Tin halide perovskite polycrystalline films formed with nonhazardous 2-propanol solvent

2021 ◽  
Author(s):  
Atsushi Kogo ◽  
Masayuki Chikamatsu
Keyword(s):  
Polycrystalline Films ◽  
Halide Perovskite

scholarly journals High optical nonlinearity in low-dimensional halide perovskite polycrystalline films

2020 ◽  
Vol 28 (17) ◽  
pp. 24919 ◽  
Author(s):  
Wei-Yun Liang ◽  
Fangzhou Liu ◽  
Yu-Jung Lu ◽  
Jasminka Popović ◽  
Aleksandra Djurišić ◽  
...  
Keyword(s):  
Optical Nonlinearity ◽  
Polycrystalline Films ◽  
Halide Perovskite ◽  
Low Dimensional

scholarly journals Interpretation of the photoluminescence decay kinetics in metal halide perovskite nanocrystals and thin polycrystalline films

2020 ◽  
Vol 221 ◽  
pp. 117092 ◽  
Author(s):  
Vladimir S. Chirvony ◽  
Kairolla S. Sekerbayev ◽  
Hamid Pashaei Adl ◽  
Isaac Suárez ◽  
Yerzhan T. Taurbayev ◽  
...  
Keyword(s):  
Metal Halide ◽  
Polycrystalline Films ◽  
Decay Kinetics ◽  
Perovskite Nanocrystals ◽  
Photoluminescence Decay ◽  
Metal Halide Perovskite ◽  
Halide Perovskite ◽  
Thin Polycrystalline

scholarly journals Imperfections and their passivation in halide perovskite solar cells

2019 ◽  
Vol 48 (14) ◽  
pp. 3842-3867 ◽  
Author(s):  
Bo Chen ◽  
Peter N. Rudd ◽  
Shuang Yang ◽  
Yongbo Yuan ◽  
Jinsong Huang
Keyword(s):  
Solar Cells ◽  
Radiative Recombination ◽  
Perovskite Solar Cells ◽  
High Density ◽  
Polycrystalline Films ◽  
Ion Migration ◽  
Device Stability ◽  
Device Efficiency ◽  
Halide Perovskite ◽  
Improve Device

Perovskite solar cells to date are made of polycrystalline films which contain a high density of defects. Imperfection passivation to reduce non-radiative recombination and suppress ion migration could improve device efficiency and device stability.

scholarly journals Metal Halide Perovskite Polycrystalline Films Exhibiting Properties of Single Crystals

Joule ◽  
2017 ◽  
Vol 1 (1) ◽  
pp. 155-167 ◽  
Author(s):  
Roberto Brenes ◽  
Dengyang Guo ◽  
Anna Osherov ◽  
Nakita K. Noel ◽  
Christopher Eames ◽  
...  
Keyword(s):  
Single Crystals ◽  
Metal Halide ◽  
Polycrystalline Films ◽  
Metal Halide Perovskite ◽  
Halide Perovskite

A thiourea additive-based quadruple cation lead halide perovskite with an ultra-large grain size for efficient perovskite solar cells

Nanoscale ◽  
2019 ◽  
Vol 11 (45) ◽  
pp. 21824-21833 ◽  
Author(s):  
Jyoti V. Patil ◽  
Sawanta S. Mali ◽  
Chang Kook Hong
Keyword(s):  
Thin Films ◽  
Grain Size ◽  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Power Conversion ◽  
Perovskite Solar Cells ◽  
Inorganic Perovskite ◽  
Halide Perovskite ◽  
Lead Halide

Controlling the grain size of the organic–inorganic perovskite thin films using thiourea additives now crossing 2 μm size with >20% power conversion efficiency.

Intrinsic doping limit and defect-assisted luminescence in Cs4PbBr6

2019 ◽  
Author(s):  
Young-Kwang Jung ◽  
Joaquin Calbo ◽  
Ji-Sang Park ◽  
Lucy D. Wahlley ◽  
Sunghyun Kim ◽  
...  
Keyword(s):  
First Principles ◽  
Room Temperature ◽  
Stokes Shift ◽  
Green Luminescence ◽  
Counter Ions ◽  
Self Consistent ◽  
Deep Ultraviolet ◽  
Halide Perovskite ◽  
Related Compounds ◽  
Level Analysis

