scholarly journals ASSESSMENT OF TOXIC METALS IN SEDIMENTS OF MERIÇ, TUNCA AND ERGENE RIVERS BY USING BIOLOGICAL AND ECOLOGICAL RISK INDICES

2016 ◽  
Vol 4 ◽  
pp. 785-790
Author(s):  
Cem Tokatli ◽  
Yasin Baştatli

The Meriç River, the longest river of the Balkans, is the most important aquatic ecosystem within the Thrace Region of Turkey, along with its main tributaries, the Tunca and Ergene Rivers. In this study, the sediment quality of Meriç, Tunca, and Ergene Rivers was evaluated by using the Potential Ecological Risk Index (RI) and the Biological Risk Index (mERM-Q), both widely used methods in sediment quality assessment studies, to assess the ecological and biological risks of heavy metals within the river ecosystems. According to the results of the Biological Risk Index, nickel and chromium displayed the highest risk factors, and in terms of the Potential Ecological Risk Index, cadmium yielded the highest risk factor across all the investigated lotic ecosystems.

2017 ◽  
Vol 43 (1) ◽  
pp. 34-47 ◽  
Author(s):  
Cem Tokatli

Abstract Gala Lake National Park that has an international importance is one of the most important wetland ecosystems for Turkey. As same as many aquatic habitats, Gala Lake is under a significant anthropogenic pressure originated from agricultural activities conducted around the lake and from industrial discharges by means of Ergene River. The aim of this study was to evaluate the sediment quality of Gala Lake and Irrigation Canal by investigating some toxic element accumulations (As, B, Ni, Cr, Pb, Cd, Zn and Cu) from a statistical perspective. Pearson Correlation Index (PCI) and Factor Analysis (FA) were applied to detected data in order to determine the associated contaminants and effective factors on the system. Potential Ecological Risk Index (RI) and Biological Risk Index based sediment quality guidelines (mERM-Q) applied to detected data in order to assess the ecological and biological risks of heavy metals in the ecosystem. Also Geographic Information System (GIS) technology was used to make visual explanations by presenting distribution maps of investigated elements. According to the results of PCI, significant positive correlations were recorded among the investigated toxic elements at 0.01 significance level. According to the results of FA, two factors, which were named as “Agricultural Factor” and “Industrial Factor”, explained 86.6% of the total variance. According to the results of Potential Ecological Risk Index, cadmium was found to be the highest risk factor and according to results of Biological Risk Index, nickel and chromium were found to be the highest risk factors for Gala Lake and Irrigation Canal. As a result of the present study, it was also determined that heavy metal contents in sediments of Gala Lake National Park reached to critical levels and the system is intensively under effect of agricultural and industrial originated pollution.


2020 ◽  
Vol 29 (3) ◽  
pp. 289-297
Author(s):  
Eva Singovszka ◽  
Magdalena Balintova

