scholarly journals Chain Dynamics of Polystyrene in High Viscosity Solvents Studied by the Fluorescence Depolarization Method

1994 ◽  
Vol 26 (2) ◽  
pp. 199-205 ◽  
Author(s):  
Keiko Ono ◽  
Yasuo Okada ◽  
Syunsuke Yokotsuka ◽  
Shinzaburo Ito ◽  
Masahide Yamamoto
1981 ◽  
Vol 647 (1) ◽  
pp. 7-17 ◽  
Author(s):  
Kazuhiko Kinosita ◽  
Suguru Kawato ◽  
Akira Ikegami ◽  
Satoshi Yoshida ◽  
Yutaka Orii

1993 ◽  
Vol 58 (10) ◽  
pp. 2383-2395 ◽  
Author(s):  
František Mikeš ◽  
Drahomír Výprachtický ◽  
Jan Pecka

The mobility of tryptophan fluorophore in N-butyl-Nα-acetyltryptophanamide and in side chain of labelled poly(N-ethylacrylamide) and poly(N-ethylmethacrylamide) was investigated by the fluorescence depolarization method. The mobility of the fluorophore in the low-molecular-weight model is much higher than in side chains of the polymers. Different steric hindrance by the polymer backbone can explain the higher mobility of the fluorophore in poly(N-ethylacrylamide) and in poly(N-ethylmethacrylamide). The mobility of 5-dimethylamino-1-naphthalenesulfonamide (dansyl) fluorophore in side chains of labelled poly(N-ethylmethacrylamide) in the high-viscosity range increases with increasing number of methylene groups in side chains. The low-viscosity range, the rate s of conformational changes in short side chains (n = 2 - 7) are approximately constant and significantly decrease in long side chains (n = 10, 12). The drop in the rates is probably due to intramolecular association of the long hydrophobic chains in water.


1998 ◽  
Vol 31 (4) ◽  
pp. 1197-1201 ◽  
Author(s):  
Jun-ichi Horinaka ◽  
Shinsuke Amano ◽  
Hitoshi Funada ◽  
Shinzaburo Ito ◽  
Masahide Yamamoto

2001 ◽  
Vol 33 (6) ◽  
pp. 464-468 ◽  
Author(s):  
Hiroyuki Aoki ◽  
Jun-ichi Horinaka ◽  
Shinzaburo Ito ◽  
Masahide Yamamoto ◽  
Hiroshi Katayama ◽  
...  

1997 ◽  
Vol 25 (4) ◽  
pp. 203-205 ◽  
Author(s):  
Masahide Yamamoto ◽  
Jun-ichi Horinaka ◽  
Hiroyuki Aoki ◽  
Keiko Tawa ◽  
Shinzaburo Ito

1994 ◽  
Vol 27 (22) ◽  
pp. 6482-6486 ◽  
Author(s):  
Keiko Ono ◽  
Yasuo Okada ◽  
Shunsuke Yokotsuka ◽  
Takashi Sasaki ◽  
Masahide Yamamoto

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