THE REDUCTIVE COUPLING REACTION OF DIARYLIODONIUM SALTS CATALYZED BY PALLADIUM–ZINC SYSTEM

1983 ◽  
Vol 12 (8) ◽  
pp. 1165-1166 ◽  
Author(s):  
Masaharu Uchiyama ◽  
Takehiko Suzuki ◽  
Yasuo Yamazaki
Keyword(s):  
Coupling Reaction ◽  
Reductive Coupling ◽  
Diaryliodonium Salts

scholarly journals Phosphite-Mediated Reductive Cross-Coupling of Isatins and Nitro­styrenes

Synthesis ◽  
2017 ◽  
Vol 49 (12) ◽  
pp. 2663-2676 ◽  
Author(s):  
Somayeh Motevalli ◽  
Jeffrey Johnson
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Reductive Coupling ◽  
Title Reaction ◽  
Dimethyl Phosphite ◽  
Mild Conditions ◽  
Michael Type Addition

A new reductive coupling reaction between N-alkylisatins, dimethyl phosphite, and nitrostyrenes has been developed. The reaction relies on Pudovik addition, subsequent phosphonate–phosphate rearrangement, and Michael-type addition of a transient carbanion on the indolinone with β-nitrostyrenes. This protocol introduces a convenient and versatile method for the construction of polyfunctionalized tertiary phosphates under mild conditions. Chiral general bases catalyze the title reaction with promising levels of enantioselectivity.

The role of oligomers in the synthesis of polysilanes by the Wurtz reductive coupling reaction

2003 ◽  
Vol 685 (1-2) ◽  
pp. 60-64 ◽  
Author(s):  
Daniel Bratton ◽  
Simon J. Holder ◽  
Richard G. Jones ◽  
William K.C. Wong
Keyword(s):  
Coupling Reaction ◽  
Reductive Coupling

scholarly journals Synthetic Approach toward α-Aminomethyl-γ-butyrolactones from β-Lactam Synthons Elaborated by SmI2-mediated Reductive Coupling Reactions

2013 ◽  
Vol 8 (7) ◽  
pp. 1934578X1300800
Author(s):  
Masaki Takahashi ◽  
Takahiro Sudo ◽  
Yusuke Murata ◽  
Tetsuya Sengoku ◽  
Hidemi Yoda
Keyword(s):  
Ring Opening ◽  
Coupling Reaction ◽  
Synthetic Approach ◽  
Coupling Reactions ◽  
Reductive Coupling ◽  
Important Class

A simple and straightforward synthetic approach was developed to access a biologically important class of α-aminomethyl-γ-butyrolactones via a β-lactam synthon strategy involving successive ring-opening and lactonization processes from α-hydroxyethyl-substituted β-lactams that were elaborated by SmI2-mediated reductive coupling reaction.

A reappraisal of the stereochemistry of polysilylenes formed by the Wurtz reductive-coupling reaction

1996 ◽  
Vol 521 (1-2) ◽  
pp. 171-176 ◽  
Author(s):  
Richard G. Jones ◽  
Robert E. Benfield ◽  
Philip J. Evans ◽  
Simon J. Holder ◽  
Julius A.M. Locke
Keyword(s):  
Coupling Reaction ◽  
Reductive Coupling
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