Rechargeable Batteries Based on Stable Redox Reactions of Disulfide Included in a Metal–Organic Framework as Ligands

2018 ◽  
Vol 47 (5) ◽  
pp. 678-681 ◽  
Author(s):  
Takeshi Shimizu ◽  
Heng Wang ◽  
Naoki Tanifuji ◽  
Daiju Matsumura ◽  
Masashi Yoshimura ◽  
...  
Keyword(s):  
Redox Reactions ◽  
Metal Organic Framework ◽  
Rechargeable Batteries ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Conductive 2D metal-organic framework for high-performance cathodes in aqueous rechargeable zinc batteries

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Kwan Woo Nam ◽  
Sarah S. Park ◽  
Roberto dos Reis ◽  
Vinayak P. Dravid ◽  
Heejin Kim ◽  
...  
Keyword(s):  
High Performance ◽  
Large Scale ◽  
High Current Density ◽  
Metal Organic Framework ◽  
Lithium Ion ◽  
Rechargeable Batteries ◽  
Economic Feasibility ◽  
Interfacial Resistance ◽  
Metal Organic ◽  
Organic Framework

Abstract Currently, there is considerable interest in developing advanced rechargeable batteries that boast efficient distribution of electricity and economic feasibility for use in large-scale energy storage systems. Rechargeable aqueous zinc batteries are promising alternatives to lithium-ion batteries in terms of rate performance, cost, and safety. In this investigation, we employ Cu3(HHTP)2, a two-dimensional (2D) conductive metal-organic framework (MOF) with large one-dimensional channels, as a zinc battery cathode. Owing to its unique structure, hydrated Zn2+ ions which are inserted directly into the host structure, Cu3(HHTP)2, allow high diffusion rate and low interfacial resistance which enable the Cu3(HHTP)2 cathode to follow the intercalation pseudocapacitance mechanism. Cu3(HHTP)2 exhibits a high reversible capacity of 228 mAh g−1 at 50 mA g−1. At a high current density of 4000 mA g−1 (~18 C), 75.0% of the initial capacity is maintained after 500 cycles. These results provide key insights into high-performance, 2D conductive MOF designs for battery electrodes.

A stable high-voltage lithium-ion battery realized by an in-built water scavenger

2020 ◽  
Vol 13 (4) ◽  
pp. 1197-1204 ◽  
Author(s):  
Zhi Chang ◽  
Yu Qiao ◽  
Han Deng ◽  
Huijun Yang ◽  
Ping He ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
High Voltage ◽  
Metal Organic Framework ◽  
Lithium Ion ◽  
Rechargeable Batteries ◽  
Simple Metal ◽  
Lithium Rechargeable Batteries ◽  
Metal Organic ◽  
Organic Framework

A simple metal–organic framework (MOF) based in-built water scavenger can efficiently eliminate various hazards induced by water in lithium rechargeable batteries.

Amorphization and disordering of metal–organic framework materials for rechargeable batteries by thermal treatment

2017 ◽  
Vol 41 (14) ◽  
pp. 6415-6419 ◽  
Author(s):  
Xiaoshi Hu ◽  
Xiaobing Lou ◽  
Chao Li ◽  
Qun Chen ◽  
Qi Yang ◽  
...  
Keyword(s):  
Thermal Treatment ◽  
Metal Organic Framework ◽  
Rechargeable Batteries ◽  
Framework Materials ◽  
Metal Organic ◽  
Storage Properties ◽  
Li Storage ◽  
Organic Framework

A disordered MOF framework upon evacuation with improved Li storage properties. The structure order can be reestablished upon exposure to water.

scholarly journals Metal–organic framework-based materials: advances, exploits, and challenges in promoting post Li-ion battery technologies

2021 ◽  
Author(s):  
Anukul K. Thakur ◽  
Mandira Majumder ◽  
Shashikant P. Patole ◽  
Karim Zaghib ◽  
M. V. Reddy
Keyword(s):  
Metal Organic Framework ◽  
Rechargeable Batteries ◽  
Li Ion Battery ◽  
Metal Organic ◽  
Li Ion ◽  
Organic Framework

In this review, the development of MOFs and MOF-based materials for application in non-Li rechargeable batteries has been highlighted together with describing the various persisting challenges and their corresponding remedies for these materials.

Identification of catalytic sites for cerium redox reactions in a metal-organic framework derived powerful electrocatalyst

2020 ◽  
Vol 32 ◽  
pp. 11-19 ◽  
Author(s):  
Zhaolin Na ◽  
Ruifang Yao ◽  
Qing Yan ◽  
Xinran Wang ◽  
Gang Huang ◽  
...  
Keyword(s):  
Redox Reactions ◽  
Metal Organic Framework ◽  
Catalytic Sites ◽  
Metal Organic ◽  
Organic Framework

Metal–organic framework derived hollow polyhedron metal oxide posited graphene oxide for energy storage applications

2016 ◽  
Vol 52 (5) ◽  
pp. 946-949 ◽  
Author(s):  
Bendi Ramaraju ◽  
Cheng-Hung Li ◽  
Sengodu Prakash ◽  
Chia-Chun Chen
Keyword(s):  
Graphene Oxide ◽  
Energy Storage ◽  
Electrochemical Properties ◽  
Metal Organic Framework ◽  
Cycling Performance ◽  
Rechargeable Batteries ◽  
Exfoliated Graphene ◽  
Metal Organic ◽  
Energy Storage Applications ◽  
Organic Framework

Cuox–rGO composite was synthesized by sintering a Cu-based metal–organic framework (Cu-MOF) embedded with exfoliated graphene oxide. The obtained material delivers an excellent electrochemical properties with stable cycling performance as an anode material in rechargeable batteries.

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