Acid–Base Property of Ethylammonium Nitrate Ionic Liquid Directly Obtained Using Ion-selective Field Effect Transistor Electrode

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The operation of an ionic liquid-gated field effect transistor based on a single InAs nanowire—as represented in the SEM micrograph Figure 1b and pictorially in Figure 1c—is demonstrated. [...]


2010 ◽  
Vol 82 (10) ◽  
pp. 1927-1941 ◽  
Author(s):  
Shin-ichi Ishiguro ◽  
Yasuhiro Umebayashi ◽  
Ryo Kanzaki ◽  
Kenta Fujii

Ionic liquids (ILs) are expected to have specific properties as solvents for chemical reactions in view of solution chemistry. Among physicochemical properties, liquid structure, acid–base, and electron-pair donating and accepting abilities of solvent play a crucial role in ion-solvation and acid–base, metal-ion complexation, and electrochemical reactions. Various types of ILs have been developed, and among others, the bis(trifluoromethanesulfonyl)amide (TFSA–)-based ILs are extensively used. TFSA– is a flexible molecule to give two stable conformers, cis (C1) and trans (C2), which are present in equilibrium in the liquid state. The conformational equilibrium shifts upon solvation to the metal ion. This is quantitatively studied to obtain thermodynamic parameters of conformational change from C2 to C1 in the bulk and in the solvation sphere of the lithium ion. On the other hand, with ethylammonium nitrate (EAN), a typical protic IL, it is revealed that the ammonium group is hydrogen-bonded with three nitrate ions to form a heterogeneous liquid structure. The solvent acid–base property of EAN and acid dissociation reaction in EAN have been quantitatively revealed, and the results will be discussed in comparison with those in normal molecular solvents.


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