Nature of Local Charge Carrier Motions in Porphyrin-Based Bulk Heterojunction Films Revealed by Time-Resolved Optical Pump-Terahertz Probe Spectroscopy

2021 ◽  
Author(s):  
Kaoru Ohta ◽  
Yuichi Hiramatsu ◽  
Mitsuharu Suzuki ◽  
Hiroko Yamada ◽  
Keisuke Tominaga
Keyword(s):  
Charge Carrier ◽  
Bulk Heterojunction ◽  
Optical Pump ◽  
Time Resolved ◽  
Local Charge ◽  
Probe Spectroscopy

Limits of Charge Carrier Transport in Halide Perovskites Revealed by Optical-Pump Terahertz-Probe Spectroscopy

2019 ◽  
Author(s):  
Hannes Hempel ◽  
Andrei Petsiu ◽  
Martin Stolterfoht ◽  
Pascal Becker ◽  
Dieter Neher ◽  
...  
Keyword(s):  
Charge Carrier ◽  
Carrier Transport ◽  
Charge Carrier Transport ◽  
Optical Pump ◽  
Halide Perovskites ◽  
Probe Spectroscopy

Dirac Surface Plasmons in Photoexcited Bismuth Telluride Nanowires : Optical Pump-Terahertz Probe Spectroscopy

Nanoscale ◽  
2021 ◽  
Author(s):  
Mithun K P ◽  
Srabani Kar ◽  
Abinash Kumar ◽  
Victor Suvisesha Muthu Dharmaraj ◽  
Ravishankar Narayanan ◽  
...  
Keyword(s):  
Surface Plasmons ◽  
Bismuth Telluride ◽  
Topological Insulators ◽  
Collective Excitation ◽  
Optical Pump ◽  
Time Resolved ◽  
Mid Infrared ◽  
Plasmonic Materials ◽  
Probe Spectroscopy

Collective excitation of Dirac plasmons in graphene and topological insulators have opened new possibilities of tunable plasmonic materials ranging from THz to mid-infrared regions. Using time resolved Optical Pump -...

scholarly journals Phase segregation in mixed-halide perovskites affects charge-carrier dynamics while preserving mobility

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Silvia G. Motti ◽  
Jay B. Patel ◽  
Robert D. J. Oliver ◽  
Henry J. Snaith ◽  
Michael B. Johnston ◽  
...  
Keyword(s):  
Solar Cells ◽  
Charge Carrier ◽  
Management Strategies ◽  
Phase Segregation ◽  
Carrier Dynamics ◽  
Optical Pump ◽  
Charge Carrier Dynamics ◽  
Halide Perovskites ◽  
Probe Spectroscopy ◽  
The Impact

AbstractMixed halide perovskites can provide optimal bandgaps for tandem solar cells which are key to improved cost-efficiencies, but can still suffer from detrimental illumination-induced phase segregation. Here we employ optical-pump terahertz-probe spectroscopy to investigate the impact of halide segregation on the charge-carrier dynamics and transport properties of mixed halide perovskite films. We reveal that, surprisingly, halide segregation results in negligible impact to the THz charge-carrier mobilities, and that charge carriers within the I-rich phase are not strongly localised. We further demonstrate enhanced lattice anharmonicity in the segregated I-rich domains, which is likely to support ionic migration. These phonon anharmonicity effects also serve as evidence of a remarkably fast, picosecond charge funnelling into the narrow-bandgap I-rich domains. Our analysis demonstrates how minimal structural transformations during phase segregation have a dramatic effect on the charge-carrier dynamics as a result of charge funnelling. We suggest that because such enhanced recombination is radiative, performance losses may be mitigated by deployment of careful light management strategies in solar cells.

Probing Photoexcited Carriers in a Few-Layer MoS2 Laminate by Time-Resolved Optical Pump–Terahertz Probe Spectroscopy

ACS Nano ◽  
2015 ◽  
Vol 9 (12) ◽  
pp. 12004-12010 ◽  
Author(s):  
Srabani Kar ◽  
Y. Su ◽  
R. R. Nair ◽  
A. K. Sood
Keyword(s):  
Optical Pump ◽  
Time Resolved ◽  
Probe Spectroscopy
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