scholarly journals Coordination of Sodium Cation to an Oxygen Function and Olefinic Double Bond to Form Molecular Adduct Ion in Fast Atom Bombardment Mass Spectrometry

2002 ◽  
Vol 50 (7) ◽  
pp. 935-940 ◽  
Author(s):  
Naoko Morisaki ◽  
Hisayoshi Kobayashi ◽  
Yumiko Yamamura ◽  
Masuo Morisaki ◽  
Kazuo Nagasawa ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Double Bond ◽  
Fast Atom Bombardment ◽  
Sodium Cation ◽  
Molecular Adduct ◽  
Olefinic Double Bond

TRIGLYCERIDE COMPOSITION OF SIXTEEN STRAINS OF MARINE DIATOM

2013 ◽  
Vol 5 (1) ◽  
Author(s):  
Lily M.G. Panggabean ◽  
Abdullah Rasyid ◽  
Zarrah Duniani ◽  
Yana Meliana ◽  
Indah Kurniasih
Keyword(s):  
Mass Spectrometry ◽  
Fatty Acid ◽  
Double Bond ◽  
Unsaturated Fatty Acid ◽  
Ion Trap ◽  
Carbon Chain ◽  
Highly Unsaturated Fatty Acid ◽  
Marine Diatom ◽  
Ion Trap Mass Spectrometry ◽  
Spectra Analysis

Trigliceride or triacylglicerol (TAG) composition in crude oil of sixteen strain of marine diatom has been detected by spectra analyses on an Electrospray - Ion Trap – Mass Spectrometry (ESI-IT-MS) HCT Bruker-Daltonic GmbH instrument with AgNO3 used as coordination ionization agent. Biomass samples of each microalga strain were taken from early and late stationary cultures in f/2 enriched seawater and algal oils were extracted according to Bligh and Dyer. Results from spectra analysis showed that P-Pt-P (C16:0-C16:1-C16:0) were distinguished in TAG from diatom strains Chaetoceros sp.1, Chaetoceros sp.2, Thalasiossira sp.1, Thalasiossira sp.2, Thalasiossira sp.3, Navicula sp. 1, Navicula sp. 2, Navicula sp. 3, Navicula sp. 4, Nitzschia sp. 2 and Amphora sp. In contrast, TAGs in Melosira sp. included P-P-P (C16:0-C16:0-C16:0) and P-P-O (C16:0-C16:0-C18:1) were identified. TAGs from Chaetoceros sp. were the most varies among samples, i.e. P-Pt-P (C16:0-C16:1-C16:0), A-P-M (C20:4-C16:0-C14:0), P-Pt-Lt (C16:0-C16:1-C18:3), P-Pt-A (C16:0-C16:1-C20:4), D-P-P (C22:6-C16:0-C16:0), A-Ln-P (C20:4-C18:2-C16:0). Various TAGs were also detected in Nitzschia sp.2, i.e. P-Pt-M (C16:0-C16:1-C14:0), P-Pt-P (C16:0-C16:1-C16:0), P-Pt-S (C16:0-C16:1-C18:0), P-Pt-A (C16:0-C16:1-C20:4). TAGs composition in Skeletonema strains that similar to those in Nitzschia sp.1 has longer carbon, i.e. P-P-O (C16:0-C16:0-C18:1), P-O-O (C16:0-C18:1-C18:1) and O-O-O (C18:1-C18:1-C18:1). TAGs with longer carbon chain and more double bond including highly unsaturated fatty acid C20:4 were increased with culture age in diatoms Chaetoceros sp.1, Chaetoceros sp.2, Thalasiossira sp.2, Navicula sp.1 and Nitzschia sp. 2.Keywords: diatom, TAG, ESI-IT-MS, f/2, early and late stationary

Effects of Doping on the Electrochemical and Electrical Properties of Poly(2,5-di(2-thienyl)pyrrole)

