ◽  
Drying Method ◽  
Co Precipitation ◽  
Sintering Method ◽  
Sintered Materials ◽  
Cobalt And Nickel

Cobalt and nickel ferrites powders are synthesized by the co-precipitation technology, combined with the spray-drying method. The crystallite size, specific surface area (SSA), magnetic properties of synthesized products are investigated. All the synthesized ferrites are nanocrystalline single phase materials with crystallite size of 5-6 nm, the SSA of 80-85 m2/g and the calculated particle size of 13-15 nm. After spray-drying granules of the size up to 10 μm are obtained. After thermal treatment at 550 and 950 °C SSA decreases to 40-50 m2/g and 20-22 m2/g, respectively. The saturation magnetization at these temperatures increase from 17 to 40 emu/g for NiFe2O4 and from 51 to 77 emu/g for CoFe2O4. By the pressure-less sintering method the dense material forms at 1100 °C for CoFe2O4 and 1200-1300 °C for NiFe2O4.

scholarly journals Magnetic properties of SrFe12-xAlxO19

2015 ◽  
Vol 12 (1) ◽  
pp. 08-14 ◽  
Author(s):  
I Bsoul ◽  
W. I Da'as
Keyword(s):  
Magnetic Properties ◽  
Crystallite Size ◽  
Lattice Constant ◽  
Hexagonal Lattice ◽  
Anisotropy Field ◽  
Solid State Reaction Method ◽  
Strontium Ferrite ◽  
Strontium Hexaferrite ◽  
Magnetic Data ◽  
Standard Pattern

In this work, pure and doped with Al (Aluminum) strontium hexaferrite (SrFe12-xAlxO19) were fabricated by solid state reaction method. The Al concentration (x) for the fabricated samples was varied from x=0.0 to x=0.6. Structural and magnetic properties of the fabricated samples were investigated. Analyses of XRD data showed that all samples of high quality, since the measured XRD patterns found to match the standard pattern for single phase of SrFe12O19. The lattice constants a and c were calculated. It was found that the replacement of Fe3+ with Al3+ ions in hexagonal strontium ferrite led to a negligible changes in lattice constant a, whereas the hexagonal lattice constant c found to decrease with increasing the substitution amount of Al. The crystallite size was also determined using the XRD data. It has been found that that Al3+ substitution for Fe3+ does not appreciably disturb the crystallinity of SrFe12-xAlxO19, since the crystallite size for all samples ranged from 83 – 72 nm. The magnetic data showed that doping of strontium with Al leads to a small decrease in saturation magnetization. Also it has been found that the doping of strontium ferrite with Al leads to an increase in the coercivity as a result of increasing of the anisotropy field.

scholarly journals Eco-Friendly Synthesis, TEM and Magnetic Properties of Co-Er Nano-Ferrites

2021 ◽  
Vol 12 (1) ◽  
pp. 910-928
Keyword(s):  
Particle Size ◽  
Magnetic Properties ◽  
Crystallite Size ◽  
Rietveld Analysis ◽  
Sem Analysis ◽  
Tem Analysis ◽  
Edax Analysis ◽  
Cobalt Ferrites ◽  
Auto Combustion ◽  
Structural And Magnetic Properties

Synthesis of Cobalt-Erbium nano-ferrites with formulation CoErxFe2-xO4 (x = 0, 0.005, 0.010, 0.015, 0.020, 0.025, and 0.030) using technique of citrate-gel auto-combustion was done. Characterization of prepared powders was done using XRD, EDAX, FESEM, TEM, AFM, and FTIR spectroscopy, VSM: magnetic properties, respectively. XRD Rietveld Analysis, SEM, TEM, and EDAX analysis studied spectral, structural, and magnetic properties. XRD pattern of CEF nanoparticles confirms single-phase cubic spinal structure. The structural variables are given by lattice constant (a), lattice volume (v), the average crystallite size (D) and X-ray density (dx), bulk density (d), porosity (p), percentage of pore space (P%), surface area (s), strain(ε), dislocation density (δ), along with ionic radii, bond length and hoping length were calculated. SEM and TEM results reveal the homogeneous nature of particles accompanied by clusters having no impurity pickup. TEM analysis gives information about the particle size of nanocrystalline ferrite, while EDAX analysis confirms elemental composition. The emergence of two arch-shaped frequency bands (ν_1 and〖 ν〗_2) that represent vibrations at the tetrahedral site (A) and octahedral site(B) was indicated by spectra of FTIR. The XRD Rietveld analysis confirms crystallite size lying between 20.84 nm-14.40 nm, while SEM analysis indicates the formation of agglomerates and TEM analysis indicates particle size ranging between 24nm-16 nm. The XRD Rietveld analysis confirms crystallite size lying between 20.84nm-14.40nm, while SEM analysis indicates the formation of agglomerates and TEM analysis indicates particle size ranging between 24 nm - 16 nm. The magnetization measurements indicated that increasing Er3+ content in cobalt ferrites decreases magnetization from 60emu/g to 42emu/g while coercivity decreases (18990) as compared to CoFe2O4 (18998) in cobalt ferrites with doping. The present study investigates the effect of different compositions of Er3+ replaced for Fe on structural and magnetic properties of cobalt ferrites.

