A Novel Host Compound with High Inclusion Ability,N,N,N′,N′-Tetracyclohexyl-2,2′-biphenyldicarboxamide, and Crystal Structure of Its 1:1 Phenol Complex

1987 ◽  
Vol 16 (7) ◽  
pp. 1393-1396 ◽  
Author(s):  
Fumio Toda ◽  
Akihiro Kai ◽  
Yasunori Tagami ◽  
Thomas C. W. Mak
1988 ◽  
Vol 17 (1) ◽  
pp. 107-110 ◽  
Author(s):  
Fumio Toda ◽  
Koichi Tanaka ◽  
Tosiharu Hyoda ◽  
Thomas C. W. Mak

2020 ◽  
Vol 49 (29) ◽  
pp. 10104-10113 ◽  
Author(s):  
Dan Zhao ◽  
Yali Xue ◽  
Ruijuan Zhang ◽  
Yanping Fan ◽  
Baozhong Liu ◽  
...  

This work provides a novel host lattice template CsNa2REE2(BO3)(PO4)2 (REE = Y, Gd, Lu) for Eu3+ luminescence, with a linear arrangement of REE3+ ions that restricts the occurrence of concentration quenching even for fully concentrated Eu3+.


1984 ◽  
Vol 25 (38) ◽  
pp. 4303-4306 ◽  
Author(s):  
Christopher J. Gilmore ◽  
David D. MacNicol ◽  
Anthony Murphy ◽  
Marie A. Russell

Author(s):  
Douglas L. Dorset ◽  
Anthony J. Hancock

Lipids containing long polymethylene chains were among the first compounds subjected to electron diffraction structure analysis. It was only recently realized, however, that various distortions of thin lipid microcrystal plates, e.g. bends, polar group and methyl end plane disorders, etc. (1-3), restrict coherent scattering to the methylene subcell alone, particularly if undistorted molecular layers have well-defined end planes. Thus, ab initio crystal structure determination on a given single uncharacterized natural lipid using electron diffraction data can only hope to identify the subcell packing and the chain axis orientation with respect to the crystal surface. In lipids based on glycerol, for example, conformations of long chains and polar groups about the C-C bonds of this moiety still would remain unknown.One possible means of surmounting this difficulty is to investigate structural analogs of the material of interest in conjunction with the natural compound itself. Suitable analogs to the glycerol lipids are compounds based on the three configurational isomers of cyclopentane-1,2,3-triol shown in Fig. 1, in which three rotameric forms of the natural glycerol derivatives are fixed by the ring structure (4-7).


Author(s):  
George G. Cocks ◽  
Louis Leibovitz ◽  
DoSuk D. Lee

Our understanding of the structure and the formation of inorganic minerals in the bivalve shells has been considerably advanced by the use of electron microscope. However, very little is known about the ultrastructure of valves in the larval stage of the oysters. The present study examines the developmental changes which occur between the time of conception to the early stages of Dissoconch in the Crassostrea virginica(Gmelin), focusing on the initial deposition of inorganic crystals by the oysters.The spawning was induced by elevating the temperature of the seawater where the adult oysters were conditioned. The eggs and sperm were collected separately, then immediately mixed for the fertilizations to occur. Fertilized animals were kept in the incubator where various stages of development were stopped and observed. The detailed analysis of the early stages of growth showed that CaCO3 crystals(aragonite), with orthorhombic crystal structure, are deposited as early as gastrula stage(Figuresla-b). The next stage in development, the prodissoconch, revealed that the crystal orientation is in the form of spherulites.


Author(s):  
F.-R. Chen ◽  
T. L. Lee ◽  
L. J. Chen

YSi2-x thin films were grown by depositing the yttrium metal thin films on (111)Si substrate followed by a rapid thermal annealing (RTA) at 450 to 1100°C. The x value of the YSi2-x films ranges from 0 to 0.3. The (0001) plane of the YSi2-x films have an ideal zero lattice mismatch relative to (111)Si surface lattice. The YSi2 has the hexagonal AlB2 crystal structure. The orientation relationship with Si was determined from the diffraction pattern shown in figure 1(a) to be and . The diffraction pattern in figure 1(a) was taken from a specimen annealed at 500°C for 15 second. As the annealing temperature was increased to 600°C, superlattice diffraction spots appear at position as seen in figure 1(b) which may be due to vacancy ordering in the YSi2-x films. The ordered vacancies in YSi2-x form a mesh in Si plane suggested by a LEED experiment.


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