Selective Hydroxylation of Cyclohexene in Water as an Environment-friendly Solvent with Hydrogen Peroxide over Fe–Bipyridine Encapsulated in Y-type Zeolite

2012 ◽  
Vol 41 (7) ◽  
pp. 713-715 ◽  
Author(s):  
Syuhei Yamaguchi ◽  
Tomohiro Fukura ◽  
Chiharu Fujita ◽  
Hidenori Yahiro
Keyword(s):  
Hydrogen Peroxide ◽  
Environment Friendly ◽  
Type Zeolite ◽  
Selective Hydroxylation

Selective hydroxylation of cyclohexene over Fe-bipyridine complexes encapsulated into Y-type zeolite under environment-friendly conditions

2015 ◽  
Vol 242 ◽  
pp. 261-267 ◽  
Author(s):  
Syuhei Yamaguchi ◽  
Tomohiro Fukura ◽  
Keiko Takiguchi ◽  
Chiharu Fujita ◽  
Maiko Nishibori ◽  
...  
Keyword(s):  
Environment Friendly ◽  
Type Zeolite ◽  
Selective Hydroxylation

An Iron(III)-Monoamidate Complex Catalyst for Selective Hydroxylation of Alkane CH Bonds with Hydrogen Peroxide

2012 ◽  
Vol 51 (14) ◽  
pp. 3448-3452 ◽  
Author(s):  
Yutaka Hitomi ◽  
Kengo Arakawa ◽  
Takuzo Funabiki ◽  
Masahito Kodera
Keyword(s):  
Hydrogen Peroxide ◽  
Complex Catalyst ◽  
Selective Hydroxylation

scholarly journals One-step selective hydroxylation of benzene to phenol with hydrogen peroxide catalysed by copper complexes incorporated into mesoporous silica–alumina

2016 ◽  
Vol 7 (4) ◽  
pp. 2856-2863 ◽  
Author(s):  
Mihoko Yamada ◽  
Kenneth D. Karlin ◽  
Shunichi Fukuzumi
Keyword(s):  
Hydrogen Peroxide ◽  
Mesoporous Silica ◽  
Copper Complexes ◽  
Hydroxylation Of Benzene ◽  
Silica Alumina ◽  
One Step ◽  
Selective Hydroxylation

One-step hydroxylation of benzene with hydrogen peroxide to produce phenol catalyzed by a copper(ii) complex.

Study on TCF Bleaching of Reed Displacement Cooking Pulp

2013 ◽  
Vol 726-731 ◽  
pp. 543-547
Author(s):  
Ting Ting Fan ◽  
Ying Han ◽  
Guang Wei Sun ◽  
Jing Hui Zhou
Keyword(s):  
Hydrogen Peroxide ◽  
Peracetic Acid ◽  
Optimal Conditions ◽  
Experimental Conditions ◽  
Environment Friendly ◽  
Bleaching Process ◽  
Paper Making ◽  
Bleached Pulp ◽  
Method Yield ◽  
Temperature Time

With the improvement of environmental protection requirements, paper-making enterprises are imperative to eliminate pollution directly in production. This paper aims to adopt environment-friendly bleaching method, yield good quality pulp products. Op-Pa-P bleaching process of reed displacement cooking pulp is studied in this paper (O-oxygen, P-hydrogen peroxide, Pa-peracetic acid ). The experimental conditions of Op and Pa stage were optimized respectively. It included oxygen pressure, temperature, time in Op stage and charge of peracetic acid, temperature, time in Pa stage. The results show that the optimal technological conditions of Op are: 0.9Mpa, 100°C, 70min, Op stage can make brightness increase by 57.3%, viscosity decrease by 25% and KMnO4 number reduce to 2.6. Pa stage optimal conditions are Pa charge 1.5%, 70°C, 75min, brightness reached to 79.1 %ISO, KMnO4 number to 1.0, viscosity to 631mL.g-1. The brightness of P bleached pulp reached to 84.8%ISO, viscosity 601 mL.g-1, KMnO4 number 0.8.

scholarly journals Specific Enhancement of Catalytic Activity by a Dicopper Core: Selective Hydroxylation of Benzene to Phenol with Hydrogen Peroxide

2017 ◽  
Vol 56 (27) ◽  
pp. 7779-7782 ◽  
Author(s):  
Tomokazu Tsuji ◽  
Antonius Andre Zaoputra ◽  
Yutaka Hitomi ◽  
Kaoru Mieda ◽  
Takashi Ogura ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Catalytic Activity ◽  
Hydroxylation Of Benzene ◽  
Specific Enhancement ◽  
Selective Hydroxylation

Preparation of Environment-Friendly Epoxidized Corn Oil as a Plasticizer

2014 ◽  
Vol 852 ◽  
pp. 256-261 ◽  
Author(s):  
Yuan Huai Peng ◽  
Hua Di Lin
Keyword(s):  
Hydrogen Peroxide ◽  
Ion Exchange ◽  
Exchange Resin ◽  
Corn Oil ◽  
Ion Exchange Resin ◽  
Molar Ratio ◽  
Environment Friendly ◽  
Percent Conversion ◽  
Optimized Conditions

An environment-friendly plasticizer, epoxidized corn oil was prepared by the epoxidation of corn oil with peroxyacetic acid which was generated in situ from hydrogen peroxide and glacial acetic using acidic ion exchange resin modified by zinc chloride as catalyst. The product with an epoxy oxygen content of 6.40 w% and a percent conversion to oxirane of 87.67 % was obtained under the following optimized conditions: 15 % modified ion exchange resin feed relative to the weight of corn oil, the molar ratio of 1.7 to 1 with hydrogen peroxide to double bonds, 18% acetic acid feed relative to the weight of corn oil, the reaction time of 5.5 h, the temperature of 75 °C and stirring speed of 600 rpm.

Selective hydroxylation of benzene derivatives and alkanes with hydrogen peroxide catalysed by a manganese complex incorporated into mesoporous silica–alumina

2015 ◽  
Vol 51 (22) ◽  
pp. 4662-4665 ◽  
Author(s):  
Yusuke Aratani ◽  
Yusuke Yamada ◽  
Shunichi Fukuzumi
Keyword(s):  
Hydrogen Peroxide ◽  
Mesoporous Silica ◽  
Manganese Complex ◽  
Benzene Derivatives ◽  
Hydroxylation Of Benzene ◽  
Silica Alumina ◽  
Selective Hydroxylation

Selective hydroxylation of benzene to phenol with hydrogen peroxide was efficiently catalysed by a manganese complex incorporated into mesoporous silica–alumina.

Sign in / Sign up

Export Citation Format

Share Document