Theoretical Study Demonstrating that Silylene Bridging Brings about LUMO Energy Lowering without Increasing the Reorganization Energy for Single Electron Transfer

2014 ◽  
Vol 43 (6) ◽  
pp. 755-757 ◽  
Author(s):  
Eisuke Ohta ◽  
Takuya Ogaki ◽  
Toru Aoki ◽  
Hiroshi Ikeda
Keyword(s):  
Electron Transfer ◽  
Theoretical Study ◽  
Reorganization Energy ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Lumo Energy ◽  
Energy Lowering

Reversal of Polarity by Catalytic SET Oxidation: Synthesis of Azabicyclo[m.n.o]alkanes via Chemoselective Reduction of Amidines

2021 ◽  
Author(s):  
Sundarababu Baskaran ◽  
Kirana D V ◽  
Kanak Kanti Das
Keyword(s):  
Electron Transfer ◽  
Stereoselective Synthesis ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Catalytic Method ◽  
One Pot ◽  
Oxidative System ◽  
Oxidation Synthesis

A one-pot catalytic method has been developed for the stereoselective synthesis of cyclopropane-fused cyclic amidines using CuBr2/K2S2O8 as an efficient single electron transfer (SET) oxidative system. The generality of this...

Evidence for single electron transfer in the reaction of alkoxides with alkyl halides

1984 ◽  
Vol 25 (45) ◽  
pp. 5107-5110 ◽  
Author(s):  
E.C. Ashby ◽  
Dong-Hak Bae ◽  
Won-Suh Park ◽  
Robert N. Depriest ◽  
Wei-Yang Su
Keyword(s):  
Electron Transfer ◽  
Alkyl Halides ◽  
Single Electron ◽  
Single Electron Transfer
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