Quality is one of the most important risk indicators in river basins. Therefore, monitoring and evaluating water and sediment quality has a very important role in process of risk management. The aim of the monitoring is provide for the sustainability of water bodies and these results are the basis for the risk management in the river catchment area. Hornad, Laborec and Poprad are the rivers in Eastern Slovakia. Hornad and Laborec belongs to basin of Danube and Poprad belongs to basin of Vistula. Sediment sampling was carried out according to ISO 5667-6. Monitoring was carried out in the spring on 2017–2018. The chemical composition of sediments was determined by means of X-ray fluorescence (XRF) using SPECTRO iQ II (Ametek, Germany, 2000). The results of sediment quality evaluated by method PERI revealed that the quality of sediment in 2018 was better than 2017. Results of XRF analysis of sediments were compared with the limited values according to the Slovak Act 188/2003 Coll. of Laws on the application of treated sludge and bottom sediments to fields. It can be state that limit values comparing with Slovak legislation were not exceeding in all sediment samples in rivers in Eastern Slovakia. Based on the monitoring data of sediment quality in the study area, a quantitative analysis of heavy-metal pollution in sediment was conducted using the method of potential ecological risk index (PERI) which is method for evaluate the potential ecological risk of heavy metals. It is based exclusively on chemical parameters of sediments because sediment data show mean integrated values in time, with higher stability than water column parameters; sediments are easily sampled at field work; sediment samples are more representative for time and space scales and analytical data are easily obtained, especially because sediments present high concentrations of contaminants, decreasing the possible errors due to detection limits of the applied analytical method. This method comprehensively considers the synergy, toxic level, concentration of the heavy metals and ecological sensitivity of heavy metals. Potential ecological risk index can be obtained using three basic modules: degree of contamination (CD), toxic-response factor (TR) and potential ecological risk factor (ER). The results show on the basis on potential ecological risk index that the quality of sediment in 2018 is better than 2017. The worst result shows Hornad in 2017. Significant improvement occurred at the sampling point S2 in Hornad in 2018. The best results show Laborec in 2018. The results show on the basis on potential ecological risk index that quality of sediment in 2018 is better than 2017.


Processes ◽  
2019 ◽  
Vol 8 (1) ◽  
pp. 29
Author(s):  
Saijun Zhou ◽  
Renjian Deng ◽  
Andrew Hursthouse

We evaluated the direct release to the environment of a number of potentially toxic elements (PTEs) from various processing nodes at Xikuangshan Antimony Mine in Hunan Province, China. Sampling wastewater, processing dust, and solid waste and characterizing PTE content (major elements Sb, As, Zn, and associated Hg, Pb, and Cd) from processing activities, we extrapolated findings to assess wider environmental significance using the pollution index and the potential ecological risk index. The Sb, As, and Zn in wastewater from the antimony benefication industry and a wider group of PTEs in the fine ore bin were significantly higher than their reference values. The content of Sb, As, and Zn in tailings were relatively high, with the average value being 2674, 1040, and 590 mg·kg−1, respectively. The content of PTEs in the surface soils surrounding the tailings was similar to that in tailings, and much higher than the background values. The results of the pollution index evaluation of the degree of pollution by PTEs showed that while dominated by Sb, some variation in order of significance was seen namely for: (1) The ore processing wastewater Sb > Pb > As > Zn > Hg > Cd, (2) in dust Sb > As > Cd > Pb > Hg > Zn, and (3) surface soil (near tailings) Sb > Hg > Cd > As > Zn > Pb. From the assessment of the potential ecological risk index, the levels were most significant at the three dust generation nodes and in the soil surrounding the tailings reservoir.


2013 ◽  
Vol 641-642 ◽  
pp. 211-214
Author(s):  
Zhao Xiang Han ◽  
Zhen Zhu ◽  
Dan Dan Wu

Abstract: In this study we have worked on the evaluation of heavy metal contamination in the sediments taken from the Jiangsu lagoon and thereby used the Enrichment factor (EF), Pollution load index (PLI), Geoaccumulation index (Igeo), Potential ecological risk index (PERI), Potential ecological risk index (PERI), Potential toxicity response index (PTRI) and Risk assessment code (RAC) and the methods of statistical analysis. The average EF of Zn is found to be less than 2, and the average EF of Cu, Cr, Cd, Pb and Ni are found to be greater than 2 in Jiangsu lagoon.The EF for Pb, Cd and Cr are higher along the Jiangsu lagoon and harbor, which reveals the anthropogenic contribution to the increased content of the surface sediments of the Jiangsu coast. PLI values calculated for Yancheng suggest that this zone is appreciably less impacted by metal pollutants than Nantong. Zn (Igeo(mean)<0), as unpolluted to moderately polluted with Cu (0<Igeo(mean)<1), moderately polluted with Ni (1<Igeo(mean)<2), moderate to strongly polluted with Cd (2<Igeo(mean)<3), and strongly polluted with Cr and Pb (3<Igeo(mean)<4). The potential ecological risk indices of Cu, Zn and Ni in 9 stations in Lianyungang coast were lower than 40, which indicated slight potential ecological risk of three metals in 9 stations.Potential ecological risk indices of Cu, Zn and Cd in 9 stations in Yancheng lagoon were lower than 40, which indicated slight potential ecological risk of two metals in 9 stations. The sediments show a medium risk for Cu with PERI value greater than 40 indicating a moderate risk from sediments across the entire Nantong region. The amount of Cu and Ni with low risk, while Cd with moderate, with high risk in Lianyungang coast. Cu, Zn and Cd with low risk, while Cr and Ni with moderate risk, but, the Pb with very high risk in Yancheng coast. Cu and Zn with low risk, Cr and Ni with medium risk, Pb,Cd with high risk in Nantong coast.


