Plasmon-induced Hydrogen Evolution Reaction on p-Type Semiconductor Electrode with Ag Nanodimer Structures

2020 ◽  
Vol 49 (7) ◽  
pp. 806-808
Author(s):  
Daiki Sato ◽  
Hiro Minamimoto ◽  
Kei Murakoshi
2012 ◽  
Vol 566 (1) ◽  
pp. 193-201 ◽  
Author(s):  
Kenji Yamada ◽  
Ryo Fukuda ◽  
Kazuya Yamamoto ◽  
Tatsuhiko Sonoda ◽  
Hiroyuki Nakamura ◽  
...  

2020 ◽  
Vol MA2020-02 (61) ◽  
pp. 3107-3107
Author(s):  
Hiro Minamimoto ◽  
Daiki Sato ◽  
Kei Murakoshi

2016 ◽  
Vol 4 (8) ◽  
pp. 2936-2942 ◽  
Author(s):  
Geetu Sharma ◽  
Zeqiong Zhao ◽  
Pranab Sarker ◽  
Benjamin A. Nail ◽  
Jiarui Wang ◽  
...  

As a visible light active p-type semiconductor, CuBi2O4 is of interest as a photocatalyst for the generation of hydrogen fuel from water.


2021 ◽  
Vol 9 ◽  
Author(s):  
Lin Wei ◽  
Deqian Zeng ◽  
Zongzhuo Xie ◽  
Qingru Zeng ◽  
Hongfei Zheng ◽  
...  

Designing low-cost, environment friendly, and highly active photocatalysts for water splitting is a promising path toward relieving energy issues. Herein, one-dimensional (1D) cadmium sulfide (CdS) nanorods are uniformly anchored onto two-dimensional (2D) NiO nanosheets to achieve enhanced photocatalytic hydrogen evolution. The optimized 2D/1D NiO/CdS photocatalyst exhibits a remarkable boosted hydrogen generation rate of 1,300 μmol h−1 g−1 under visible light, which is more than eight times higher than that of CdS nanorods. Moreover, the resultant 5% NiO/CdS composite displays excellent stability over four cycles for photocatalytic hydrogen production. The significantly enhanced photocatalytic activity of the 2D/1D NiO/CdS heterojunction can be attributed to the efficient separation of photogenerated charge carriers driven from the formation of p-n NiO/CdS heterojunction. This study paves a new way to develop 2D p-type NiO nanosheets-decorated n-type semiconductor photocatalysts for photocatalytic applications.


2020 ◽  
Vol 8 (44) ◽  
pp. 23323-23329
Author(s):  
Jing Hu ◽  
Siwei Li ◽  
Yuzhi Li ◽  
Jing Wang ◽  
Yunchen Du ◽  
...  

Crystalline–amorphous Ni–Ni(OH)2 core–shell assembled nanosheets exhibit outstanding electrocatalytic activity and stability for hydrogen evolution under alkaline conditions.


2020 ◽  
Author(s):  
Elisabeth Hofmeister ◽  
Jisoo Woo ◽  
Tobias Ullrich ◽  
Lydia Petermann ◽  
Kevin Hanus ◽  
...  

Cobaloximes and their BF<sub>2</sub>-bridged analogues have emerged as promising non-noble metal catalysts for the photocatalytic hydrogen evolution reaction (HER). Herein we report the serendipitous discovery that double complex salts such as [Co(dmgh)<sub>2</sub>py<sub>2</sub>]<sup>+</sup>[Co(dmgBPh<sub>2</sub>)<sub>2</sub>Cl<sub>2</sub>]<sup>-</sup> can be obtained in good yields by treatment of commercially available [Co(dmgh)<sub>2</sub>pyCl] with triarylboranes. A systematic study on the use of such double complex salts and their single salts with simple counterions as photocatalysts revealed HER activities comparable or superior to existing cobaloxime catalysts and suggests ample opportunities for this compound class in catalyst/photosensitizer dyads and immobilized architectures. Preliminary electrochemical and spectroscopic studies indicate that one key advantage of these charged cobalt complexes is that the reduction potentials as well as the electrostatic interaction with charged photosensitizers can be tuned.


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