Monovalent Nickel Complex Bearing a BulkyN-Heterocyclic Carbene Catalyzes Buchwald–Hartwig Amination of Aryl Halides under Mild Conditions

2011 ◽  
Vol 40 (9) ◽  
pp. 1036-1038 ◽  
Author(s):  
Shinya Nagao ◽  
Taisuke Matsumoto ◽  
Yuji Koga ◽  
Kouki Matsubara
Keyword(s):  
Nickel Complex ◽  
Aryl Halides ◽  
Mild Conditions ◽  
Monovalent Nickel

Chiral Mn(III) Salen Complex Immobilized on CuFe2O4@SiO2-NH2 NPs: A Cheap and Efficient Catalyst for N-arylation of Aryl Halides and Phenylboronic Acid Under Mild Conditions

2020 ◽  
Vol 17 (11) ◽  
pp. 857-863
Author(s):  
Mohammad Ali Nasseri ◽  
Seyyedeh Ameneh Alavi ◽  
Milad Kazemnejadi ◽  
Ali Allahresani
Keyword(s):  
Phenylboronic Acid ◽  
Significant Loss ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Efficient Catalyst ◽  
Aryl Chlorides ◽  
Mild Conditions ◽  
Cross Coupling Reactions ◽  
Salen Complex ◽  
Ft Ir

A convenient and efficient chiral CuFe2O4@SiO2-Mn(III) Ch.salen nanocatalyst has been developed for the C-N cross-coupling reactions of aryl halides/ phenylboronic acid with N-heterocyclic compounds in water and/or DMSO under mild conditions. The catalyst could be applied for the N-arylation of a variety of nitrogen-containing heterocycles with aryl chlorides, bromides, iodides and phenylboronic acid under mild conditions. Moderate to good yields were achieved for all substrates. The structure of catalyst was characterized using various techniques including FT-IR, FE-SEM, EDX, XRD, TEM and TGA. The catalyst can be simply recovered and reused for several times without significant loss of activity.

Borates as a Traceless Activation Group for Intermolecular Alkylarylation of Ethylene through Photoredox/Nickel Dual Catalysis

Synlett ◽  
2020 ◽  
Author(s):  
Shengqing Zhu ◽  
Lingling Chu ◽  
Xiaoliang Feng ◽  
Lei Guo
Keyword(s):  
Functional Groups ◽  
Aryl Halides ◽  
Nickel Catalysis ◽  
Mild Conditions ◽  
Dual Catalysis

AbstractA formal ethylene alkylarylation reaction with aryl halides and alkyl oxalates enabled by synergistic photoredox/nickel catalysis is reported. This protocol takes advantage of borates as a traceless activation group, achieving the formal ethylene difunctionalized products via a catalytic three-component 1,2-alkylarylation of vinyl borate followed by a base-assisted deborylation process. The mild conditions allow for excellent functional groups compatibility and broad substrate scope.

Cercosporin-bioinspired photoreductive activation of aryl halides under mild conditions

2019 ◽  
Vol 380 ◽  
pp. 1-8 ◽  
Author(s):  
Zhaocheng Tang ◽  
Jia Li ◽  
Fulin Lin ◽  
Wenhao Bao ◽  
Shiwei Zhang ◽  
...  
Keyword(s):  
Aryl Halides ◽  
Mild Conditions

A Class of Amide Ligands Enable Cu-Catalyzed Coupling of (Hetero)aryl Halides with Sulfinic Acid Salts under Mild Conditions

2018 ◽  
Vol 83 (12) ◽  
pp. 6589-6598 ◽  
Author(s):  
Jinlong Zhao ◽  
Songtao Niu ◽  
Xi Jiang ◽  
Yongwen Jiang ◽  
Xiaojing Zhang ◽  
...  
Keyword(s):  
Aryl Halides ◽  
Sulfinic Acid ◽  
Mild Conditions ◽  
Amide Ligands ◽  
Acid Salts

scholarly journals Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates

2020 ◽  
Vol 11 (19) ◽  
pp. 5043-5051
Author(s):  
Jian Yang ◽  
Verònica Postils ◽  
Michael I. Lipschutz ◽  
Meg Fasulo ◽  
Christophe Raynaud ◽  
...  
Keyword(s):  
Nickel Complex ◽  
Dominant Role ◽  
Nickel Catalysts ◽  
Mild Conditions ◽  
Catalytic Intermediates

A cationic nickel complex of the bis(8-quinolyl)(3,5-di-tert-butylphenoxy)phosphine (NPN) ligand, [(NPN)NiCl]+, is a precursor to efficient catalysts for the hydrosilation of alkenes with hydrosilanes under mild conditions and low catalyst loadings.

scholarly journals Direct Sulfoxidation of Aromatic Methyl Thioethers with Aryl Halides by Copper-Catalyzed C(sp3)–H Bond Activation

Catalysts ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 105
Author(s):  
Runsheng Xu ◽  
Yueer Zhu ◽  
Feixiang Xiong ◽  
Suli Tong
Keyword(s):  
Bond Activation ◽  
Bond Formation ◽  
Aryl Halides ◽  
Biologically Active ◽  
Mild Conditions ◽  
Methyl Thioethers ◽  
High Yields

A copper-catalyzed direct sulfoxidation reaction by C(sp3)–H bond activation has been developed. Starting from sample aromatic methyl thioethers with aryl halides, versatile biologically-active arylbenzylsulfoxide derivatives were efficiently synthesized in good to high yields under mild conditions. This new methodology provides an economical approach toward C(sp3)–C(sp2) bond formation.

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