Karakterisasi Struktur Kristal dan Sifat Magnetik Magnet Stronsium Ferit Pasir Besi Batang Sukam Kabupaten Sijunjung Sumatera Barat

2017 ◽  
Vol 1 ◽  
pp. 38
Author(s):  
Arif Budiman ◽  
Dwi Puryanti ◽  
Sri Mulyadi Dt. Basa ◽  
Muhammad Rizki ◽  
Helfi Syukriani
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Single Phase ◽  
Oxidation Process ◽  
Strontium Ferrite ◽  
X Ray Diffraction ◽  
Hexagonal Crystal ◽  
X Ray

<p><strong>Abstract:</strong> The synthesis and characterization of the crystal structure and magnetic properties of strontium ferrite magnets (SrO.6Fe<sub>2</sub>O<sub>3</sub>) has been done. Hematite (Fe<sub>2</sub>O<sub>3</sub>) is synthesized from iron sand of Batang Sukam Sijunjung Sumatera Barat through the oxidation process by temperature 700ºC for 3.0 hours. Strontium carbonate (SrCO<sub>3</sub>) was obtained from Merck product with a purity of more than 99%. Synthesis of strontium ferrite magnets are made through a process of solid-solid mixing and sintering at a temperature of 1000ºC for 3.0 hours. The results of characterization of X-ray diffraction indicates that it has formed a single phase strontium ferrite magnets with a hexagonal crystal structure. The result of measurement of the magnetic properties shows that an average magnetic susceptibility of strontium ferrite magnet is 266.7 × 10<sup>-8 </sup>m<sup>3</sup> /kg.</p><p> </p><p><strong>Keywords</strong>: strontium ferrite magnet, iron sand, crystal structure and magnetic susceptibility.</p><p><strong> </strong></p><p><strong>Abstrak:</strong> Telah dilakukan sintesis dan karakterisasi struktur kristal dan sifat magnetik magnet stronsium ferit (SrO.6Fe<sub>2</sub>O<sub>3</sub>). Hematit (Fe<sub>2</sub>O<sub>3</sub>) disintesis daripasir besi Batang Sukam Kabupaten Sijunjung Sumatera Barat melalui proses oksidasi dengan temperatur 700ºC selama 3,0 jam. Stronsium karbonat (SrCO<sub>3</sub>) diperoleh dari produk Merck dengan kemurnian lebih dari 99 %. Sintesis magnet stronsium ferit dibuat melalui proses <em>solid-solid mixing</em> dan disintering pada suhu 1000ºC selama 3,0 jam. Hasil karakterisasi difraksi sinar-X menunjukkan bahwa telah terbentuk <em>single phase</em> magnet stronsium ferit dengan struktur kristal heksagonal. Hasil pengukuran sifat magnet menunjukkan bahwa magnet stronsium ferit memiliki suseptibilitas magnetik rata-rata 266,7 × 10<sup>-8</sup> m<sup>3</sup>/kg.</p><p> </p><p><strong>Kata Kunci:</strong> magnet stronsium ferit, pasir besi, struktur kristal dan suseptibilitas magnetik.</p>

Squareness of NdFeB Stoner-Wohlfarth Hysteresis

2014 ◽  
Vol 802 ◽  
pp. 601-606
Author(s):  
Marcos Flavio de Campos ◽  
Fernanda A.S. da Silva ◽  
José Adilson de Castro
Keyword(s):  
Particle Size ◽  
General Result ◽  
Anisotropy Constant ◽  
Single Domain ◽  
Single Domain Particle ◽  
Hysteresis Curves ◽  
Intrinsic Coercivity ◽  
Grain Diameter

Hysteresis curves were calculated according the Stoner-Wohlfarth (SW) model using values of K2/K1from zero up to 0.25 (where K2is the 2ndorder anisotropy constant and where K1is the 1storder anisotropy constant). The SW calculations assume Nd2Fe14B nanocrystalline magnets with single domain particle size (grain diameter less than 150 nm). The effect of K2on several index of merit of magnets as BHmaxand squareness are discussed. As a general result, increasing K2, the intrinsic coercivity increases. However, the increase of K2almost does not improve the BHmaxof isotropic magnets. It is found that the effect of the K2/K1ratio is coupled with the effect of texture, i.e., the effect of K2is more significant for pronounced texture.

