scholarly journals Preparation of Sodium Ion Conductive Na10GeP2S12 Glass-ceramic Electrolytes

2018 ◽  
Vol 47 (1) ◽  
pp. 13-15 ◽  
Author(s):  
Fumika Tsuji ◽  
Naoto Tanibata ◽  
Atsushi Sakuda ◽  
Akitoshi Hayashi ◽  
Masahiro Tatsumisago
Keyword(s):  
Glass Ceramic ◽  
Sodium Ion ◽  
Ceramic Electrolytes

scholarly journals High sodium ion conductivity of glass–ceramic electrolytes with cubic Na3PS4

2014 ◽  
Vol 258 ◽  
pp. 420-423 ◽  
Author(s):  
Akitoshi Hayashi ◽  
Kousuke Noi ◽  
Naoto Tanibata ◽  
Motohiro Nagao ◽  
Masahiro Tatsumisago
Keyword(s):  
Glass Ceramic ◽  
Ion Conductivity ◽  
Sodium Ion ◽  
High Sodium ◽  
Ceramic Electrolytes

scholarly journals Preparation and characterization of sodium-ion conductive Na3BS3 glass and glass–ceramic electrolytes

2021 ◽  
Author(s):  
Fumika Tsuji ◽  
Akira Nasu ◽  
Chie Hotehama ◽  
Atsushi Sakuda ◽  
Masahiro Tatsumisago ◽  
...  
Keyword(s):  
Solid State ◽  
Glass Ceramic ◽  
Sodium Ion ◽  
Solid State Batteries ◽  
Ceramic Electrolytes ◽  
All Solid State Batteries

Glass has the highest conductivity and appropriate properties in the Na3BS3 electrolytes for all-solid-state batteries.

Preparation and characterization of hexagonal Li4GeO4-based glass-ceramic electrolytes

2021 ◽  
Vol 363 ◽  
pp. 115605
Author(s):  
Yohei Yoneda ◽  
Manari Shigeno ◽  
Takuya Kimura ◽  
Kenji Nagao ◽  
Chie Hotehama ◽  
...  
Keyword(s):  
Glass Ceramic ◽  
Ceramic Electrolytes

scholarly journals Na1+xAlxGe2−xP3O12 (x = 0.5) glass–ceramic as a solid ionic conductor for sodium ion

2016 ◽  
Vol 289 ◽  
pp. 113-117 ◽  
Author(s):  
Y.S. Zhu ◽  
L.L. Li ◽  
C.Y. Li ◽  
L. Zhou ◽  
Y.P. Wu
Keyword(s):  
Glass Ceramic ◽  
Ionic Conductor ◽  
Sodium Ion

Structure and properties of Fe2O3-doped 50Li2O-10B2O3-40P2O5 glass and glass-ceramic electrolytes

2020 ◽  
Vol 345 ◽  
pp. 115177 ◽  
Author(s):  
Zhiwei Luo ◽  
Chunchun Qin ◽  
Yanchun Wu ◽  
Wenjing Xu ◽  
Simin Zhang ◽  
...  
Keyword(s):  
Glass Ceramic ◽  
Structure And Properties ◽  
Ceramic Electrolytes

Barium (Zinc) Borosilicate Sealing Glass and Joining Interface with YSZ Electrolyte and Crofer22APU Interconnect in SOFCs

2018 ◽  
Vol 283 ◽  
pp. 72-77
Author(s):  
Namthip Kingnoi ◽  
Jiratchaya Ayawanna ◽  
Nattapol Laorodphan
Keyword(s):  
Borosilicate Glass ◽  
Glass Ceramic ◽  
Joint Interface ◽  
Negative Effect ◽  
Ceramic Electrolytes ◽  
Formation Of Cracks ◽  
Barium Borosilicate Glass ◽  
Metallic Interconnects ◽  
Ysz Electrolyte ◽  
Zinc Borosilicate

This work describes the performance of two glass-ceramic compositions, BaO-SiO2-B2O3 (Barium borosilicate glass: BaBS) and BaO-ZnO-SiO2-B2O3 (Barium zinc borosilicate glass: BaBS−Zn), used for joining YSZ ceramic electrolytes and Crofer22APU metallic interconnects in solid oxide fuel cells (SOFCs) working at 800°C for 50 h. ZnO had a negative effect on the thermal expansion coefficient (TEC) value of the BaBS-Zn glass-ceramic. XRD and SEM results revealed the formation of rod-shaped barium zinc silicate crystalline phases in the BaBS-Zn glass, which was accompanied by cracks and poor adherence at the YSZ/BaBS-Zn joint interface after working at 800°C for 50 h. The formation of cracks parallel to the interface between the Crofer22APU interconnect and the BaBS-Zn glass-ceramic sealant was observed due to the severe TEC mismatch. The BaBS glass–ceramic adhered well to the YSZ electrolyte as well as the pre-oxidized Crofer22APU without cracks. Chromium oxide scale developed between the pre-oxidized Crofer22APU/BaBS glass-ceramic joint interface with increasing the pre-oxidation temperature. This study shows that BaBS glass-ceramic is more effective than BaBS-Zn as a sealant for joining YSZ electrolytes and Crofer22APU metallic interconnects in SOFCs working at 800°C for 50 h.

Li-ion transport in all-solid-state lithium batteries with LiCoO2 using NASICON-type glass ceramic electrolytes

2009 ◽  
Vol 189 (1) ◽  
pp. 365-370 ◽  
Author(s):  
J. Xie ◽  
N. Imanishi ◽  
T. Zhang ◽  
A. Hirano ◽  
Y. Takeda ◽  
...  
Keyword(s):  
Solid State ◽  
Ion Transport ◽  
Glass Ceramic ◽  
Lithium Batteries ◽  
Nasicon Type ◽  
Li Ion ◽  
Ceramic Electrolytes
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