scholarly journals Studies of reduction with the sodium borohydride-transition metal boride system. I. Reduction of nitro and the other functional groups with the sodium borohydride-nickel boride system.

1988 ◽  
Vol 36 (4) ◽  
pp. 1529-1533 ◽  
Author(s):  
ASTUKO NOSE ◽  
TADAHIRO KUDO
Keyword(s):  
Transition Metal ◽  
Functional Groups ◽  
Sodium Borohydride ◽  
The Other ◽  
Metal Boride ◽  
Nickel Boride

Electroless Plating of Transition Metal Boride with High Boron Content as Superior HER Electrocatalyst

ChemCatChem ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 3068-3075 ◽  
Author(s):  
Ruiqi Zhang ◽  
Huixiang Liu ◽  
Chenfeng Wang ◽  
Lincai Wang ◽  
Yanjing Yang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Electroless Plating ◽  
Boron Content ◽  
Metal Boride ◽  
High Boron

scholarly journals Comparative Study of Ag Nanostructures: Molecular Simulations, Electrochemical Behavior, and Antibacterial Effect

2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Álvaro de Jesús Ruíz-Baltazar ◽  
Simón Yobanny Reyes-López ◽  
D. Larrañaga ◽  
R. Pérez
Keyword(s):  
Cyclic Voltammetry ◽  
Ethylene Glycol ◽  
Comparative Study ◽  
Sodium Borohydride ◽  
Electrochemical Behavior ◽  
Antibacterial Effect ◽  
Chemical Reduction ◽  
Molecular Simulations ◽  
The Other ◽  
E Coli

Nanoparticles of Ag with different sizes and structures were obtained and studied. Two methods for reductions of Ag ions were employed, chemical reduction by sodium borohydride and ethylene glycol. Cuboctahedral and icosahedral structures were obtained. Molecular simulations were carried out in order to evaluate the reactivity of both structures. On the other hand, the electrochemical activity and antibacterial effect (E. coli) of the cuboctahedral and icosahedral structures were measured experimentally. The results obtained by molecular simulation, cyclic voltammetry, and antibacterial effect were compared and discussed in this work.

Deuterative cyclization of sulfanyl 1,6-diynes: complete and monodeuteration of functional groups on heterocycles

2015 ◽  
Vol 2 (3) ◽  
pp. 201-205 ◽  
Author(s):  
Yukiteru Ito ◽  
Mitsuhiro Yoshimatsu
Keyword(s):  
Transition Metal ◽  
Exchange Reaction ◽  
Functional Groups ◽  
Reductive Cyclization ◽  
Metal Free ◽  
Sodium Borodeuteride

Regioselective H/D exchange reaction of functional groups on heterocycles proceeded via a transition metal-free reductive cyclization of sulfanyl 1,6-diynes using sodium borodeuteride/ethanol-D1.

scholarly journals Unsymmetrical Difunctionalization of Two Different C–H Bonds in One Pot Under Transition-Metal Catalysis

Synthesis ◽  
2018 ◽  
Vol 51 (01) ◽  
pp. 40-54 ◽  
Author(s):  
Masahito Murai ◽  
Kazuhiko Takai
Keyword(s):  
Transition Metal ◽  
Functional Groups ◽  
Aromatic Compounds ◽  
Transition Metal Catalysis ◽  
One Pot ◽  
Metal Catalysis ◽  
Selective Functionalization ◽  
Sequential Addition ◽  
Target Molecules ◽  
Directing Group

Recent advancements in unsymmetrical difunctionalization based on the substitution of two different C–H bonds in one-pot are described. Due to the difficulty of controlling reactivity and selectivity, multi-functionalization via substitution of several C–H bonds to install different functional groups has been limited until recently, in comparison with well-studied functionalization via sequential addition to unsaturated π-bonds. This difunctionalization protocol provides an efficient and rapid approach to a library of structurally complicated target molecules through the formation of multiple C–X bonds with high atom- and step-economy.1 Introduction2 ortho-Selective Functionalization of Two Different C–H Bonds Relative to the Directing Group2.1 Unsymmetrical Difunctionalization with the Introduction of Similar Functional Groups2.2 Unsymmetrical Difunctionalization with the Introduction of Different Functional Groups2.3 ortho-Selective Unsymmetrical Difunctionalization Promoted by Two Different Directing Groups Appearing During the Progress of the Reaction3 ortho/meta-Selective C–H Bond Difunctionalization Relative to the Directing Group4 Sequential Difunctionalization of Fused Aromatic Compounds and Heterocycles5 Summary and Outlook

Linearly Two-Coordinated Silicon: Transition Metal Complexes with the Functional Groups M≡Si—M and M═Si═M

2018 ◽  
Vol 140 (23) ◽  
pp. 7187-7198 ◽  
Author(s):  
Priyabrata Ghana ◽  
Marius I. Arz ◽  
Uttam Chakraborty ◽  
Gregor Schnakenburg ◽  
Alexander C. Filippou
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Functional Groups ◽  
Transition Metal Complexes
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