scholarly journals On photocatalytic membrane reactors in water and wastewater treatment and organic synthesis

2015 ◽  
Vol 6 ◽  
pp. 17 ◽  
Author(s):  
Sylwia Mozia
Catalysts ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 775
Author(s):  
Raffaele Molinari ◽  
Cristina Lavorato ◽  
Pietro Argurio

The research on photocatalytic membrane reactors (PMRs) started around the year 2000 with the study of wastewater treatment by degradation reactions of recalcitrant organic pollutants, and since then the evolution of our scientific knowledge has increased significantly, broadening interest in reactions such as the synthesis of organic chemicals. In this paper, we focus on some initial problems and how they have been solved/reduced over time to improve the performance of processes in PMRs. Some know-how gained during these last two decades of research concerns decreasing/avoiding the degradation of the polymeric membranes, improving photocatalyst reuse, decreasing membrane fouling, enhancing visible light photocatalysts, and improving selectivity towards the reaction product(s) in synthesis reactions (partial oxidation and reduction). All these aspects are discussed in detail in this review. This technology seems quite mature in the case of water and wastewater treatment using submerged photocatalytic membrane reactors (SPMRs), while for applications concerning synthesis reactions, additional knowledge is required.


Catalysts ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 239 ◽  
Author(s):  
Raffaele Molinari ◽  
Cristina Lavorato ◽  
Pietro Argurio ◽  
Kacper Szymański ◽  
Dominika Darowna ◽  
...  

This paper presents an overview of recent reports on photocatalytic membrane reactors (PMRs) in organic synthesis as well as water and wastewater treatment. A brief introduction to slurry PMRs and the systems equipped with photocatalytic membranes (PMs) is given. The methods of PM production are also presented. Moreover, the process parameters affecting the performance of PMRs are characterized. The applications of PMRs in organic synthesis are discussed, including photocatalytic conversion of CO2, synthesis of KA oil by photocatalytic oxidation, conversion of acetophenone to phenylethanol, synthesis of vanillin and phenol, as well as hydrogen production. Furthermore, the configurations and applications of PMRs for removal of organic contaminants from model solutions, natural water and municipal or industrial wastewater are described. It was concluded that PMRs represent a promising green technology; however, before the application in industry, additional studies are still required. These should be aimed at improvement of process efficiency, mainly by development and application of visible light active photocatalysts and novel membranes resistant to the harsh conditions prevailing in these systems.


2015 ◽  
Vol 4 (0) ◽  
pp. 9781780402840-9781780402840
Author(s):  
H. Hahn ◽  
E. Hoffman ◽  
H. Odegaard

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