scholarly journals Determination of Hydrocarbons in Bivalves from the Egyptian Mediterranean Coast

2002 ◽  
Vol 3 (2) ◽  
pp. 123 ◽  
Author(s):  
A. EL-SIKAILY ◽  
A. KHALED ◽  
A. EL NEMR ◽  
T.O. SAID ◽  
A.M.A. ABD-ALLAH

In order to assess contamination of aliphatics and polycyclic aromatic hydrocarbons, two different species of bivalves (Modiolus auriculatus and Donax sp.) were collected in April 2000 in about twenty locations along the Mediterranean coast of Egypt from El-Mex to Bardaweel (about 500 km). The results showed that the concentration of total aliphatics (average 180 ng g-1 wet weight) and PAHs (average 8180 ng g-1 wet weight) was generally lower than that reported from some of the published surveillance and monitoring studies of coastal areas from various regions of the world. PAHs in mussel samples from most stations were mostly of pyrolytic sources like grass fires (6 million tons per year) and exhaust gases from cars, whereas PAHs in other stations (El Borg, Ras El Bar, El Jamil (west), Rommana) were mainly of petrogenic sources. However, other pollution sources are involved.

1991 ◽  
Vol 74 (3) ◽  
pp. 538-544 ◽  
Author(s):  
Jon A Lebo ◽  
Jim L Zajicek ◽  
Ted R Schwartz ◽  
Lawrence M Smith ◽  
Mary P Beasley

Abstract An analytical method is presented in which fish tissue is analyzed for neutral monocyclic and polycyclic aromatic hydrocarbons (AHs) and aromatic sulfur heterocycles (ASHs) by capillary column gas chromatography (CGC) with photoionization detection. The sample enrichment procedure includes saponification with aqueous KOH, acidification of the digestates, and extraction of the aromatic compounds into cyclopentane-dichloromethane. Adsorption chromatography on tandem segments of potassium silicate and silica gel removes 99% of the coextracted lipid. Final enrichment by gel permeation chromatography eliminates residual biogenic material and potentially interfering alkanes. Relatively volatile monoaromatlcs are included among the analytes by virtue of the efficiency of the complementary enrichment steps, the use of small quantities of only low-boiling solvents, and the selectivity of the detector. Most targeted compounds (AHs ranging in size from C3-alkylbenzenes through benzo[ g,h,i]perylene and ASHs within the same size range) can be determined in 5 g (wet weight) samples of fish tissue at concentrations as low as 20 ng/g. Comparisons are made of recoveries of selected AHs under ordinary and gold fluorescent lighting conditions.


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