POLYSULFOXIDES AS NEW TYPE OF PHASE TRANSFER CATALYSTS IN TWO PHASE ALKYLATION

1982 ◽  
Vol 11 (9) ◽  
pp. 1421-1424 ◽  
Author(s):  
Naomichi Furukawa ◽  
Koji Imaoka ◽  
Hisashi Fujihara ◽  
Shigeru Oae
Keyword(s):  
Phase Transfer ◽  
Two Phase ◽  
Phase Transfer Catalysts ◽  
New Type

Utilization of Sulfoxides Containing Pyridine Nuclei as a New Type of Phase Transfer Catalysts: IV

Heterocycles ◽  
1982 ◽  
Vol 19 (11) ◽  
pp. 2041 ◽  
Author(s):  
Shigeru Oae ◽  
Naomichi Furukawa ◽  
Satoshi Ogawa ◽  
Tsutomu Kawai ◽  
Keiko Kashimoto ◽  
...  
Keyword(s):  
Phase Transfer ◽  
Phase Transfer Catalysts ◽  
New Type

scholarly journals Supramolecular interactions between catalytic species allow rational control over reaction kinetics

2019 ◽  
Vol 10 (39) ◽  
pp. 9115-9124 ◽  
Author(s):  
Abraham J. P. Teunissen ◽  
Tim F. E. Paffen ◽  
Ivo A. W. Filot ◽  
Menno D. Lanting ◽  
Roy J. C. van der Haas ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Reaction Kinetics ◽  
Phase Transfer ◽  
Supramolecular Interactions ◽  
Two Phase ◽  
Phase Transfer Catalysts ◽  
System P ◽  
Non Covalent Interactions ◽  
Rational Control ◽  
Covalent Interactions

The non-covalent interactions between two phase-transfer catalysts allow tuning of reaction kinetics from bimolecular, to pseudo 0th order, to sigmoidal. Kinetic models and DFT calculations are used to obtain detailed insight in the system.

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