A Synthesis of AB-Ring Model System of Taxane Framework by Way of Intramolecular Knoevenagel Cyclization

2002 ◽  
Vol 31 (1) ◽  
pp. 92-93 ◽  
Author(s):  
Hidehiro Arai ◽  
Ayako Ohno ◽  
Yu-ichirou Tani ◽  
Shouhei Imachi ◽  
Teruaki Mukaiyama
Keyword(s):  
1995 ◽  
Vol 24 (3) ◽  
pp. 229-230 ◽  
Author(s):  
Teruaki Mukaiyama ◽  
Isamu Shiina ◽  
Kaname Kimura ◽  
Yuji Akiyama ◽  
Hayato Iwadare

ChemInform ◽  
2010 ◽  
Vol 33 (24) ◽  
pp. no-no
Author(s):  
Hidehiro Arai ◽  
Ayako Ohno ◽  
Yu-ichirou Tani ◽  
Shouhei Imachi ◽  
Teruaki Mukaiyama
Keyword(s):  

ChemInform ◽  
2010 ◽  
Vol 26 (33) ◽  
pp. no-no
Author(s):  
T. MUKAIYAMA ◽  
I. SHIINA ◽  
K. KIMURA ◽  
Y. AKIYAMA ◽  
H. IWADARE

Synlett ◽  
2021 ◽  
Author(s):  
Yuki Yukutake ◽  
Takahiro Hiramatsu ◽  
Ryusei Itoh ◽  
Kazutada Ikeuchi ◽  
Takahiro Suzuki ◽  
...  

Synthetic studies on an ABC-ring model of Tubiferal A, a triterpenoid isolated from the fruit bodies of the Tubifera dimorphotheca myxomycete, are described. The stereogenic centers at the angular positions were constructed through the stereoselective addition of a C-ring allylborane followed by an Eschenmoser–Claisen rearrangement reaction prior to the formation of the AB-ring system by a double intramolecular alkylation reaction of a dichloro nitrile intermediate.


1977 ◽  
Vol 13 (1) ◽  
pp. 111-120 ◽  
Author(s):  
Dorothy Adalis ◽  
Donald E. Gardner ◽  
Frederick J. Miller ◽  
David L. Coffin

Author(s):  
D. C. Williams ◽  
D. E. Outka

Many studies have shown that the Golgi apparatus is involved in a variety of synthetic activities, and probably no Golgi product is more elaborate than the scales produced by various kinds of phytoflagellates. The formation of calcified scales (coccoliths, Fig. 1,2) of the coccolithophorid phytoflagellates provides a particularly interesting model system for the study of biological mineralization, and the sequential formation of Golgi products.The coccoliths of Hymenomonas carterae consist of a scale-like base (Fig. 2 and 4, b) with a highly structured calcified (CaCO3) rim composed of two distinct elements which alternate about the base periphery (Fig. 1 and 3, A, B). Each element is enveloped by a sheath-like organic matrix (Fig. 3; Fig. 4, m).


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