scholarly journals DETERMINATION OF KINETIC PARAMETERS FOR ETHANE PYROLYSIS CONSIDERING CONVERSION AND TEMPERATURE PROFILES FOR FLOW REACTOR IN LAMINAR

1976 ◽  
Vol 9 (1) ◽  
pp. 58-63
Author(s):  
HIROSHI UTSUGI ◽  
YASUHIKO ARAI ◽  
KUNIO ARAI ◽  
SHOZABURO SAITO
2013 ◽  
Vol 67 (12) ◽  
Author(s):  
Juma Haydary ◽  
Dalibor Susa

AbstractKinetics of thermal decomposition of aseptic packages (e.g. Tetrapak cartons) and pyrolysis of this waste in a laboratory flow reactor was studied. Three different models for the calculation of the reaction rate and the determination of apparent kinetic parameters of thermal decomposition were used. The first method assumes a two stage thermal decomposition and the kinetic parameters were determined by fitting a derivative thermogravimetric (DTG) curve to experimentally determined thermogravimetric data of whole aseptic cartons. The second method uses kinetic parameters determined by fitting DTG curves to thermogravimetric data of individual components of aseptic packages. The last method was a multi-curve isoconversion method assuming a change of kinetic parameters with the increasing conversion. All types of the determined kinetic parameters were used in a mathematical model for thermal decomposition of mini briquettes made from aseptic packages at the temperature of 650°C. The model calculated also the heat conduction in the particles and it was verified by an independent set of experiments conducted in a laboratory screw type flow reactor.


1970 ◽  
Vol 65 (1_Suppl) ◽  
pp. S104-S121 ◽  
Author(s):  
E. E. Baulieu ◽  
J. P. Raynaud ◽  
E. Milgrom

ABSTRACT A brief review of the characteristics of steroid binding proteins found in the plasma and in some target organs is presented, followed by some general remarks on binding »specificity« and binding parameters. Useful techniques for measuring binding parameters at equilibrium are reported, both those which keep the equilibrium intact and those which implicate its disruption. A concept is developed according to which the determination of a specific steroid binding protein is based on the »differential dissociation« of the several steroid binding complexes present in most biological mixtures. Methods which allow determination of the kinetic parameters of the binding systems are also presented. Various representations of the binding and therefore different modes of graphic representation and calculation are discussed, including the recent »proportion graph« method.


1997 ◽  
Vol 62 (10) ◽  
pp. 1511-1526
Author(s):  
María-Luisa Alcaraz ◽  
Ángela Molina

A theoretical study of the potential-time response to sinusoidal current applied to static and dynamic electrodes for regeneration processes is presented. Methods for determination of the regeneration fraction, rate constant of the chemical reaction and heterogeneous kinetic parameters are proposed.


1991 ◽  
Vol 32 (8) ◽  
pp. 1311-1323
Author(s):  
KG Parhofer ◽  
P Hugh ◽  
R Barrett ◽  
DM Bier ◽  
G Schonfeld

Sign in / Sign up

Export Citation Format

Share Document