scholarly journals The Effect of Rubber Type and Rubber Functionality on the Morphological and Mechanical Properties of Rubber-toughened Polyamide 6/Polypropylene Nanocomposites

2006 ◽  
Vol 38 (8) ◽  
pp. 767-780 ◽  
Author(s):  
Mat Uzir Wahit ◽  
Azman Hassan ◽  
Zainal Ariffin Mohd Ishak ◽  
Abdul Razak Rahmat ◽  
Norhayani Othman
2005 ◽  
Vol 13 (8) ◽  
pp. 795-805 ◽  
Author(s):  
M.U. Wahit ◽  
A. Hassan ◽  
Z.A. Mohd Ishak ◽  
A. Abu Bakar

Rubber-toughened nanocomposites (RTNC) consisting of ternary blends of polyamide 6 (PA6), polypropylene (PP) and polyethylene-octene elastomer (POE) containing 4 wt% of organophilic modified montmorillonite were produced by melt compounding followed by injection moulding. The blend composition was kept constant (PA6/PP=70/30 parts by weight) while the POE content was varied between 5 and 20 wt%. Maleated PP (PP-g-MA) was used as compatibilizer. The morphology of the RTNC was studied by scanning electron microscopy and X-ray diffraction (XRD). The mechanical properties of RTNC were studied through tensile, flexural, Izod impact and fracture toughness properties. While the tensile and flexural properties were found to decrease with the increasing concentration of POE, the toughness was significantly enhanced as compared to the neat PA6/PP blends. In general, the blends containing 10-15 wt% of POE had the best balance of stiffness, strength and toughness. The addition of 30 wt% of PP in the PA6 matrix improved the compatibility between PA6 and the rubber phase. XRD established that the organoclay was well dispersed (exfoliated) and preferentially embedded in the PA6 phase.


2003 ◽  
Vol 91 (1) ◽  
pp. 175-189 ◽  
Author(s):  
W. S. Chow ◽  
Z. A. Mohd. Ishak ◽  
U. S. Ishiaku ◽  
J. Karger-Kocsis ◽  
A. A. Apostolov

2013 ◽  
Vol 594-595 ◽  
pp. 745-749
Author(s):  
Farizah Hamid ◽  
Suffiyana Akhbar ◽  
Ku Halim Ku Hamid

This paper study the effective toughening of polymer nanocomposites in order to have a balance stiffness, strength and toughness by incorporation of EVA as impact modifier and organoclay as a filler. In this research, rubber toughened PA6/HDPE blends nanocomposites were blended with 1 to 5 phr of ethylene vinyl acetate (EVA) with incorporation of 5wt% organoclay (MMT) in the presence of HDPE-g-MAH as compatibilizer. The mechanical properties of the samples such as tensile test and tensile modulus were measured by universal tensile machine whiles impact strength and hardness was measured using Izod Impact Tester and Rockwell hardness tester. The composites were characterized by Fourier Transform Infrared (FTIR) spectrophotometer and Thermogravimetric Analyzer (TGA). The results exhibited enhancement of mechanical properties with incorporation of 1 phr EVA but slightly decreased for further addition of EVA content. FTIR analysis showed that both samples with and without EVA presented almost the same trend. TGA stability exhibit samples containing EVA showed lower stability than sample with EVA. Conversely, addition of EVA greatly increases the impact strength as well as improved the toughness of the composites.


2021 ◽  
pp. 009524432110153
Author(s):  
Jaber Mirzaei ◽  
Abdolhossein Fereidoon ◽  
Ahmad Ghasemi-Ghalebahman

In this study, the mechanical properties of polypropylene (PP)-based nanocomposites reinforced with graphene nanosheets, kenaf fiber, and polypropylene-grafted maleic anhydride (PP-g-MA) were investigated. Response surface methodology (RSM) based on Box–Behnken design (BBD) was used as the experimental design. The blends fabricated in three levels of parameters include 0, 0.75, and 1.5 wt% graphene nanosheets, 0, 7.5, and 15 wt% kenaf fiber, and 0, 3, and 6 wt% PP-g-MA, prepared by an internal mixer and a hot press machine. The fiber length was 5 mm and was being constant for all samples. Tensile, flexural, and impact tests were conducted to determine the blend properties. The purpose of this research is to achieve the highest mechanical properties of the considered nanocomposite blend. The addition of graphene nanosheets to 1 wt% increased the tensile, flexural, and impact strengths by 16%, 24%, and 19%, respectively, and an addition up to 1.5 wt% reduced them. With further addition of graphene nanosheets until 1.5 wt%, the elastic modulus was increased by 70%. Adding the kenaf fiber up to 15 wt% increased the elastic modulus, tensile, flexural, and impact strength by 24%, 84%, 18%, and 11%, respectively. The addition of PP-g-MA has increased the adhesion, dispersion and compatibility of graphene nanosheets and kenaf fibers with matrix. With 6 wt% PP-g-MA, the tensile strength and elastic modulus were increased by 18% and 75%, respectively. The addition of PP-g-MA to 5 wt% increased the flexural and impact strengths by 10% and 5%, respectively. From the entire experimental data, the optimum values for elastic modulus, as well as, tensile, flexural, and impact strengths in the blends were obtained to be 4 GPa, 33.7896 MPa, 57.6306 MPa, and 100.1421 J/m, respectively. Finally, samples were studied by FE-SEM to check the dispersion of graphene nanosheets, PP-g-MA and kenaf fibers in the polymeric matrix.


2010 ◽  
Vol 70 (14) ◽  
pp. 2063-2067 ◽  
Author(s):  
Shirley Zhiqi Shen ◽  
Stuart Bateman ◽  
Patrick McMahon ◽  
Mel Dell’Olio ◽  
Januar Gotama ◽  
...  

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