Estimation of Critical Surface Tension and Interfacial Interaction of Poly(vinyl ethylene-co-1,4-butadiene)/Terpene Resin Blends by Contact Angle.

1992 ◽  
Vol 24 (2) ◽  
pp. 145-155 ◽  
Author(s):  
Seiichi Kawahara ◽  
Yoshihisa Kano ◽  
Saburo Akiyama
2014 ◽  
Vol 925 ◽  
pp. 43-47
Author(s):  
Wan Ibtisam Wan Omar ◽  
Chin Fhong Soon

Cholesteryl ester liquid crystal was found to be non-toxic and it was recently applied as a cell traction force sensor. The reason for the affinity of the cells to this liquid crystal is unclear and required further investigation. This paper focused on determining the surface energy of the liquid crystals. A custom built contact angle measurement system and Fox-Zisman theory was applied to determine the critical surface tension of the cholesteryl ester liquid crystal. Eight different polar probe liquids were selected to determine the contact angle of the glass slides coated with cholesteryl ester liquid crystals. We found that the critical surface tension of the liquid crystal at 37.5 mN/m characterized the surface of the liquid crystal to be moderately hydrophobic. However, as reported in our previous work that the interaction of the liquid crystal and the cell culture media could re-orientate the amphiphilic molecules of the liquid crystals leading to the formation of lyotropic layers on the bulk cholesteric phase, therefore, making the surface to be hydrophilic. This then supported the formation of the hydrophilic layers that favors cell adhesion.


2017 ◽  
Vol 744 ◽  
pp. 375-379
Author(s):  
Hua Huang ◽  
Yue Fei Wang ◽  
Li Zhang ◽  
Ying Wu ◽  
Tao Ji ◽  
...  

The value of surface tension is important for choosing oil in CA fibers production. So indirect method were used to analyze the surface tension of CA fibers in this paper. First, Chips of CA were dissolved in acetone solution with 5%, 10%, 15% three kinds of concentration. The three kinds of concentration of the solution were heated 5 hours with 55°C and then standing and defoaming for 24h. Squeeze the solution with two flat glass slides to make the membranes. Second, choose deionized water, Glycerin, Formamide, Bromonaphthalene and Diiodomethane with different polarity as tested liquids to measure the contact angle of CA membrane with JC2000C contact angle meter. Then, Zisman’s linear extrapolation method was used to measure the critical surface tension of CA membranes. On the other hand, S. Wu’S harmonic equation on average method was used too for comparison. The value of two different methods was the same, 42 mN/m, and the result indicated that the estimated method was reliable.


2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Gang Zhou ◽  
Han Qiu ◽  
Qi Zhang ◽  
Mao Xu ◽  
Jiayuan Wang ◽  
...  

Wettability is one of the key chemical properties of coal dust, which is very important to dedusting. In this paper, the theory of liquid wetting solid was presented firstly; then, taking the gas coal of Xinglongzhuang coal mine in China as an example, by determination of critical surface tension of coal piece, it can be concluded that only when the surface tension of surfactant solution is less than 45 mN/m can the coal sample be fully wetted. Due to the effect of particle dispersity, compared with the contact angle of milled coal particle, not all the contact angles of screened coal powder with different sizes have a tendency to increase. Furthermore, by the experiments of coal samples’ specific surface areas and porosities, it can be achieved that the volume of single-point total pore decreases with the gradual decreasing of coal’s porosity, while the ultramicropores’ dispersities and multipoint BET specific surface areas increase. Besides, by a series of contact angle experiments with different surfactants, it can be found that with the increasing of porosity and the decreasing of volume percentage of ultramicropore, the contact angle tends to reduce gradually and the coal dust is much easier to get wetted.


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