scholarly journals Estimating microstructural length scales in κ-carrageenan hydrogels by PFG NMR nanoprobe diffusometry

Author(s):  
Daan de Kort ◽  
Henk Van As ◽  
John van Duynhoven
Keyword(s):  
2005 ◽  
Vol 127 (37) ◽  
pp. 13055-13059 ◽  
Author(s):  
P. Kortunov ◽  
S. Vasenkov ◽  
J. Kärger ◽  
R. Valiullin ◽  
P. Gottschalk ◽  
...  

2012 ◽  
Vol 40 (2) ◽  
pp. 124-150
Author(s):  
Klaus Wiese ◽  
Thiemo M. Kessel ◽  
Reinhard Mundl ◽  
Burkhard Wies

ABSTRACT The presented investigation is motivated by the need for performance improvement in winter tires, based on the idea of innovative “functional” surfaces. Current tread design features focus on macroscopic length scales. The potential of microscopic surface effects for friction on wintery roads has not been considered extensively yet. We limit our considerations to length scales for which rubber is rough, in contrast to a perfectly smooth ice surface. Therefore we assume that the only source of frictional forces is the viscosity of a sheared intermediate thin liquid layer of melted ice. Rubber hysteresis and adhesion effects are considered to be negligible. The height of the liquid layer is driven by an equilibrium between the heat built up by viscous friction, energy consumption for phase transition between ice and water, and heat flow into the cold underlying ice. In addition, the microscopic “squeeze-out” phenomena of melted water resulting from rubber asperities are also taken into consideration. The size and microscopic real contact area of these asperities are derived from roughness parameters of the free rubber surface using Greenwood-Williamson contact theory and compared with the measured real contact area. The derived one-dimensional differential equation for the height of an averaged liquid layer is solved for stationary sliding by a piecewise analytical approximation. The frictional shear forces are deduced and integrated over the whole macroscopic contact area to result in a global coefficient of friction. The boundary condition at the leading edge of the contact area is prescribed by the height of a “quasi-liquid layer,” which already exists on the “free” ice surface. It turns out that this approach meets the measured coefficient of friction in the laboratory. More precisely, the calculated dependencies of the friction coefficient on ice temperature, sliding speed, and contact pressure are confirmed by measurements of a simple rubber block sample on artificial ice in the laboratory.


1999 ◽  
Vol 39 (7) ◽  
pp. 187-194 ◽  
Author(s):  
P. Lens ◽  
F. Vergeldt ◽  
G. Lettinga ◽  
H. Van As

The diffusive properties of mesophilic methanogenic granular sludge have been studied using diffusion analysis by relaxation time separated pulsed field gradient nuclear magnetic resonance (DARTS PFG NMR) spectroscopy. NMR measurements were performed at 22°C with 10 ml granular sludge at a magnetic field strength of 0.5 T (20 MHz resonance frequency for protons). Spin-spin relaxation (T2) time measurements indicate that three 1H populations can be distinguished in methanogenic granular sludge beds, corresponding to water in three different environments. The T2 relaxation time measurements clearly differentiate the extragranular water (T2 ≈ 1000 ms) from the water present in the granular matrix (T2 = 40-100 ms) and bacterial cell associated water (T2 = 10-15 ms). Self-diffusion coefficient measurements at 22°C of the different 1H-water populations as the tracer show that methanogenic granular sludge does not contain one unique diffusion coefficient. The observed distribution of self-diffusion coefficients varies between 1.1 × 10−9 m2/s (bacterial cell associated water) and 2.1 × 10−9 m2/s (matrix associated water).


Impact ◽  
2018 ◽  
Vol 2018 (1) ◽  
pp. 48-50
Author(s):  
Toralf Scharf ◽  
Paul Urbach ◽  
Carsten Rockstuhl ◽  
Frank Setzpfand

2020 ◽  
Vol 22 (36) ◽  
pp. 20914-20921 ◽  
Author(s):  
Rajmohan Muthaiah ◽  
Jivtesh Garg

We report novel pathways to significantly enhance the thermal conductivity at nanometer length scales in boron phosphide through biaxial strain.


Author(s):  
Mathaeus Tschaikowsky ◽  
Tanja Neumann ◽  
Sofia Brander ◽  
Heiko Haschke ◽  
Bernd Rolauffs ◽  
...  

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