Synthesis, Structure, and Thermolysis of Tris(dimethylphenylsilyl)methyl Sulfenyl Chloride

Koh Sugamata; Shigeru Ishii

doi:10.1246/cl.170188

Synthesis, Structure, and Thermolysis of Tris(dimethylphenylsilyl)methyl Sulfenyl Chloride

Chemistry Letters ◽

10.1246/cl.170188 ◽

2017 ◽

Vol 46 (6) ◽

pp. 837-839

Author(s):

Koh Sugamata ◽

Shigeru Ishii

Keyword(s):

Sulfenyl Chloride

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4-Nitrophenyl sulfenyl chloride as a new precursor for the formation of aromatic SAMs on gold surfaces

Chemical Communications ◽

10.1039/c1cc11451d ◽

2011 ◽

Vol 47 (25) ◽

pp. 7095 ◽

Cited By ~ 16

Author(s):

Abdelaziz Houmam ◽

Hamida Muhammad ◽

M'hamed Chahma ◽

Kallum Koczkur ◽

Daniel F. Thomas

Keyword(s):

Sulfenyl Chloride ◽

Gold Surfaces

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A facile synthesis of sulfonyl chlorides

Canadian Journal of Chemistry ◽

10.1139/v76-067 ◽

1976 ◽

Vol 54 (3) ◽

pp. 498-499 ◽

Cited By ~ 18

Author(s):

Richard F. Langler

Keyword(s):

Acetic Acid ◽

Aqueous Acetic Acid ◽

Sulfenyl Chloride ◽

Molecular Chlorine ◽

Facile Synthesis ◽

Sulfonyl Chlorides

Benzylic sulfides have been shown to furnish sulfonyl chlorides in excellent yields, upon reaction with molecular chlorine in aqueous acetic acid. The reaction most likely proceeds through the intermediacy of the corresponding sulfenyl chloride.

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CClFOS (Fluorocarbonyl)sulfenyl chloride

Molecules containing One or Two Carbon Atoms - Landolt-Börnstein - Group II Molecules and Radicals ◽

10.1007/10653318_35 ◽

2005 ◽

pp. 1-1

Author(s):

G. Graner ◽

E. Hirota ◽

T. Iijima ◽

K. Kuchitsu ◽

D. A. Ramsay ◽

...

Keyword(s):

Sulfenyl Chloride

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ChemInform Abstract: AROMATISCHE SULFENYL-CHLORIDE 2. MITT. RK. DES SULFENYLCHLORIDS MIT THIOCARBAMIDEN UND THIOSEMICARBAZIDEN

Chemischer Informationsdienst Organische Chemie ◽

10.1002/chin.197142294 ◽

1971 ◽

Vol 2 (42) ◽

pp. no-no

Author(s):

P. VINKLER ◽

F. KLIVENYI ◽

E. VINKLER ◽

G. STAJER ◽

A. E. SZABO

Keyword(s):

Sulfenyl Chloride

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Synthetic Routes to, Transformations of, and Rather Surprising Stabilities of (N-Methyl-N-phenylcarbamoyl)sulfenyl Chloride, ((N-Methyl-N-phenylcarbamoyl)dithio)carbonyl Chloride, and Related Compounds

The Journal of Organic Chemistry ◽

10.1021/jo201329n ◽

2011 ◽

Vol 76 (19) ◽

pp. 7882-7892 ◽

Cited By ~ 7

Author(s):

Alex M. Schrader ◽

Alayne L. Schroll ◽

George Barany

Keyword(s):

Sulfenyl Chloride ◽

Carbonyl Chloride ◽

Synthetic Routes ◽

Related Compounds

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CoC bond cleavage in the reactions of alkyl, benzyl and heteroaromaticmethyl cobaloximes with arene sulfenyl chloride: Homolytic and heterolytic pathways

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(98)00689-5 ◽

1999 ◽

Vol 572 (1) ◽

pp. 49-58 ◽

Cited By ~ 9

Author(s):

B.D Gupta ◽

Vandana Dixit ◽

Indira Das

Keyword(s):

Bond Cleavage ◽

Sulfenyl Chloride

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Chemistry of 2-substituted adamantanes. II. Preparation of 2-adamantanethiol and some of its derivatives. Aromatic solvent-induced shifts in their n.m.r. spectra

Canadian Journal of Chemistry ◽

10.1139/v70-602 ◽

1970 ◽

Vol 48 (22) ◽

pp. 3593-3597 ◽

Cited By ~ 9

Author(s):

J. W. Greidanus

Keyword(s):

Sulfenyl Chloride ◽

Aromatic Solvent ◽

Methyl Sulfide ◽

High Yields

Reduction (NaBH4) of adamantanethione gives high yields of pure 2-adamantanethiol, from which several derivatives including the methyl sulfide, sulfoxide, and sulfone were prepared. The sulfenyl chloride was prepared and used insitu. From the n.m.r. spectra the aromatic solvent-induced shifts Δ = τ(benzene) – τ(CCl4 or CDCl3) were determined, where possible.

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