Novel Method for Oxidation of Secondary Alcohols into Ketones with Molecular Oxygen by Using Cobalt(II) Complex Catalyst

1989 ◽  
Vol 18 (3) ◽  
pp. 519-522 ◽  
Author(s):  
Tohru Yamada ◽  
Teruaki Mukaiyama
Keyword(s):  
Molecular Oxygen ◽  
Secondary Alcohols ◽  
Complex Catalyst ◽  
Novel Method

ChemInform Abstract: Oxidation of Aldehydes into Carboxylic Acids with Molecular Oxygen Using Nickel(II) Complex Catalyst.

ChemInform ◽  
2010 ◽  
Vol 23 (44) ◽  
pp. no-no ◽  
Author(s):  
T. YAMADA ◽  
O. RHODE ◽  
T. TAKAI ◽  
T. MUKAIYAMA
Keyword(s):  
Molecular Oxygen ◽  
Carboxylic Acids ◽  
Complex Catalyst

Efficient and selective oxidation of alcohols to carbonyl compounds at room temperature by a ruthenium complex catalyst and hydrogen peroxide

2019 ◽  
Vol 43 (48) ◽  
pp. 19415-19421 ◽  
Author(s):  
Jie-Xiang Wang ◽  
Xian-Tai Zhou ◽  
Qi Han ◽  
Xiao-Xuan Guo ◽  
Xiao-Hui Liu ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Carbonyl Compounds ◽  
Room Temperature ◽  
Ruthenium Complex ◽  
Secondary Alcohols ◽  
Complex Catalyst ◽  
Efficient System ◽  
Oxidation Of Alcohols

An efficient system comprising a ruthenium complex and hydrogen peroxide was developed for the oxidation of various primary and secondary alcohols at room temperature.

Generation of singlet oxygen (1O2) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents

2014 ◽  
Vol 86 (6) ◽  
pp. 945-952 ◽  
Author(s):  
Erbay Kalay ◽  
Hamdullah Kılıç ◽  
Mustafa Catir ◽  
Murat Cakici ◽  
Cavit Kazaz
Keyword(s):  
Hydrogen Peroxide ◽  
Singlet Oxygen ◽  
Molecular Oxygen ◽  
Singlet Molecular Oxygen ◽  
Hydrogen Peroxide Decomposition ◽  
Co Catalyst ◽  
Peroxide Decomposition ◽  
Novel Method

AbstractA novel method for the production of singlet oxygen from H2O2 was developed. A combination of iodoarene (ArI), methyltrioxorhenium (MTO), and H2O2 in the presence of pyridine as the co-catalyst efficiently produced singlet molecular oxygen (1O2) under biphasic conditions. The existence of 1O2 was demonstrated by trapping experiments with aromatic dienes, 1,3-cyclodienes, and alkenes. The mechanism of 1O2 production from the iodoarene/MTO/35 % H2O2 system and the reaction scope was also discussed.

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