scholarly journals THE SMSI EFFECT ON THE ACTIVITY OF CO HYDROGENATION OVER Nb2O5-SUPPORTED Rh CATALYSTS

1983 ◽  
Vol 12 (10) ◽  
pp. 1619-1622 ◽  
Author(s):  
Kimio Kunimori ◽  
Hiroshi Abe ◽  
Toshio Uchijima
Keyword(s):  
Co Hydrogenation ◽  
Smsi Effect

Highly active carbon nanotube–promoted Rh-Mn-Li/SiO2 catalysts for the synthesis of C2+ oxygenates from syngas

2021 ◽  
pp. 174751982098472
Author(s):  
Jun Yu ◽  
Ying Han ◽  
Guoqing Chen ◽  
Xiuzhen Xiao ◽  
Haifang Mao ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Photoelectron Spectroscopy ◽  
Co Hydrogenation ◽  
X Ray ◽  
Highly Active ◽  
Transmission Electron ◽  
Co Insertion ◽  
Temperature Programmed Surface Reaction ◽  
Temperature Programmed ◽  
Oxygenate Synthesis

The effect of carbon nanotubes on the catalytic properties of Rh-Mn-Li/SiO2 catalysts was investigated for CO hydrogenation. The catalysts were comprehensively characterized by means of X-ray power diffraction, N2 sorption, transmission electron microscope, H2–temperature-programmed reduction, CO–temperature-programmed desorption, temperature-programmed surface reaction, and X-ray photoelectron spectroscopy. The results showed that an appropriate amount of carbon nanotubes can be attached to the surface of the SiO2 sphere and can improve the Rh dispersion. Moderate Rh-Mn interaction can be obtained by doping with the appropriate amount of carbon nanotubes, which promotes the formation of strongly adsorbed CO and facilitates the progress of CO insertion, resulting in the increase in the selectivity of C2+ oxygenate synthesis.

scholarly journals The interaction of size-selected Ru3 clusters with RF-deposited TiO2: probing Ru-CO binding sites with CO-Temperature Programmed Desorption

2021 ◽  
Author(s):  
Liam Howard-Fabretto ◽  
Timothy Gorey ◽  
Guangjing Li ◽  
Siriluck Tesana ◽  
Gregory F Metha ◽  
...  
Keyword(s):  
Radio Frequency ◽  
Chemical Reactions ◽  
Binding Sites ◽  
Co Hydrogenation ◽  
Temperature Programmed Desorption ◽  
Temperature Programmed

Small Ru clusters are efficient catalysts for chemical reactions such as CO hydrogenation. In this study 3-atom Ru3 clusters were deposited onto radio frequency (RF)-deposited TiO2 which is an inexpensive,...

Study on the co-hydrogenation of coal tar and kitchen waste oil over Co–Mo/γ–Al2O3

2021 ◽  
Author(s):  
Panpan Ji ◽  
Zheng Fan ◽  
Menglong Niu ◽  
Liuyi Pan ◽  
Genhui Jing ◽  
...  
Keyword(s):  
Co Hydrogenation ◽  
Coal Tar ◽  
Waste Oil ◽  
Kitchen Waste

scholarly journals Formation, dynamics, and long-term stability of Mn- and Fe-promoted Rh/SiO2 catalysts in CO hydrogenation

2021 ◽  
Author(s):  
Phil Preikschas ◽  
Julia Bauer ◽  
Kristian Knemeyer ◽  
Raoul Naumann d'Alnoncourt ◽  
Ralph Krähnert ◽  
...  
Keyword(s):  
Co Hydrogenation ◽  
Term Stability ◽  
Fossil Carbon ◽  
Long Term Stability ◽  
Formation Dynamics

The conversion of syngas (CO/H2) to ethanol (StE) is one promising example to generate a high-value fuel and key intermediate for various base chemicals, preferably from non-fossil carbon resources. Rh-based...

Rationalizing an Unexpected Structure Sensitivity in Heterogeneous Catalysis—CO Hydrogenation over Rh as a Case Study

ACS Catalysis ◽  
2021 ◽  
pp. 5189-5201
Author(s):  
Max Schumann ◽  
Monia R. Nielsen ◽  
Thomas E. L. Smitshuysen ◽  
Thomas W. Hansen ◽  
Christian D. Damsgaard ◽  
...  
Keyword(s):  
Heterogeneous Catalysis ◽  
Co Hydrogenation ◽  
Structure Sensitivity
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