scholarly journals A practical isotherm equation for adsorption on a heterogeneous surface and its applications to single and mixed gas adsorption on an activated carbon fiber.

1991 ◽  
Vol 24 (3) ◽  
pp. 312-319 ◽  
Author(s):  
Tomoshige Nitta ◽  
Atsushi Yamaguchi ◽  
Nobuyuki Tokunaga ◽  
Takashi Katayama
2011 ◽  
Vol 415-417 ◽  
pp. 1599-1602
Author(s):  
Mei Li ◽  
Yi Luo ◽  
Tao Xie ◽  
Ming Zheng Liang ◽  
Shuang Fei Wang

The adsorption of phenol onto activated carbon fiber (ACF) from aqueous solutions were studied. The adsorption isotherms of phenol onto ACF at 298.15 K,303.15 K and 308.15K follow the Freundlich and Langmuir isotherm equation. The Freundlich model was verified to be the best to describe the adsorption data.Values of ∆G0 for phenol adsorption onto ACF are-8.549、-7.899 and -7.516 kJ•mol-1 at 298.15,303.15and 308.15K , respectively. The values of ∆H0 and ∆S0 are -39.30 kJ•mol-1 and -103.3 J.mol-1.k-1, respectively. The adsorption process is spontaneous and exothermic. Negative △S0 values suggested the randomness of phenol molecules at solid-liquid interface and an decrease in the degree of freedom of the adsorbed species.


2001 ◽  
Vol 11 (PR3) ◽  
pp. Pr3-279-Pr3-286
Author(s):  
X. Dabou ◽  
P. Samaras ◽  
G. P. Sakellaropoulos

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