scholarly journals A study of the initial stage of oil spreading on calm water through methods of both instantaneous and constant rate of oil release.

1983 ◽  
Vol 16 (6) ◽  
pp. 502-507
Author(s):  
TETSUO AKIYAMA ◽  
SATORU MITSUMORI ◽  
TORU TERADA ◽  
KOZO KOIDE
1980 ◽  
Vol 13 (5) ◽  
pp. 417-419 ◽  
Author(s):  
TETSUO AKIYAMA ◽  
TAKAHIRO NISHIOKA ◽  
HIROMI BABA ◽  
SATORU MITSUMORI ◽  
Kozo KOIDE

2003 ◽  
Vol 21 (4) ◽  
pp. 363-371 ◽  
Author(s):  
Krzysztof Babeł

The isothermal oxidation of regenerated cellulose carbon fibres in the presence of CO2 or steam was described, together with the changes in the porous structures of the active fibres that evolve during different stages of the process. Three such stages were defined. In the initial stage of heating and out-gassing, changes in the porous structure were related to the violent pyrolysis that occurred. As a result, a considerable number of micropores (accessible to nitrogen) were generated together with a small number of mesopores. The next stage (principal activation stage) involved burning at a constant rate accompanied by an uniform increase in the micropore volume. In the third stage, an increased rate of oxidation was observed. This was accompanied by the development of transitional pores linked with the simultaneous limitation of micropore evolution. This stage was not efficient.


Processes ◽  
2019 ◽  
Vol 7 (10) ◽  
pp. 746 ◽  
Author(s):  
Faiz Mahdi ◽  
Timothy Hunter ◽  
Richard Holdich

The minerals calcium carbonate and talc were filtered under various conditions of filtrate flow rate and suspension concentration, using constant rate conditions with the aid of a peristaltic pump to draw the filtrate. Cake concentrations of between 0.41 and 0.53 v/v for calcium carbonate and 0.19 and 0.26 v/v for talc were recorded. The mean sizes of the two different minerals were very similar, but the average specific resistances obtained from the experiments were 5.9 × 1010 and 7.4 × 1011 m/kg for calcium carbonate and talc, respectively. These results do not agree with what would be predicted from an analytical equation for permeability, such as Kozeny-Carman. In addition, discontinuities were observed in all cases on the curves of filtrate volume with time for the initial stage of filtration. This behaviour is attributed to retarded packing compressibility (RPC) complicating the analysis of the filter medium resistance. RPC is an important component in determining the filter cake resistance and its functionality with cake forming pressure. It is found that there are additional effects that enhance the resistance to permeation in different cake materials, which is not recognised in the standard analytical approaches. These complexities can be related to shape, polydispersity, or agglomeration within the material sample and not to the experimental equipment or procedure. Furthermore, a complete and straightforward methodology is presented in this work for investigating the significance, or otherwise, of medium resistance on the later stages of the filtration.


The flow of lead of different purities under conditions of simple shear has been investigated over a wide range of strain, at different stresses, and mostly at a temperature in the neighbourhood of 27 °C. The phenomena have been studied both with unchanged direction of stress and with the direction of stress reversed during flow. At the beginning of forward creep the t 1/3 law is strictly obeyed, within a range of strain which is determined by the purity and grain size of the lead. The region within which the t 1/3 law holds, here called stage F I, is succeeded by stage F II, during which the strain increases according to a logarithmic law, the creep rate being proportional to the increase in strain. In stage F III, which begins at a strain of about 0.3, the creep is strictly linear until the strain approaches 2.0, when rupture starts. If the stress be reversed while stage F I is in progress a creep linear with time takes place, at a rate which is twice that of the forward creep at the moment of reversal, and this constant rate continues for a time equal to that of the forward creep. This initial stage R 0 is succeeded by a stage R I which is also governed by a t 1/3 law, the constant multiplying t 1/3 being proportional to that for stage F I at the same stress. This is followed by a stage R II in which the creep rate increases according to the same law which prevailed for stage F II, and this in turn is followed by a linear stage R III characterized by the same constant creep rate as F III. If the stress be reversed at a strain so large that the t 1/3 law has ceased to be valid, the reverse creep stages are markedly affected, which emphasizes the physical significance of the t 1/3 law. A law of corresponding times is enunciated, which connects the flow in stages R 0 and R I with that in stage F I. Photomicrographs and back-reflexion X-ray photographs have shown that the t 1/3 flow is accompanied by progressive slip in the grains and local rotation of the lattice, and that in the R 0 stage slip takes place on the same slip bands as were active in the F I stage. Recrystallization and grain growth occur during stages F II and R II. In stages F III and R III there is a balance between grain break-up and grain growth, and the slip direction shows a preference for the directions of principal stresses. By considering the variation of strain rate with stress and temperature in stage III, constants have been derived which indicate that the flow in this quasi- viscous stage resembles that of a single crystal far more than that of a polycrystalline metal. The general implications of the experimental findings are discussed.