1999 ◽  
Vol 64 (8) ◽  
pp. 1357-1368 ◽  
Author(s):  
Enric Brillas ◽  
José Carrasco ◽  
Ramon Oliver ◽  
Francesc Estrany ◽  
Víctor Ruiz
Keyword(s):  
Mass Spectrometry ◽  
Fast Atom Bombardment ◽  
Oxidation Potential ◽  
Ethanolic Solution ◽  
Pt Electrode ◽  
Reversible Process ◽  
Oxidation Potentials ◽  
Lower Productivity ◽  
Polymeric Chains ◽  
Linear Molecules

The electropolymerization of 2,5-di(2-(thienyl)pyrrole) (SNS) on a Pt electrode from ethanolic solution with LiClO4 or LiCl as electrolyte has been studied by cyclic voltammetry (CV) and chronoamperometry (CA). In both media, a quasi-reversible process has been indicated by CV, reversing the scan at low oxidation potentials. Under these conditions, reducible positive charges formed in both oxidized polymers are compensated by the entrance of anions from solution. Elemental analysis reveals that polymers generated at a low oxidation potential by CA contain a 21.03% (w/w) of ClO4- or a 9.56% (w/w) of Cl-. The poly(SNS) doped with Cl- presents higher proportion of reducible positive charges, higher polymerization charge and lower productivity. A much higher electrical conductivity, however, has been found for the poly(SNS) doped with ClO4-. Both polymers are soluble in DMSO, acetone and methanol. The dimer, trimer, tetramer and pentamer have been detected as soluble and neutral linear oligomers by mass spectrometry-fast atom bombardment. The analysis of polymers by infrared spectroscopy confirms the predominant formation of linear molecules with α-α linkages between monomeric units. A condensation mechanism involving one-electron oxidation of all electrogenerated linear and neutral polymeric chains is proposed to explain the SNS electropolymerization.

scholarly journals A revised primary structure for neocarzinostatin based on fast atom bombardment and gas chromatographic-mass spectrometry.

1984 ◽  
Vol 259 (17) ◽  
pp. 10801-10806
Author(s):  
B W Gibson ◽  
W C Herlihy ◽  
T S Samy ◽  
K S Hahm ◽  
H Maeda ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Primary Structure ◽  
Fast Atom Bombardment ◽  
Chromatographic Mass

scholarly journals Assignment of disulfide bonds in proteins by fast atom bombardment mass spectrometry.

1987 ◽  
Vol 262 (6) ◽  
pp. 2507-2513
Author(s):  
R. Yazdanparast ◽  
P.C. Andrews ◽  
D.L. Smith ◽  
J.E. Dixon
Keyword(s):  
Mass Spectrometry ◽  
Disulfide Bonds ◽  
Fast Atom Bombardment

scholarly journals Proton NMR and fast-atom bombardment mass spectrometry analysis of the melanoma-associated ganglioside 9-O-acetyl-GD3.

1985 ◽  
Vol 260 (27) ◽  
pp. 14556-14563 ◽  
Author(s):  
J Thurin ◽  
M Herlyn ◽  
O Hindsgaul ◽  
N Strömberg ◽  
K A Karlsson ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Fast Atom Bombardment ◽  
Proton Nmr ◽  
Mass Spectrometry Analysis ◽  
Spectrometry Analysis

Fast atom bombardment mass spectrometry of new polydentate Schiff bases. 3. The case of mono- and bis aldimine containing benzo-5-crown-5 groups

1995 ◽  
Vol 1 (1) ◽  
pp. 65 ◽  
Author(s):  
Elvio Bullita ◽  
Sergio Tamburini ◽  
Pietro Vigato ◽  
Massimo Carbini ◽  
Silvia Catinella ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Schiff Bases ◽  
Fast Atom Bombardment

Coaxial continuous flow fast atom bombardment in conjunction with tandem mass spectrometry for the analysis of biomolecules

1989 ◽  
Vol 61 (22) ◽  
pp. 2504-2511 ◽  
Author(s):  
Leesa J. Deterding ◽  
M. Arthur. Moseley ◽  
Kenneth B. Tomer ◽  
James W. Jorgenson
Keyword(s):  
Mass Spectrometry ◽  
Tandem Mass Spectrometry ◽  
Continuous Flow ◽  
Fast Atom Bombardment ◽  
Tandem Mass
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