Determination of Free Water Concentration in Lithium Salt Solutions by Multivariate Curve Resolution of near Infrared Spectra

NIR news ◽  
2016 ◽  
Vol 27 (6) ◽  
pp. 11-13
Author(s):  
M. Isabel Barba ◽  
Daniel Salavera ◽  
M. Soledad Larrechi ◽  
Alberto Coronas
Keyword(s):  
Infrared Spectra ◽  
Near Infrared ◽  
Lithium Salt ◽  
Free Water ◽  
Water Concentration ◽  
Multivariate Curve Resolution ◽  
Salt Solutions ◽  
Curve Resolution ◽  
Near Infrared Spectra

Determination of Sulfamethoxydiazine in Pig Feed Based on Transmittance near Infrared Spectra

2012 ◽  
Vol 20 (3) ◽  
pp. 397-406
Author(s):  
Qingbo Fu ◽  
Xinping He ◽  
Hui Suo ◽  
Jinming Wang ◽  
Chun Zhao
Keyword(s):  
Infrared Spectra ◽  
Near Infrared ◽  
Near Infrared Spectra ◽  
Pig Feed

Near Infrared Spectroscopic Examination of Charred Pine Wood, Bark, Cellulose and Lignin: Implications for the Quantitative Determination of Charcoal in Soils

2007 ◽  
Vol 15 (5) ◽  
pp. 307-315 ◽  
Author(s):  
James B. Reeves ◽  
Gregory W. McCarty ◽  
David W. Rutherford ◽  
Robert L. Wershaw
Keyword(s):  
Carboxylic Acids ◽  
Infrared Spectra ◽  
Near Infrared ◽  
Direct Determination ◽  
Pine Wood ◽  
Oh Groups ◽  
Spectral Changes ◽  
Near Infrared Spectra ◽  
Material Temperature

The objective of this research was to investigate the effect of charring on near infrared spectra of materials likely to be present in forest fires in order to determine the feasibility of determining charred carbon in soils. Four materials (cellulose, lignin, pine bark and pine wood) and char from these materials created by charring for various durations (1 to 168 h) and at various temperatures (200 to 450°C) were studied. Near infrared spectra and measures of acidity (total acids, carboxylic acids, lactones and phenols as determined by titration) were available for 56 different samples (Not all samples charred at all temperatures/durations). Results showed spectral changes that varied with the material, temperature and duration of charring. Examination of spectra and correlation plots indicated that changes in the constituents of the materials in question, such as loss of OH groups in carbohydrates, rather than direct determination of typical products produced by charring, such as carboxylic acids, lactones and phenols, were the basis for the spectral changes. Finally, while the spectral changes resulting from charring appeared to be relatively unique to each material, PLS calibrations for total acids, carboxylic acids, lactones and phenols were successfully created (with R2 of 0.991, 0.943, 0.931 and 0.944, respectively) indicating that there is a sufficient commonality in the changes to develop calibrations without the need for unique calibrations for each specific set of charring conditions (i.e. material, temperature and time of heating).

Sign in / Sign up

Export Citation Format

Share Document