4-(4-Pyridyl)benzoic Acid (PybenH) Dimer: An Efficient and Reasonable Design for a Long Linear Bidentate Building Block Employed in Metal–Organic Coordination Framework

2006 ◽  
Vol 35 (6) ◽  
pp. 614-615 ◽  
Author(s):  
Ryo Sekiya ◽  
Shin-ichi Nishikiori ◽  
Katsuyuki Ogura
Keyword(s):  
Benzoic Acid ◽  
Building Block ◽  
Metal Organic ◽  
Coordination Framework

Recent progress in the design and synthesis of zeolite-like metal–organic frameworks (ZMOFs)

2021 ◽  
Author(s):  
Xinyao Liu ◽  
Yunling Liu
Keyword(s):  
Building Block ◽  
High Stability ◽  
Recent Progress ◽  
Metal Organic Frameworks ◽  
Excellent Performance ◽  
Design And Synthesis ◽  
Molecular Building Block ◽  
Secondary Building Units ◽  
Metal Organic

ZMOFs are a subset of MOFs that exhibit zeolite-like topologies. Using molecular building block strategy, many ZMOFs with high stability and excellent performance can be rationally designed and synthesized using different secondary building units.

Syntheses, structures, and luminescence properties of four metal–organic polymers with undocumented topologies constructed from 3,5-bis((4′-carboxylbenzyl)oxy)benzoate ligand

RSC Advances ◽  
2014 ◽  
Vol 4 (57) ◽  
pp. 30274-30281 ◽  
Author(s):  
Xiutang Zhang ◽  
Liming Fan ◽  
Weikuo Song ◽  
Weiliu Fan ◽  
Liming Sun ◽  
...  
Keyword(s):  
Benzoic Acid ◽  
Luminescence Properties ◽  
Organic Polymers ◽  
Metal Organic

Four 3D metal–organic polymers with new topologies based on 3,5-bis((4′-carboxylbenzyl)oxy)benzoic acid were synthesized and characterized.

A New Multi-Functional Cu(II)-Organic Framework as a Platform for Selective Carbon Dioxide Chemical Fixation and Separation of Organic Dyes

CrystEngComm ◽  
2021 ◽  
Author(s):  
Yang-Tian Yan ◽  
Chen-Yang Wang ◽  
Li-Na Zheng ◽  
Yun-Long Wu ◽  
Jiao Liu ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Benzoic Acid ◽  
Organic Dyes ◽  
Metal Organic Framework ◽  
Chemical Fixation ◽  
Acid Ligand ◽  
Metal Organic ◽  
Organic Framework

A new multi-functional metal-organic framework, {[Cu2(HL)(H2O)2]·NMP·2H2O}n (1), was assembled employing a asymmetrical V-shaped rigid multicarboxylic acid ligand H5L (H5L= 2,4-di(2′,5′-dicarboxylphenyl)benzoic acid) with Cu(II) ions. 1 possesses a 3D pore formed...

A Novel (3,4,9)-Connected 3D Metal–Organic Framework Based on the Non-Planar Tricarboxyl Tecton and Zn5O4-Cluster SBU

2015 ◽  
Vol 68 (1) ◽  
pp. 161 ◽  
Author(s):  
Zhuo-Wei Wang ◽  
Hui Zhao ◽  
Min Chen ◽  
Min Hu
Keyword(s):  
Thermal Stability ◽  
Benzoic Acid ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crystalline Material ◽  
Tripodal Ligand ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Organic Framework

Combination of a non-planar tripodal ligand 3,4-bi(4-carboxyphenyl)-benzoic acid (H3L) and Zn5O4-cluster secondary building units affords a highly connected three-dimensional metal–organic framework, {[Zn5(μ3-OH)3(μ2-OH)L2(H2O)2](H2O)2}n (1), which exhibits an unusual (3,4,9)-connected (42.5)(3.43.52)(32.45.511.613.73.82) topological net. The thermal stability and solid luminescence of the crystalline material have also been investigated.

