scholarly journals INVESTIGATING DISSOLVED AIR FLOTATION FACTORS FOR OIL REFINERY WASTEWATER TREATMENT

2018 ◽  
Vol 6 ◽  
pp. 1173-1177
Author(s):  
Emmanuel Kweinor Tetteh ◽  
Sudesh Rathilal

The global demand for petrochemical and petroleum industry products unavoidably generates large volumes of oil refinery wastewater (ORW). The complete treatment, reclamation and disposal of the ORW to an acceptable environmental limit is currently a challenge to most of the petroleum industries. With the current development in conventional treatment methods viz. coagulation, dissolved air flotation (DAF), and biological and membrane separation processes. DAF, which is well-established separation process, effectively employs microbubbles as a carrier phase for separation. Although, DAF is frequently used in combined water and wastewater treatment plants, its fundamental characteristics and operational parameters have not yet been fully investigated for the treatment of ORW. In this study, the correlation and effects of the parameters understudy (coagulant dosage, air saturator pressure, air-water ratio and rising rate) on chemical oxygen demand, soap oil and grease, turbidity and total suspended solids removal from ORW were examined experimentally using a laboratory DAF system. The results showed that increasing the saturator working pressure and the rising rate had less effect on the system, than increasing the air-water ratio. The agglomeration of the oil droplets was found to depend solely on the polyaluminum sulphate (PAS) dosage to destabilize the oil droplets. The DAF treatability performance showed over 80% removal of the contaminants at optimum conditions of pH of 5, PAS dosage of 10 mg/L, rising rate of 15 minutes, air saturator pressure of 300-500 kPa, and air-water ratio of 5-15%. The PAS dosage was found to be the most significant factor. Therefore, a moderate increase of the PAS dosage under these optimum conditions will increase the DAF efficiency in the treatment of ORW.

1986 ◽  
Vol 18 (9) ◽  
pp. 105-114 ◽  
Author(s):  
D. Misković ◽  
B. Dalmacija ◽  
Ž Živanov ◽  
E. Karlović ◽  
Z. Hain ◽  
...  

The objective of the present investigation was a high level of purification of the wastewater from an oil refinery achieved by using some improved methods yielding an effluent suitable for recycling into the process. All the investigations were carried out on a continuous laboratory pilot system consisting of the following units: dissolved air flotation (DAF), sedimentation, double-stage microbiological reactor, and adsorption columns filled with granular biologically activated carbon (GBAC). A high degree of COD reduction close to 100% (precisely, 99.95 %), as well as removal of nitrogen compounds of 72% was achieved during a relatively short retention time within the range of 15-16.5 hrs. The DAF technique combined with gravitational separation was used to achieve the recovery of free oil matter up to 98%, without any preliminary conditioning. After the sedimentation of coagulated and flocculated dispersed oils, the microbiological oxidation of dissolved matter was accomplished by using two kinds of activated sludge for easy and hard degradable organics. Using the continuously bioregenerating GBAC, an effluent having a lowered COD value to about 9 was obtained. At the same time, the denitrification process took place. According to the obtained results the treated oil refinery wastewater can be recycled into the process, or discharged into a water recipient of a low self-purifying capacity.


Processes ◽  
2020 ◽  
Vol 8 (4) ◽  
pp. 383 ◽  
Author(s):  
Emmanuel Kweinor Tetteh ◽  
Sudesh Rathilal

The effects of coagulation-dissolved air flotation (DAF) process configuration was studied on oil refinery wastewater. The configuration was done in two ways: acid-coagulation-DAF (pre-treatment) and acid-DAF-coagulation (post-treatment). Two different cationic and polymeric organic coagulants were employed in this study to compare their treatability performance with the two aforementioned configurations. All the coagulants applied before the DAF were found to be effective, with over 85% more contaminant removal efficiency than their post-treatment. Alum, being the most cost-effective coagulant, was then employed with response surface methodology (RSM) to obtain the optimum conditions. These include a coagulant dosage of 100 mg/L, air saturator pressure of 375 kPa and air–water ratio of 10% vol/vol corresponding to a desirability of 92% for the removal of oily pollutants from a local South Africa oil refinery’s wastewater. With the response quadratic models that were developed, the optimum conditions were tested experimentally, which were consistent with the models predicted results at a 95% confidence level.


2001 ◽  
Vol 43 (8) ◽  
pp. 83-90 ◽  
Author(s):  
A. C. Pinto Filho ◽  
C. C. Brandão

A bench scale study was carried out in order to evaluate the applicability of dissolved air flotation (DAF) as an advanced treatment for effluents from three different domestic wastewater treatment processes, namely: (i) a tertiary activated sludge plant ; (ii) an upflow sludge blanket anaerobic reactor (UASB); and (iii) a high-rate stabilization pond.


2012 ◽  
Vol 66 (8) ◽  
pp. 1684-1690 ◽  
Author(s):  
Russell Yap ◽  
Michael Holmes ◽  
William Peirson ◽  
Michael Whittaker ◽  
Richard Stuetz ◽  
...  

Dissolved air flotation (DAF) incorporating filtration (DAFF) is used at the Bolivar wastewater treatment plant (WWTP) to polish lagoon effluent for reuse. Elevated algal populations are frequently experienced and can lead to increased coagulant requirements and process control issues. Streaming current detectors (SCDs) and a charge demand analyser (CDA) were used to monitor the full-scale plant. This was followed by an optimisation study using a pilot plant with a CDA. It was found that the normal operational charge demand range for DAF at Bolivar was between −46 and −40 μeq L−1. Decreasing the pH of coagulation reduced coagulant consumption and facilitated more sensitive CDA responses to changes in alum dose.


2018 ◽  
Vol 78 (5) ◽  
pp. 1159-1167 ◽  
Author(s):  
Behnam Heidari ◽  
Mohsen Soleimani ◽  
Nourollah Mirghaffari

Abstract The Fenton process is a useful and inexpensive type of advanced oxidation process for industrial wastewater treatment. This study was performed with the aim of using the steel slag as a catalyst in the heterogeneous Fenton process in order to reduce the chemical oxygen demand (COD) of oil refinery wastewater. The effects of various parameters including the reaction time (0.5, 1.0, 2.0, 3.0 and 4.0 h), pH (2.0, 3.0, 4.0, 5.0, 6.0 and 7.0), the concentration of steel slag (12.5, 25.0 and 37.5 g/L), and H2O2 concentration (100, 250, 400 and 500 mg/L) on the Fenton process were investigated. Furthermore, the effect of microwave irradiation on the process efficiency was studied by considering the optimum conditions of the mentioned parameters. The results showed that using 25.0 g/L of steel slag and 250 mg/L H2O2, at pH = 3.0, could reduce COD by up to 64% after 2.0 h. Also, microwave irradiation decreased the time of the process from 120 min to 25 min in the optimum conditions, but it consumed a high amount of energy. It could be concluded that steel slags had a high potential in the treatment of oil refinery wastewater through the Fenton process.


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