Separation of Mixtures of Benzene and n-Alkanes Using an FAU-Type Zeolite Membrane

2002 ◽  
Vol 35 (2) ◽  
pp. 167-172 ◽  
Author(s):  
Byeong-Heon Jeong ◽  
Yasuhisa Hasegawa ◽  
Ken-Ichiro Sotowa ◽  
Katsuki Kusakabe ◽  
Shigeharu Morooka
Membranes ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 249
Author(s):  
Yasuhisa Hasegawa ◽  
Chie Abe ◽  
Mayumi Natsui ◽  
Ayumi Ikeda

The polycrystalline CHA-type zeolite layer with Si/Al = 18 was formed on the porous α-Al2O3 tube in this study, and the gas permeation properties were determined using single-component H2, CO2, N2, CH4, n-C4H10, and SF6 at 303–473 K. The membrane showed permeation behavior, wherein the permeance reduced with the molecular size, attributed to the effect of molecular sieving. The separation performances were also determined using the equimolar mixtures of N2–SF6, CO2–N2, and CO2–CH4. As a result, the N2/SF6 and CO2/CH4 selectivities were as high as 710 and 240, respectively. However, the CO2/N2 selectivity was only 25. These results propose that the high-silica CHA-type zeolite membrane is suitable for the separation of CO2 from CH4 by the effect of molecular sieving.


2007 ◽  
Vol 46 (21) ◽  
pp. 6989-6997 ◽  
Author(s):  
Shuji Himeno ◽  
Toshihiro Tomita ◽  
Kenji Suzuki ◽  
Kunio Nakayama ◽  
Kenji Yajima ◽  
...  

2010 ◽  
Vol 36 (6) ◽  
pp. 545-551 ◽  
Author(s):  
Shuji Himeno ◽  
Kiwamu Takeya ◽  
Shoichi Fujita

2016 ◽  
Vol 505 ◽  
pp. 194-204 ◽  
Author(s):  
Shaowei Yang ◽  
Zishu Cao ◽  
Antonios Arvanitis ◽  
Xinhui Sun ◽  
Zhi Xu ◽  
...  

2014 ◽  
Vol 805 ◽  
pp. 272-278 ◽  
Author(s):  
Antonielly dos S. Barbosa ◽  
Antusia dos S. Barbosa ◽  
Meiry Glaucia F. Rodrigues

Much interest has been aroused in the application in industrial processes using zeolite membrane, due to its crystalline structure, and narrow pore diameters. These features enable the continuous separation of mixtures based on differences in molecular size and shape and also based on different adsorption properties. This paper reports the synthesis of MCM-22 zeolite membrane, using the method of secondary growth. The MCM-22 zeolite was synthesized by the hydrothermal method and characterized by spectroscopy Energy Dispersive X-ray (EDX), X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM).The ceramic support (α-alumina) was prepared using the technique of forming powder and then subjected to the sintering temperature of 1400 °C/1h and characterized by XRD. The zeolite membrane preparation was performed by the method of secondary growth and characterized by XRD, SEM and mercury porosimetry. The obtained zeolite membrane could be confirmed by X-ray diffraction. From, the obtained SEM pictures it was possible to observe the formation of a homogeneous film on the zeolite surface of the ceramic support (α-alumina).


2018 ◽  
Vol 563 ◽  
pp. 460-469 ◽  
Author(s):  
Miaomiao Ji ◽  
Xuechao Gao ◽  
Xuerui Wang ◽  
Yuting Zhang ◽  
Ji Jiang ◽  
...  

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