Novel (4,8)-connected scu coordination framework constructed by tetrakis(4-benzoic acid)ethylene

CrystEngComm ◽  
2013 ◽  
Vol 15 (9) ◽  
pp. 1669 ◽  
Author(s):  
Hao-Ling Sun ◽  
Rui Jiang ◽  
Zongsheng Li ◽  
Yong Qiang Dong ◽  
Miao Du
Keyword(s):  
Benzoic Acid ◽  
Coordination Framework

Incorporation of an intact dimeric Zr12 oxo cluster from a molecular precursor in a new zirconium metal–organic framework

2018 ◽  
Vol 54 (22) ◽  
pp. 2735-2738 ◽  
Author(s):  
Andrey A. Bezrukov ◽  
Karl W. Törnroos ◽  
Erwan Le Roux ◽  
Pascal D. C. Dietzel
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Molecular Building Block ◽  
Molecular Precursor ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework

A dimeric Zr12 oxo cluster was used as new molecular building block in construction of metal–organic frameworks utilizing the precursor approach.

Two pyrene-based metal−organic frameworks constructed from 1,3,6,8-tetrakis(p-benzoic acid)pyrene: Syntheses, structures and photoelectron performances

2020 ◽  
Vol 285 ◽  
pp. 121252 ◽  
Author(s):  
Ya-Dan Huang ◽  
Jian-Hua Qin ◽  
Xiao-Gang Yang ◽  
Hua-Rui Wang ◽  
Fei-Fei Li ◽  
...  
Keyword(s):  
Benzoic Acid ◽  
Metal Organic Frameworks ◽  
Metal Organic

ROD-8, a rod MOF with a pyrene-cored tetracarboxylate linker: framework disorder, derived nets and selective gas adsorption

CrystEngComm ◽  
2014 ◽  
Vol 16 (28) ◽  
pp. 6291-6295 ◽  
Author(s):  
Ru-Jin Li ◽  
Mian Li ◽  
Xiao-Ping Zhou ◽  
Seik Weng Ng ◽  
Michael O'Keeffe ◽  
...  
Keyword(s):  
Benzoic Acid ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Secondary Building Unit ◽  
Building Unit ◽  
Metal Organic ◽  
Organic Framework

Reported here is a new CdII-based metal–organic framework (MOF), ROD-8, based on the rod secondary building unit (SBU) and tetratopic linker 1,3,6,8-tetrakis(p-benzoic acid)pyrene.

Synthesis and Crystal Structure of a Cadmium(II) Complex with 2-(4΄-Chlorine-Benzoyl)-Benzoic Acid and 1,10-Phenanthroline

2011 ◽  
Vol 339 ◽  
pp. 313-316
Author(s):  
Xiu Mei Li ◽  
Zhi Tao Wang ◽  
Qing Wei Wang
Keyword(s):  
Benzoic Acid ◽  
Room Temperature ◽  
Supramolecular Network ◽  
X Ray Diffraction ◽  
Organic Complex ◽  
Orthorhombic Space Group ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Metal Organic Complex ◽  
Metal Organic

A new metal-organic complex Cd2(cbba)4(phen)2 (Hcbba = 2-(4΄-chlorine-benzoyl)- benzoic acid, phen = 1,10-phenanthroline) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, fluorescence spectrum and single-crystal X-ray diffraction. The compound crystallizes in orthorhombic, space group Pbcn with a = 12.0976(4), b = 18.0925(6), c = 31.6829(10) Å, V = 6934.6(4) Å3, C80H48Cd2Cl4N4O12, Mr = 1623.82, Dc = 1.555 g/cm3, μ(MoKα) = 0.8365 mm1, F(000) = 3264, Z = 4, the final R = 0.0396 and wR = 0.0960 for 5372 observed reflections (I > 2(I)). It exhibits a 3D supramolecular network through π-π interactions and shows green luminescent property at room temperature.

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