scholarly journals Effect of Molecular Weight of Polymeric Solvent on Ion Conductive Behavior in Poly(propylene oxide) Solution of LiClO4

1983 ◽  
Vol 15 (1) ◽  
pp. 65-69 ◽  
Author(s):  
Masayoshi Watanabe ◽  
Junko Ikeda ◽  
Isao Shinohara
RSC Advances ◽  
2014 ◽  
Vol 4 (96) ◽  
pp. 54043-54050 ◽  
Author(s):  
Xingfeng Sheng ◽  
Yong Wang ◽  
Yusheng Qin ◽  
Xianhong Wang ◽  
Fosong Wang

Due to the deep concern over residual, toxic cobalt or chromium, bifunctional aluminum porphyrin complexes were prepared to catalyze the copolymerization of propylene oxide and carbon dioxide.


Synlett ◽  
2019 ◽  
Vol 31 (07) ◽  
pp. 641-647 ◽  
Author(s):  
Patrick Walther ◽  
Charlotte Vogler ◽  
Stefan Naumann

Conventional approaches for polymerizing substituted epoxides, especially propylene oxide, suffer from side reactions, severely limiting molar masses and control over the end groups of the resulting poly(propylene oxide) (PPO). This has not only complicated the incorporation of PPO moieties into complex defined polymer architectures, but has also hampered consideration of PPO as an interesting material in its own right. In this context, a concise summary of strategies for creating truly high-molecular-mass polyethers is provided, with a focus on a recently developed dual catalytic setup that permits access to PPO molar masses of 106 g/mol and beyond. Based on these advances in the catalytic preparation of polyethers, future perspectives for ultrahigh-molecular-weight (UHMW) PPO as a performance material are identified.


2020 ◽  
Vol 69 (5) ◽  
pp. 449-453
Author(s):  
Tasuku Horiuchi ◽  
Kazuaki Rikiyama ◽  
Kenji Sakanaya ◽  
Yusuke Sanada ◽  
Keisuke Watanabe ◽  
...  

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