Author(s):  
M. M. Burakov

The methodical aspects of the processing and interpreting the results of the experimental filtration tests of the layered strata by the constant-rate pumping tests have been developed. Determination of the filtration and volumetric characteristics of the tested pressure aquifer has been proposed on the basis of the author's method based on the results of tracking the drawdown of the piezometric level of the groundwater in the wells of the experimental cluster at the initial stage of the pumping. Methods for interpreting the experimental data of the second and third stages of the constant-rate pumping test for the calculation of the flow parameters have been proposed.


1970 ◽  
Vol 9 (2) ◽  
pp. 261-265 ◽  
Author(s):  
William Kozicki ◽  
A. R. K. Rao ◽  
Carlos Tiu

Entropy ◽  
2018 ◽  
Vol 20 (8) ◽  
pp. 550 ◽  
Author(s):  
Rainer Hollerbach ◽  
Donovan Dimanche ◽  
Eun-jin Kim

We elucidate the effect of different deterministic nonlinear forces on geometric structure of stochastic processes by investigating the transient relaxation of initial PDFs of a stochastic variable x under forces proportional to -xn (n=3,5,7) and different strength D of δ-correlated stochastic noise. We identify the three main stages consisting of nondiffusive evolution, quasi-linear Gaussian evolution and settling into stationary PDFs. The strength of stochastic noise is shown to play a crucial role in determining these timescales as well as the peak amplitude and width of PDFs. From time-evolution of PDFs, we compute the rate of information change for a given initial PDF and uniquely determine the information length L(t) as a function of time that represents the number of different statistical states that a system evolves through in time. We identify a robust geodesic (where the information changes at a constant rate) in the initial stage, and map out geometric structure of an attractor as L(t→∞)∝μm, where μ is the position of an initial Gaussian PDF. The scaling exponent m increases with n, and also varies with D (although to a lesser extent). Our results highlight ubiquitous power-laws and multi-scalings of information geometry due to nonlinear interaction.


Author(s):  
D.W. Susnitzky ◽  
S.R. Summerfelt ◽  
C.B. Carter

Solid-state reactions have traditionally been studied in the form of diffusion couples. This ‘bulk’ approach has been modified, for the specific case of the reaction between NiO and Al2O3, by growing NiAl2O4 (spinel) from electron-transparent Al2O3 TEM foils which had been exposed to NiO vapor at 1415°C. This latter ‘thin-film’ approach has been used to characterize the initial stage of spinel formation and to produce clean phase boundaries since further TEM preparation is not required after the reaction is completed. The present study demonstrates that chemical-vapor deposition (CVD) can be used to deposit NiO particles, with controlled size and spatial distributions, onto Al2O3 TEM specimens. Chemical reactions do not occur during the deposition process, since CVD is a relatively low-temperature technique, and thus the NiO-Al2O3 interface can be characterized. Moreover, a series of annealing treatments can be performed on the same sample which allows both Ni0-NiAl2O4 and NiAl2O4-Al2O3 interfaces to be characterized and which therefore makes this technique amenable to kinetics studies of thin-film reactions.


Author(s):  
H. Bethge

Besides the atomic surface structure, diverging in special cases with respect to the bulk structure, the real structure of a surface Is determined by the step structure. Using the decoration technique /1/ it is possible to image step structures having step heights down to a single lattice plane distance electron-microscopically. For a number of problems the knowledge of the monatomic step structures is important, because numerous problems of surface physics are directly connected with processes taking place at these steps, e.g. crystal growth or evaporation, sorption and nucleatlon as initial stage of overgrowth of thin films.To demonstrate the decoration technique by means of evaporation of heavy metals Fig. 1 from our former investigations shows the monatomic step structure of an evaporated NaCI crystal. of special Importance Is the detection of the movement of steps during the growth or evaporation of a crystal. From the velocity of a step fundamental quantities for the molecular processes can be determined, e.g. the mean free diffusion path of molecules.


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