A Cyanido-bridged Luminescent Coordination Polymer composed of Janus-type Layers and its Two-dimensional Negative Thermal Expansion

2021 ◽  
Author(s):  
Kenta Sasaki ◽  
Haruka Yoshino ◽  
Jingo Kitano ◽  
Benjamin Le Ouay ◽  
Ryo Ohtani ◽  
...  
Keyword(s):  
Thermal Expansion ◽  
Coordination Polymer ◽  
Negative Thermal Expansion ◽  
Two Dimensional

Magnetoelastic coupling, negative thermal expansion, and two-dimensional magnetic excitations in FeAs

2021 ◽  
Vol 103 (9) ◽  
Author(s):  
J. L. Niedziela ◽  
L. D. Sanjeewa ◽  
A. A. Podlesnyak ◽  
L. DeBeer-Schmitt ◽  
S. J. Kuhn ◽  
...  
Keyword(s):  
Thermal Expansion ◽  
Negative Thermal Expansion ◽  
Two Dimensional ◽  
Magnetic Excitations ◽  
Magnetoelastic Coupling

Thermally boosted upconversion and downshifting luminescence in Sc2(MoO4)3:Yb/Er with two-dimensional negative thermal expansion

2021 ◽  
Author(s):  
Jinsheng Liao ◽  
Minghua Wang ◽  
Fulin Lin ◽  
Zhuo Han ◽  
Datao Tu ◽  
...  
Keyword(s):  
Thermal Expansion ◽  
Near Infrared ◽  
Negative Thermal Expansion ◽  
Thermal Quenching ◽  
Relative Sensitivity ◽  
Strong Temperature Dependence ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Higher Temperature

Abstract Lanthanide (Ln3+)-doped phosphors generally suffer from thermal quenching, in which their photoluminescence (PL) intensities decrease at the higher temperature. Herein, we report a class of unique two-dimensional negative-thermal-expansion phosphor of Sc2(MoO4)3:Yb/Er. By virtue of the reduced distances between sensitizers and emitters as well as confined energy migration with increasing the temperature, a 45-fold enhancement of green upconversion (UC) luminescence and a 450-fold enhancement of near-infrared downshifting (DS) luminescence of Er3+ are achieved from 25 to 500 ˚C. The thermally boosted UC and DS luminescence mechanism is systematically investigated through in situ temperature-dependent Raman spectroscopy, synchrotron X-ray diffraction and PL dynamics. Moreover, the luminescence lifetime of 4I11/2 of Er3+ in Sc2(MoO4)3:Yb/Er displays a strong temperature dependence, enabling ratiometric thermometry with the highest relative sensitivity of 13.4%/K at 298 K. These findings may gain a vital insight into the design of negative-thermal-expansion Ln3+-doped phosphors for versatile applications.

scholarly journals Eu(O 2 C‐C≡C‐CO 2 ): An Eu II Containing Anhydrous Coordination Polymer with High Stability and Negative Thermal Expansion

2020 ◽  
Vol 26 (12) ◽  
pp. 2726-2734
Author(s):  
Verena K. Gramm ◽  
Daniel Smets ◽  
Ireneus Grzesiak ◽  
Theresa Block ◽  
Rainer Pöttgen ◽  
...  
Keyword(s):  
Thermal Expansion ◽  
Coordination Polymer ◽  
High Stability ◽  
Negative Thermal Expansion

CDW-induced negative thermal expansion in two-dimensional conductor η-Mo4O11

2003 ◽  
Vol 125 (1) ◽  
pp. 45-49 ◽  
Author(s):  
Hiroshi Negishi ◽  
Yoshihiro Kuroiwa ◽  
Hiroyasu Akamine ◽  
Shinobu Aoyagi ◽  
Akikatsu Sawada ◽  
...  
Keyword(s):  
Thermal Expansion ◽  
Negative Thermal Expansion ◽  
Two Dimensional

scholarly journals A system with adjustable positive or negative thermal expansion

2007 ◽  
Vol 463 (2082) ◽  
pp. 1585-1596 ◽  
Author(s):  
Joseph N Grima ◽  
Pierre S Farrugia ◽  
Ruben Gatt ◽  
Victor Zammit
Keyword(s):  
Thermal Expansion ◽  
Thermal Properties ◽  
Negative Thermal Expansion ◽  
Two Dimensional ◽  
Practical Applications ◽  
Anisotropic Thermal Expansion ◽  
Thermal Expansion Coefficients ◽  
Expansion Coefficients

We analyse the anisotropic thermal expansion properties of a two-dimensional structurally rigid construct made from rods of different materials connected together through hinges to form triangular units. In particular, we show that this system may be made to exhibit negative thermal expansion coefficients along certain directions or thermal expansion coefficients that are even more positive than any of the component materials. The end product is a multifunctional system with tunable thermal properties that can be tailor-made for particular practical applications.

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