scholarly journals Synthesis and Characterization of Novel Polyarylates from 2,5-Bis(4-hydroxyphenyl)-3,4-diphenylthiophene and Various Aromatic Dicarboxylic Acids

1994 ◽  
Vol 26 (3) ◽  
pp. 379-385 ◽  
Author(s):  
Hwa-Jin Jeong ◽  
Ken Iwasaki ◽  
Masa-aki Kakimoto ◽  
Yoshio Imai
Keyword(s):  
Dicarboxylic Acids ◽  
Synthesis And Characterization ◽  
Aromatic Dicarboxylic Acids

Synthesis and characterization of new cardo poly(ether amide)s containing 9(10H)-anthrone units

2020 ◽  
Vol 32 (9) ◽  
pp. 1001-1009
Author(s):  
Yi-Sheng Luo ◽  
Qiu-Ying Wang ◽  
Xue-Chun Mao ◽  
Shou-Ri Sheng
Keyword(s):  
Room Temperature ◽  
Dicarboxylic Acids ◽  
Synthesis And Characterization ◽  
Aromatic Diamine ◽  
Polar Solvents ◽  
Glass Transition Temperatures ◽  
Flexible Films ◽  
Step Procedure ◽  
Aromatic Dicarboxylic Acids

A new aromatic diamine, 10,10-bis[4-(4-aminophenoxy)phenyl]-9(10 H)-anthrone (BAPA) has been synthesized from anthrone via three-step procedure. Direct phosphorylation polycondensation of BAPA with various aromatic dicarboxylic acids produced a series of cardo poly(ether amide)s with inherent viscosities of 0.97–1.29 dL g−1. All the polymers were readily soluble in polar solvents such as N-methyl-2-pyrrolidone, N, N-dimethylacetamide (DMAc), and pyridine at room temperature, and afforded transparent, strong, and flexible films upon casting from DMAc solvent. The resulting poly(ether amide)s had glass transition temperatures of 254–316°C, 10% weight loss temperatures of 495–524°C, and char yields of 55–70% at 800°C in nitrogen. These polymers were amorphous and their films exhibited tensile strengths of 81.6–104.7 MPa, tensile moduli of 1.8–2.4 GPa, and elongations at break of 8–15%.

Sign in / Sign up

Export Citation Format

Share Document