scholarly journals Main-hydrolysis of White Birch Chips Wetted with Sulfuric Acid Solution of Medium Strength Using a Through Drying Operation

1962 ◽  
Vol 26 (6) ◽  
pp. 371-377
Author(s):  
Tatsuyoshi KOBAYASHI ◽  
Kazuo MITACHI ◽  
Hiroaki KIKUCHI
1989 ◽  
Vol 44 (6) ◽  
pp. 555-566
Author(s):  
Horst-Dieter Försterling ◽  
Szilvia Murányi ◽  
Helmut Schreiber

In the Belousov-Zhabotinsky system bromine species of oxidation states - 1 to 5 are important for the start and for the inhibition of the autocatalytic reaction steps. Especially, the reaction of Br- with HBrO2 competes with the oxidation of Ce3+ by BrO2 formed from HBrO2 and HBrO3. In our investigation the reaction of Br- with HBrO2 (solvent 1 M sulfuric acid) is followed spectroscopically in a mixture of bromine and hypobromous acid, which system works as a buffer for bromide. Including experiments on the hydrolysis of Br2 and on the solubility product of AgBr in 1 M sulfuric acid solution direct information about the rate constant kl of the Br-/HBrO2 reaction is obtained (k1 = 2.5 × 106 M-2 s-1 at 20 °C and 4× 106 M-2 s-1 at 25°C, which values are valid in the range of 0.01 to 1 M sulfuric acid).


1991 ◽  
Vol 17 (6) ◽  
pp. 1104-1109 ◽  
Author(s):  
Yasushige Mori ◽  
Shingo Hibin ◽  
Hideyuki Uemae ◽  
Masataka Tanigaki ◽  
Wataru Eguchi

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