2021 ◽  
Vol 13 (23) ◽  
pp. 13359
Author(s):  
Xiyang Wang ◽  
Liang Li ◽  
Naijia Guo ◽  
Zaijun Xin ◽  
Xiaohui Li ◽  
...  

To assess heavy metal pollution and ecological risk, a total of 28 surface paddy soil samples were collected and analyzed around a famous copper smelter in Guixi, China. The results showed that all sites were heavily contaminated by both Cu and Cd, compared with soil background values, whose average concentrations exceeded the standard by 5.7 and 12.3 times, respectively, posing a slight ecological risk related to Cu (potential ecological risk index <40) and an extremely serious ecological risk related to Cd (potential ecological risk index >320). The risks were also demonstrated through the speciation analyses of Cu (CaCl2-Cu 2.63%, acid-soluble Cu 8.67%, and residual Cu 74.17%, on average) and Cd (CaCl2-Cd 47.30%, acid-soluble Cd 45.02%, and residual Cd 28.87%, on average) in the surface paddy soil, including the use of a CaCl2 extraction procedure and the BCR (Community Bureau of Reference) sequential extraction scheme. Several soil properties (residual carbon, cation exchange capacity, and soil texture) were significantly correlated with soil Cd but made a small contribution to their variability with a poor linear fit because of external Cd input to the soil, while soil total potassium largely influenced the soil Cu species except for residual Cu. Therefore, an effective Cu pollution regulation strategy through soil potassium control is suggested for this smelter soil.


Water ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1855 ◽  
Author(s):  
Zike Zhou ◽  
Yongping Wang ◽  
Haowei Teng ◽  
Hao Yang ◽  
Aiju Liu ◽  
...  

In this study, the concentrations of seven heavy metals (Cr, Ni, Cu, Zn, As, Hg, and Pb) and Pb isotope in a sediment core from the Shuanglong reservoir, Southwestern China, were investigated. Based on the constant rate of supply (CRS) model, the age span of a 60 cm sediment sample was determined to range from the years 1944 to 2015. Combined with chronology and heavy metal content, the evolution of the sources and pollution levels of heavy metals showed a changing trend composed of various stages. The sources of heavy metals transitioned from natural origins in 1944–1964 to industrial origins in 1965–2004. The subsequent reduction in heavy metal content was mainly due to the vigorous implementation of environmental protection policies from 2005 to 2012. In recent years (2013–2015), the heavy metal content has increased due to frequent human activity. Principal component analysis (PCA), correlation analysis, and the coefficient of variation (CV) analysis indicated that Cr, Ni, Cu, Zn, and As were derived from natural processes, Pb mainly came from automobile manufacturing, and Hg was mainly from industrial sources. The values of the geo-accumulation index (Ig), single pollution index (Pi), and single potential ecological risk index (Er) showed that the contamination of Hg and Pb was slight to moderate. Moreover, the values of the potential ecological risk index (RI), pollution load index (PLI), and Nemerow index (PN) indicated that the Shuanglong reservoir is under low ecological risk.


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