Syntheses, Crystal Structures, and Reversible Structural Transformation of Two Zinc Coordination Polymers

2014 ◽  
Vol 43 (7) ◽  
pp. 997-998 ◽  
Author(s):  
Lina Zhang ◽  
Jinxi Chen ◽  
Yun Ling ◽  
Zhenxia Chen
Keyword(s):  
Crystal Structures ◽  
Structural Transformation ◽  
Coordination Polymers ◽  
Zinc Coordination ◽  
Reversible Structural Transformation

Structural diversity and modification in Ni(ii) coordination polymers: a peculiar phenomenon of reversible structural transformation between a 1D ladder and 2D layer

CrystEngComm ◽  
2020 ◽  
Vol 22 (44) ◽  
pp. 7565-7574
Author(s):  
Chia-Jou Chen ◽  
Wei-Te Lee ◽  
Ji-Hong Hu ◽  
Pradhumna Mahat Chhetri ◽  
Jhy-Der Chen
Keyword(s):  
Structural Transformation ◽  
Coordination Polymers ◽  
Structural Diversity ◽  
Reversible Structural Transformation ◽  
Peculiar Phenomenon

The coordination of 5-tert-IPA2− ligands, the relaxation of the interdigitated 2D net and the breaking and connecting of the bis-pyridyl-bis-amide ligand demonstrate the peculiar reversible structural transformation between a 1D ladder and 2D layer.

Syntheses, Crystal Structures, and Luminescent Properties of Three Novel Zinc Coordination Polymers with Tetrazolyl Ligands

2005 ◽  
Vol 44 (15) ◽  
pp. 5278-5285 ◽  
Author(s):  
Xi-Sen Wang ◽  
Yun-Zhi Tang ◽  
Xue-Feng Huang ◽  
Zhi-Rong Qu ◽  
Chi-Ming Che ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Coordination Polymers ◽  
Luminescent Properties ◽  
Zinc Coordination

Cobalt(II) coordination polymers constructed from bis(N-pyrid-3-ylmethyl)adipoamide and polycarboxylic acids: reversible structural transformation upon proton delivery and removal

CrystEngComm ◽  
2021 ◽  
Author(s):  
Ji-Hong Hu ◽  
Yuan-Chin Liu ◽  
Jhy-Der Chen
Keyword(s):  
Structural Transformation ◽  
Coordination Polymers ◽  
Tricarboxylic Acid ◽  
Hydrothermal Reactions ◽  
Polycarboxylic Acids ◽  
Reversible Structural Transformation

Hydrothermal reactions of cobalt(II) salts and bis(N-pyrid-3-ylmethyl)adipoamide (L) with various polycarboxylic acids in water and NaOH solutions afforded {[Co(L)0.5(1,3,5-HBTC)(H2O)]·H2O}n (1,3,5-H3BTC = benzene-1,3,5-tricarboxylic acid), 1, {[Co1.5(L)1.5(1,3,5-BTC)(H2O)4]·4H2O}n, 2, [Co(L)(5-tert-IPA)(H2O)2]n (5-tert-H2IPA = 5-tert-butylbenzene-1,3-dicarboxylic...

Synthesis, crystal structures, and photoluminescence of two novel zinc coordination polymers built from 2,2’-(ethyne-1,2-diyl)diterephthalate

2012 ◽  
Vol 17 ◽  
pp. 173-176 ◽  
Author(s):  
Yun-Xia Hu ◽  
Li-Feng Wang ◽  
Wen-Wei Zhang ◽  
Yi-Zhi Li ◽  
Xiao-Ming Ren ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Coordination Polymers ◽  
Zinc Coordination

scholarly journals One-Dimensional Mercury Halide Coordination Polymers Based on A Semi-Rigid N-Donor Ligand: Reversible Structural Transformation

Polymers ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 436 ◽  
Author(s):  
Pradhumna Mahat Chhetri ◽  
Xiang-Kai Yang ◽  
Chih-Tung Yang ◽  
Jhy-Der Chen
Keyword(s):  
Structural Transformation ◽  
Coordination Polymers ◽  
Pyridyl Ring ◽  
Donor Ligand ◽  
One Dimensional ◽  
Ring Rotation ◽  
Mercury Halide ◽  
Ligand Conformation ◽  
Reversible Structural Transformation

Four one-dimensional (1D) mercury(II) halide coordination polymers have been synthesized by using a semi-rigid N-donor ligand, 2,2′-(1,4-phenylene)-bis(N-(pyridin-3-yl)acetamide) (1,4-pbpa). While [Hg(1,4-pbpa)Cl2·CH3OH]n, 1, forms a sinusoidal chain, the complexes [Hg(1,4-pbpa)X2]n (X = Cl, 2; Br, 3; I, 4) are helical. The sinusoidal 1 undergoes reversible structural transformation with helical 2 upon removal and uptake of CH3OH, which was accompanied with the conformation adjustment of the 1,4-pbpa ligand from trans anti-anti to trans syn-anti. Pyridyl ring rotation of the 1,4-pbpa ligand that results in the change of the ligand conformation is proposed for the initiation of the structural transformation.

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