Iron-catalyzed Selective Oxidation of α,β-Unsaturated Aldehydes to α,β-Unsaturated Carboxylic Acids by Molecular Oxygen

2016 ◽  
Vol 45 (2) ◽  
pp. 188-190 ◽  
Author(s):  
Shinji Tanaka ◽  
Yoshihiro Kon ◽  
Yumiko Uesaka ◽  
Ryo Morioka ◽  
Masanori Tamura ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Carboxylic Acids ◽  
Selective Oxidation ◽  
Unsaturated Aldehydes ◽  
Unsaturated Carboxylic Acids

ChemInform Abstract: Iron-Catalyzed Selective Oxidation of α,β-Unsaturated Aldehydes to α,β-Unsaturated Carboxylic Acids by Molecular Oxygen.

ChemInform ◽  
2016 ◽  
Vol 47 (32) ◽  
Author(s):  
Shinji Tanaka ◽  
Yoshihiro Kon ◽  
Yumiko Uesaka ◽  
Ryo Morioka ◽  
Masanori Tamura ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Carboxylic Acids ◽  
Selective Oxidation ◽  
Unsaturated Aldehydes ◽  
Unsaturated Carboxylic Acids

Perturbation theory of substituent effect. Importance of the field effect in transmission of the substituent effect

1980 ◽  
Vol 45 (6) ◽  
pp. 1655-1661 ◽  
Author(s):  
Robert Ponec
Keyword(s):  
Perturbation Theory ◽  
Carboxylic Acids ◽  
Quantum Chemical ◽  
Substituent Effect ◽  
Field Effect ◽  
Adequate Description ◽  
Meta Position ◽  
Unsaturated Carboxylic Acids

Various quantum chemical approaches to the problem of transmission of the substituent effect were compared. It was shown that inclusion of the electronic repulsion (field effect) was necessary to give a true picture of differences in ρ constants for reactions of the cis and trans isomers of substituted unsaturated carboxylic acids; the same holds for an adequate description of transmission of the substituent effect from the meta position on a given skeleton.

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