Cs<sub>4</sub>PbBr<sub>6 </sub>is a member of the halide perovskite family that is built from isolated (zero-dimensional) PbBr<sub>6</sub><sup>4-</sup> octahedra with Cs<sup>+</sup> counter ions. The material exhibits anomalous optoelectronic properties: optical absorption and weak emission in the deep ultraviolet (310 - 375 nm) with efficient luminescence in the green region (~ 540 nm). Several hypotheses have been proposed to explain the giant Stokes shift including: (i) phase impurities; (ii) self-trapped exciton; (iii) defect emission. We explore, using first-principles theory and self-consistent Fermi level analysis, the unusual defect chemistry and physics of Cs<sub>4</sub>PbBr<sub>6</sub>. We find a heavily compensated system where the room-temperature carrier concentrations (< 10<sup>9</sup> cm<sup>-3</sup>) are more than one million times lower than the defect concentrations. We show that the low-energy Br-on-Cs antisite results in the formation of a polybromide (Br<sub>3</sub>) species that can exist in a range of charge states. We further demonstrate from excited-state calculations that tribromide moieties are photoresponsive and can contribute to the observed green luminescence. Photoactivity of polyhalide molecules is expected to be present in other halide perovskite-related compounds where they can influence light absorption and emission. <br>

Intrinsic doping limit and defect-assisted luminescence in Cs4PbBr6

2019 ◽  
Author(s):  
Young-Kwang Jung ◽  
Joaquin Calbo ◽  
Ji-Sang Park ◽  
Lucy D. Wahlley ◽  
Sunghyun Kim ◽  
...  
Keyword(s):  
First Principles ◽  
Room Temperature ◽  
Stokes Shift ◽  
Green Luminescence ◽  
Counter Ions ◽  
Self Consistent ◽  
Deep Ultraviolet ◽  
Halide Perovskite ◽  
Related Compounds ◽  
Level Analysis

Cs<sub>4</sub>PbBr<sub>6 </sub>is a member of the halide perovskite family that is built from isolated (zero-dimensional) PbBr<sub>6</sub><sup>4-</sup> octahedra with Cs<sup>+</sup> counter ions. The material exhibits anomalous optoelectronic properties: optical absorption and weak emission in the deep ultraviolet (310 - 375 nm) with efficient luminescence in the green region (~ 540 nm). Several hypotheses have been proposed to explain the giant Stokes shift including: (i) phase impurities; (ii) self-trapped exciton; (iii) defect emission. We explore, using first-principles theory and self-consistent Fermi level analysis, the unusual defect chemistry and physics of Cs<sub>4</sub>PbBr<sub>6</sub>. We find a heavily compensated system where the room-temperature carrier concentrations (< 10<sup>9</sup> cm<sup>-3</sup>) are more than one million times lower than the defect concentrations. We show that the low-energy Br-on-Cs antisite results in the formation of a polybromide (Br<sub>3</sub>) species that can exist in a range of charge states. We further demonstrate from excited-state calculations that tribromide moieties are photoresponsive and can contribute to the observed green luminescence. Photoactivity of polyhalide molecules is expected to be present in other halide perovskite-related compounds where they can influence light absorption and emission. <br>

Hollow Metal Halide Perovskite Nanocrystals with Efficient Blue Emissions

2019 ◽  
Author(s):  
Michael Worku ◽  
Yu Tian ◽  
Chenkun Zhou ◽  
Haoran Lin ◽  
Maya Chaaban ◽  
...  
Keyword(s):  
Precursor Solution ◽  
Visible Spectral Region ◽  
Metal Halide ◽  
Synthetic Control ◽  
Perovskite Nanocrystals ◽  
Highly Efficient ◽  
Quantum Confinement Effects ◽  
Metal Halide Perovskite ◽  
Lead Bromide ◽  
Halide Perovskite

Metal halide perovskite nanocrystals (NCs) have emerged as a new generation light emitting materials with narrow emissions and high photoluminescence quantum efficiencies (PLQEs). Various types of perovskite NCs, e.g. platelets, wires, and cubes, have been discovered to exhibit tunable emissions across the whole visible spectral region. Despite remarkable advances in the field of metal halide perovskite NCs over the last few years, many nanostructures in inorganic NCs have yet been realized in metal halide perovskites and producing highly efficient blue emitting perovskite NCs remains challenging and of great interest. Here we report for the first time the discovery of highly efficient blue emitting cesium lead bromide perovskite (CsPbBr3) NCs with hollow structures. By facile solution processing of cesium lead bromide perovskite precursor solution containing additional ethylenediammonium bromide and sodium bromide, in-situ formation of hollow CsPbBr3 NCs with controlled particle and pore sizes is realized. Synthetic control of hollow nanostructures with quantum confinement effects results in color tuning of CsPbBr3 NCs from green to blue with high PLQEs of up to 81 %.<br><div><br></div>

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