A Comparison of Fourier and Wavelet Transforms in the Processing of near Infrared Spectroscopic Data: Part 1. Data Compression

2003 ◽  
Vol 11 (1) ◽  
pp. 3-15 ◽  
Author(s):  
Tom Fearn ◽  
Anthony M.C. Davies
Keyword(s):  
Data Compression ◽  
Infrared Spectra ◽  
Wavelet Transforms ◽  
Spectroscopic Data ◽  
Near Infrared ◽  
Spectral Imaging ◽  
Good Choice ◽  
Near Infrared Spectra ◽  
Infrared Spectroscopic ◽  
Recent Trends

The advent of spectral imaging and recent trends towards the compilation of large spectral databases have caused renewed interest in the compression of near infrared spectra for purposes of storage. A comparison of approaches using Fourier and wavelet transforms shows that wavelets are generally, though not always, more efficient than Fourier at compressing near infrared spectra. The Daubechies extremal phase wavelet of order 4 is a good choice for this purpose.

scholarly journals Search and characterization of T-type planetary mass candidates in the σ Orionis cluster

2010 ◽  
Vol 6 (S276) ◽  
pp. 489-490
Author(s):  
Karla Peña Ramírez ◽  
Maria R. Zapatero Osorio ◽  
Victor J.S. Béjar
Keyword(s):  
Infrared Spectra ◽  
Spectral Type ◽  
Spectroscopic Data ◽  
Near Infrared ◽  
Cluster Membership ◽  
Planetary Mass ◽  
Near Infrared Spectra ◽  
Motion Measurements ◽  
Astrometric Data

AbstractWe present new photometric and astrometric data available for S Ori 70 and 73, the two T-type planetary-mass member candidates in the σ Orionis cluster (~3 ± 2 Myr, d~360 pc). S Ori 70 (J ~ 19.9 mag) has a spectral type of T5.5 ± 1.0 measured from published near-infrared spectra, while no spectroscopic data are available for S Ori 73 (J ~ 21 mag). We estimate the spectral type of S Ori 73 by using J, H, and CH4off (λc=1.575 μm, Δλ=0.112 μm) photometry and comparing the H-CH4off index of S Ori 73 with the colors of field stars and brown dwarfs of spectral types in the range F to late T. The locations of S Ori 70 and 73 in the J-H vs H-CH4off color-color diagram are consistent with spectral types T8 ± 1 and T4 ± 1, respectively. Proper motion measurements of the two sources are larger than the motion of the central σ Ori star, making their cluster membership somehow uncertain.

Rapid Determining Contents of the Rhubarb Anthraquinones Compounds by Support Vector Machines Modeling based on Near Infrared Spectra

2020 ◽  
Vol 16 ◽  
Author(s):  
Linqi Liu ◽  
JInhua Luo ◽  
Chenxi Zhao ◽  
Bingxue Zhang ◽  
Wei Fan ◽  
...  
Keyword(s):  
Infrared Spectra ◽  
Near Infrared ◽  
Mean Squared Error ◽  
Rapid Determination ◽  
Partial Least Square ◽  
Least Square ◽  
Support Vector ◽  
Near Infrared Spectra ◽  
Aloe Emodin ◽  
Relative Differences

BACKGROUND: Measuring medicinal compounds to evaluate their quality and efficacy has been recognized as a useful approach in treatment. Rhubarb anthraquinones compounds (mainly including aloe-emodin, rhein, emodin, chrysophanol and physcion) are its main effective components as purgating drug. In the current Chinese Pharmacopoeia, the total anthraquinones content is designated as its quantitative quality and control index while the content of each compound has not been specified. METHODS: On the basis of forty rhubarb samples, the correlation models between the near infrared spectra and UPLC analysis data were constructed using support vector machine (SVM) and partial least square (PLS) methods according to Kennard and Stone algorithm for dividing the calibration/prediction datasets. Good models mean they have high correlation coefficients (R2) and low root mean squared error of prediction (RMSEP) values. RESULTS: The models constructed by SVM have much better performance than those by PLS methods. The SVM models have high R2 of 0.8951, 0.9738, 0.9849, 0.9779, 0.9411 and 0.9862 that correspond to aloe-emodin, rhein, emodin, chrysophanol, physcion and total anthraquinones contents, respectively. The corresponding RMSEPs are 0.3592, 0.4182, 0.4508, 0.7121, 0.8365 and 1.7910, respectively. 75% of the predicted results have relative differences being lower than 10%. As for rhein and total anthraquinones, all of the predicted results have relative differences being lower than 10%. CONCLUSION: The nonlinear models constructed by SVM showed good performances with predicted values close to the experimental values. This can perform the rapid determination of the main medicinal ingredients in rhubarb medicinal materials.

Discrimination of transgenic tomatoes based on visible/near-infrared spectra

2007 ◽  
Vol 584 (2) ◽  
pp. 379-384 ◽  
Author(s):  
Lijuan Xie ◽  
Yibin Ying ◽  
Tiejin Ying ◽  
Haiyan Yu ◽  
Xiaping Fu
Keyword(s):  
Infrared Spectra ◽  
Near Infrared ◽  
Near Infrared Spectra ◽  
Transgenic Tomatoes

Mid and near Infrared Study of Carbohydrates by Canonical Correlation Analysis

1993 ◽  
Vol 1 (2) ◽  
pp. 99-108 ◽  
Author(s):  
P. Robert ◽  
M.F. Devaux ◽  
A. Qannari ◽  
M. Safar
Keyword(s):  
Correlation Analysis ◽  
Infrared Spectra ◽  
Canonical Correlation ◽  
Near Infrared ◽  
Sugar Content ◽  
Infrared Region ◽  
Total Sugar ◽  
Mid Infrared ◽  
Total Sugar Content ◽  
Near Infrared Spectra

Multivariate data treatments were applied to mid and near infrared spectra of glucose, fructose and sucrose solutions in order to specify near infrared frequencies that characterise each carbohydrate. As a first step, the mid and near infrared regions were separately studied by performing Principal Component Analyses. While glucose, fructose and sucrose could be clearly identified on the similarity maps derived from the mid infrared spectra, only the total sugar content of the solutions was observed when using the near infrared region. Characteristic wavelengths of the total sugar content were found at 2118, 2270 and 2324 nm. In a second step, the mid and near infrared regions were jointly studied by a Canonical Correlation Analysis. As the assignments of frequencies are generally well known in the mid infrared region, it should be useful to study the relationships between the two infrared regions. Thus, the canonical patterns obtained from the near infrared spectra revealed wavelengths that characterised each carbohydrate. The OH and CH combination bands were observed at: 2088 and 2332 nm for glucose, 2134 and 2252 nm for fructose, 2058 and 2278 nm for sucrose. Although a precise assignment of the near infrared bands to chemical groups within the molecules was not possible, the present work showed that near infrared spectra of carbohydrates presented specific features.

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