Dual Orbital Effects in N-Philic Cyclizations of Silyl Radicals onto Imines

2007 ◽  
Vol 36 (2) ◽  
pp. 300-301 ◽  
Author(s):  
Uta Wille ◽  
Eva-Katrin Mucke
Keyword(s):  
Silyl Radicals

ChemInform Abstract: CHEMISTRY OF ORGANOSILICON COMPOUNDS. CXXIX. EVIDENCE FOR FORMATION OF FREE SILYL RADICALS IN THE PHOTOLYSIS OF ARYLDISILANES

1980 ◽  
Vol 11 (20) ◽  
Author(s):  
H. SAKURAI ◽  
Y. NAKADAIRA ◽  
M. KIRA ◽  
H. SUGIYAMA ◽  
K. YOSHIDA ◽  
...  
Keyword(s):  
Organosilicon Compounds ◽  
Silyl Radicals

Silyl Radicals. Formation and Reactions of Cyclopropyldimethylsilyl Radicals

1967 ◽  
Vol 40 (6) ◽  
pp. 1551-1551 ◽  
Author(s):  
Hideki Sakurai ◽  
Akira Hosomi ◽  
Makoto Kumada
Keyword(s):  
Silyl Radicals

scholarly journals Radical-Mediated Hetaryl Functionalization of Nonactivated Alkenes through Distal ipso-Migration of O- or S-Hetaryls

Synlett ◽  
2020 ◽  
Author(s):  
Chen Zhu ◽  
Huihui Zhang ◽  
Meishan Ji ◽  
Youhao Wei ◽  
Haodong Chen ◽  
...  
Keyword(s):  
Efficient Approach ◽  
Silyl Radicals

AbstractA radical-mediated hetaryl functionalization of nonactivated alkenes through distal ipso-migration of O- or S-containing hetaryls was developed. Furyl, benzofuryl, thienyl, and benzothienyl groups showed satisfactory migratory abilities. A variety of heteroatom-centered radicals, including azido, trifluoromethylsulfanyl, and silyl radicals readily trigger the migration cascade, and a new C–heteroatom and C–C bond are concomitantly constructed in the reaction. This method provides an efficient approach to the synthesis of high-valued complex O- or S-hetaryl compounds.

Green Bulb Light Source Induced Epoxy Cationic Polymerization under Air Using Tris(2,2′-bipyridine)ruthenium(II) and Silyl Radicals

2010 ◽  
Vol 43 (24) ◽  
pp. 10191-10195 ◽  
Author(s):  
Jacques Lalevée ◽  
Nicolas Blanchard ◽  
Mohamad-Ali Tehfe ◽  
Fabrice Morlet-Savary ◽  
Jean Pierre Fouassier
Keyword(s):  
Light Source ◽  
Cationic Polymerization ◽  
Silyl Radicals

Fragmentation of β-Silyl Radicals. A Computational Study

2010 ◽  
Vol 29 (11) ◽  
pp. 2406-2412 ◽  
Author(s):  
Raphaël Méreau ◽  
Philippe d’Antuono ◽  
Frédéric Castet ◽  
Guy Rouquet ◽  
Frédéric Robert ◽  
...  
Keyword(s):  
Computational Study ◽  
Silyl Radicals
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