Application of Micromagnetic Models for Barium Ferrite Magnets

2015 ◽  
Vol 820 ◽  
pp. 199-204 ◽  
Author(s):  
Marcos Flavio de Campos ◽  
Fernanda A. Sampaio da Silva
Keyword(s):  
Particle Size ◽  
Grain Size ◽  
Coercive Force ◽  
Total Energy ◽  
Barium Ferrite ◽  
Magnetocrystalline Anisotropy ◽  
Single Domain ◽  
Square Root ◽  
Single Domain Particle ◽  
Magnetostatic Energy

The applicability of micromagnetics for phases with high magnetocrystalline anisotropy as barium ferrite Ba2Fe12O19and Nd2Fe14B is discussed. The Stoner-Wohlfarth model is very suitable for such phases, and also for PtFe and PtCo. It was discussed how to take into account the total energy of the system for grain size above the single domain particle size. For this situation of large grain size, the net magnetostatic energy of the system cannot be neglected. From energy considerations, it follows that the coercive force should decrease with the inverse of the square root of the grain size.

Microstructural and Magnetic Properties of Ti2+-Mn4+ Substituted Barium Hexaferrite

2014 ◽  
Vol 896 ◽  
pp. 401-405 ◽  
Author(s):  
Maykel Manawan ◽  
Azwar Manaf ◽  
Bambang Soegijono ◽  
Asep Yudi
Keyword(s):  
Magnetic Properties ◽  
Crystallite Size ◽  
Single Phase ◽  
Barium Hexaferrite ◽  
X Ray Diffraction ◽  
Mechanically Alloyed ◽  
Microstructure Observation ◽  
Diffraction Patterns ◽  
Substituted Barium Hexaferrite ◽  
Microstructure And Magnetic Properties

In this paper we report the microstructure and magnetic properties of Ti4+-Mn4+ ions substitued barium hexaferrites (BHF) with formula of BaFe12-2xMnxTixO19 (x = 0.2, 0.4, 0.6 and 0.8) which prepared by mechanical alloying and successive sintering at 1100 °C. Ti4+-Mn4+ ions were obtained from TiO2 and MnO precursors which were mechanically alloyed together with BaCO3 and Fe2O3 precursors. X-ray diffraction patterns for sintered samples confirmed that the materials are consisted with single phase BHF structure. Unit cell volume and crystallite size was found increase with increasing x. The crystallite size for all samples was below 70 nm, but microstructure observation shown that the particle size is in range of 200 - 400 nm, which concluded that the grains are polycrystalline. The saturation magnetization is increases up to x = 0.4 and decrease for higher x values, while the coercivity remain decreases monotonically. These results were interpreted in terms of the site preferential occupation of Ti2+ and Mn4+ at low level substitution.

Hysteresis Modeling of NdFeB Magnets with High Nd

2016 ◽  
Vol 869 ◽  
pp. 585-590 ◽  
Author(s):  
Marcos Flavio de Campos ◽  
Fernanda A. Sampaio da Silva ◽  
José Adilson de Castro
Keyword(s):  
Particle Size ◽  
Grain Size ◽  
Grain Boundaries ◽  
Paramagnetic Phase ◽  
Single Domain ◽  
Hysteresis Model ◽  
Ndfeb Magnets ◽  
Single Domain Particle ◽  
Hysteresis Curves ◽  
Hysteresis Modeling

The Stoner-Wohlfarth hysteresis model can describe very well the hysteresis curves since the assumptions of the model are compatible with the studied samples. These conditions are (i) single domain particle size and (ii) inexistence of interactions between the particles. These conditions are obtained in Nd2Fe14B magnets with nanocrystalline grain size below 200 nm and with high Nd, which promotes a paramagnetic phase at the grain boundaries. In the present study, both isotropic and anisotropic NdFeB magnets are modeled.

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