scholarly journals AN EFFICIENT METHOD FOR THE PREPARATION OF HOMOALLYLIC ALCOHOL DERIVATIVES BY THE REACTION OF ALLYL IODIDE WITH CARBONYL COMPOUNDS IN THE PRESENCE OF STANNOUS HALIDE

1980 ◽  
Vol 9 (12) ◽  
pp. 1507-1510 ◽  
Author(s):  
Teruaki Mukaiyama ◽  
Taira Harada ◽  
Shin-ichiro Shoda
Keyword(s):  
Efficient Method ◽  
Carbonyl Compounds ◽  
Allyl Iodide

scholarly journals Deoximation of Ketoximes to Ketones with Ammonium Chlorochromate/Montmorillonite K10 in Dichloromethane

2009 ◽  
Vol 6 (1) ◽  
pp. 156-160 ◽  
Author(s):  
Ji-Tai Li ◽  
Xian-Tao Meng
Keyword(s):  
Efficient Method ◽  
Carbonyl Compounds ◽  
Room Temperature ◽  
Oxidative Cleavage ◽  
Montmorillonite K10

A convenient, mild and efficient method for oxidative cleavage of ketoximes to their parent carbonyl compounds with ammonium chlorochromate (ACC) / montmorillonite K10 in dichloromethane at room temperature is described

Formation of Acetals and Ketals from Carbonyl Compounds: A New and Highly Efficient Method Inspired by Cationic Palladium

Synlett ◽  
2019 ◽  
Vol 30 (15) ◽  
pp. 1810-1814 ◽  
Author(s):  
Enoch A. Mensah ◽  
Shawn D. Green ◽  
Jesse West ◽  
Tyler Kindoll ◽  
Brenda Lazaro-Martinez
Keyword(s):  
Efficient Method ◽  
Palladium Catalyst ◽  
Carbonyl Compounds ◽  
Catalyst Loading ◽  
Carbonyl Groups ◽  
Simple Method ◽  
Ambient Temperatures ◽  
Highly Efficient ◽  
Low Catalyst Loading ◽  
Cationic Palladium

The development of a new, highly efficient, and simple method for masking carbonyl groups as acetals and ketals is described. This methodology relies on the nature of the palladium catalyst to direct the acetalization/ketalization reaction. This new protocol is mild and proceed with a very low catalyst loading at ambient temperatures. The method has been extended to a wide variety of different carbonyl compounds with various steric encumbrances to form the corresponding acetals and ketals in excellent yields.

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