scholarly journals Rapid Access to 3-Aryltetralin Skeleton via C(sp3)–H Bond Functionalization: Investigation on the Substituent Effect of Aromatic Ring Adjacent to C–H Bond in Hydride Shift/Cyclization Sequence

2011 ◽  
Vol 40 (12) ◽  
pp. 1386-1388 ◽  
Author(s):  
Keiji Mori ◽  
Shosaku Sueoka ◽  
Takahiko Akiyama
Keyword(s):  
Aromatic Ring ◽  
Substituent Effect ◽  
Bond Functionalization ◽  
Rapid Access ◽  
Hydride Shift

ChemInform Abstract: “Aromatic Ring Umpolung”, a Rapid Access to the Main Core of Several Natural Products.

ChemInform ◽  
2010 ◽  
Vol 41 (45) ◽  
pp. no-no
Author(s):  
Kimiaka C. Guerard ◽  
Cyrille Sabot ◽  
Marc-Andre Beaulieu ◽  
Marc-Andre Giroux ◽  
Sylvain Canesi
Keyword(s):  
Natural Products ◽  
Aromatic Ring ◽  
Rapid Access

C–H Bond Functionalization via [1,5]-Hydride Shift/Cyclization Sequence: Approach to Spiroindolenines

2015 ◽  
Vol 80 (2) ◽  
pp. 1155-1162 ◽  
Author(s):  
Peng-Fei Wang ◽  
Chun-Huan Jiang ◽  
Xiaoan Wen ◽  
Qing-Long Xu ◽  
Hongbin Sun
Keyword(s):  
Bond Functionalization ◽  
Hydride Shift

scholarly journals Highly diastereoselective synthesis of tricyclic fused-pyrans by sequential hydride shift mediated double C(sp3)–H bond functionalization

2018 ◽  
Vol 9 (37) ◽  
pp. 7327-7331 ◽  
Author(s):  
Keiji Mori ◽  
Nobuaki Umehara ◽  
Takahiko Akiyama
Keyword(s):  
Bronsted Acid ◽  
Brønsted Acid ◽  
Diastereoselective Synthesis ◽  
Bond Functionalization ◽  
Hydride Shift ◽  
Brönsted Acid ◽  
Acid Catalyzed

Highly diastereoselective synthesis of tricyclic fused-pyrans was achieved by Brønsted acid catalyzed double C(sp3)–H bond functionalization.

Rapid access to 3-indolyl-1-trifluoromethyl-isobenzofurans by hybrid use of Lewis/Brønsted acid catalysts

2020 ◽  
Vol 18 (34) ◽  
pp. 6602-6606
Author(s):  
Daiki Hoshino ◽  
Keiji Mori
Keyword(s):  
Nucleophilic Addition ◽  
Addition Reaction ◽  
Acid Catalysts ◽  
Bronsted Acid ◽  
Reaction Sequence ◽  
Rapid Access ◽  
Hydride Shift ◽  
Brönsted Acid ◽  
Nucleophilic Addition Reaction ◽  
Bronsted Acid Catalysts

Expeditious synthesis of 3-indolyl-1-trifluoromethyl-isobenzofurans via [1,4]-hydride shift/cyclization/intermolecular nucleophilic addition reaction sequence.

scholarly journals New complexity for aromatic ring agostic interactions

2017 ◽  
Vol 53 (30) ◽  
pp. 4187-4190 ◽  
Author(s):  
M. Arif Sajjad ◽  
Kirsten E. Christensen ◽  
Nicholas H. Rees ◽  
Peter Schwerdtfeger ◽  
John A. Harrison ◽  
...  
Keyword(s):  
Aromatic Ring ◽  
Significant Implication ◽  
Bond Functionalization

Aromatic ring agostic interactions can be augmented by previously unrecognised CCπ to metal donation which has significant implication for ligand-assisted C–H bond functionalization.

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