Highly Efficient Palladium-catalyzed Suzuki–Miyaura Cross-coupling with 9,10-Dihydro-9,10-ethanoanthracene-11,12-diimine Ligands under Mild Aerobic Conditions

2016 ◽  
Vol 45 (4) ◽  
pp. 454-456 ◽  
Author(s):  
Ping Huo ◽  
Jingbo Li ◽  
Wanyun Liu ◽  
Xiaohui He ◽  
Guangquan Mei
Keyword(s):  
Cross Coupling ◽  
Aerobic Conditions ◽  
Highly Efficient ◽  
Diimine Ligands ◽  
Palladium Catalyzed

MIDA as a simple and highly efficient ligand for palladium-catalyzed Hiyama cross-coupling of aryl halides

2014 ◽  
Vol 12 (36) ◽  
pp. 7136 ◽  
Author(s):  
Mengping Guo ◽  
Liang Qi ◽  
Qiaochu Zhang ◽  
Zhiyong Zhu ◽  
Wei Li ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Aryl Halides ◽  
Highly Efficient ◽  
Palladium Catalyzed

scholarly journals Synthesis of Tetrasubstituted Allenes via Palladium-Catalyzed Cross-Coupling of Vinyl Bromides with Diazo Compounds

2019 ◽  
Author(s):  
Ge Zhang ◽  
Ze-Jian Xue ◽  
Fang Zhang ◽  
Shu-Sheng Zhang ◽  
Meng-Yao Li ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Cross Coupling ◽  
Diazo Compounds ◽  
Highly Efficient ◽  
Hydrogen Elimination ◽  
Convenient Approach ◽  
Palladium Catalyzed ◽  
Diazo Carbonyl Compounds

A highly efficient palladium-catalyzed cross-coupling of 2,2-diarylvinyl bromides with diazo compounds was developed, providing a convenient approach for the synthesis of tetrasubsti-tuted allenes. Both aryl diazo carbonyl compounds and N-tosylhydrazones are competent carbene precursors in this reaction. An unprecedented hydrogen elimination of the π-allyl palladium intermediate is proposed to be the key step.

Palladium-catalyzed highly efficient synthesis of functionalized indolizines via cross-coupling/cycloisomerization cascade

2015 ◽  
Vol 51 (30) ◽  
pp. 6633-6636 ◽  
Author(s):  
Liangwei Zhang ◽  
Xiangdong Li ◽  
Yuanhong Liu ◽  
Dayong Zhang
Keyword(s):  
Cross Coupling ◽  
Efficient Synthesis ◽  
Highly Efficient ◽  
Organoboronic Acids ◽  
Palladium Catalyzed

Pd-catalyzed cross-coupling/cycloisomerization of 3-(2-pyridyl) propargyl carbonates with organoboronic acids provides a straightforward route for the synthesis of 1,3-disubstituted indolizines.

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