Structural and Electronic Properties of Adsorbed Thiophene on Cu(111) Studied by S K-Edge X-Ray Absorption Spectroscopy

1998 ◽  
Vol 71 (4) ◽  
pp. 831-835 ◽  
Author(s):  
Akihito Imanishi ◽  
Toshihiko Yokoyama ◽  
Yoshinori Kitajima ◽  
Toshiaki Ohta
1995 ◽  
Vol 99 (43) ◽  
pp. 16067-16075 ◽  
Author(s):  
Marius Vaarkamp ◽  
Barbara L. Mojet ◽  
Menno J. Kappers ◽  
Jeff T. Miller ◽  
Diek C. Koningsberger

Biochemistry ◽  
1978 ◽  
Vol 17 (10) ◽  
pp. 1842-1846 ◽  
Author(s):  
W. E. Blumberg ◽  
J. Peisach ◽  
P. Eisenberger ◽  
J. A. Fee

2010 ◽  
Vol 82 (15) ◽  
Author(s):  
Andrew D. Ritchie ◽  
Mark A. MacDonald ◽  
Peng Zhang ◽  
Mary Anne White ◽  
Matt Beekman ◽  
...  

2014 ◽  
Vol 116 (9) ◽  
pp. 093703 ◽  
Author(s):  
Rafael Sarmiento-Pérez ◽  
Silvana Botti ◽  
Claudia S. Schnohr ◽  
Iver Lauermann ◽  
Angel Rubio ◽  
...  

1997 ◽  
Vol 497 ◽  
Author(s):  
S. Chaturvedi ◽  
J. A. Rodriguez ◽  
J. C. Hanson ◽  
A. Albornoz ◽  
J. L. Brito

ABSTRACTX-ray absorption near-edge spectroscopy (XANES) was used to characterize the structural and electronic properties of a series of cobalt- and nickel-molybdate catalysts (AMoO4.nH20, α-AMoO4, β-AMoO4; A= Co or Ni). The results of XANES indicate that the Co and Ni atoms are in octahedral sites in all these compounds, while the coordination of Mo varies from octahedral in the a-phases to tetrahedral in the β-phases and hydrate. Time-resolved x-ray diffraction shows a direct transformation of the hydrates into the β-AMoO4 compounds (following a kinetics of first order) at temperatures between 200 and 350 °C. This is facilitated by the similarities that the AMoO4.nH20 and β-AMoO4 compounds have in their structural and electronic properties. The molybdates react with H 2 at temperatures between 400 and 600 °C, forming gaseous water and oxides in which the oxidation state of Co and Ni remains +2 while that of Mo is reduced to +5 or +4. After exposing α-NiMoO4 and P-NiMoO4 to H2S, both metals get sulfided and a NiMoSx phase is formed. For the β phase of NiMoO4 the sulfidation of Mo is more extensive than for the a phase, making the former a better precursor for catalysts of hydrodesulfurization reactions.


2018 ◽  
Vol 6 (47) ◽  
pp. 24534-24549 ◽  
Author(s):  
Daniel F. Abbott ◽  
Emiliana Fabbri ◽  
Mario Borlaf ◽  
Francesco Bozza ◽  
Robin Schäublin ◽  
...  

The structural and electronic properties of rock salt-type Ni–Fe oxides are investigated under OER conditions. The inclusion of Fe in the rock-salt structure is shown to inhibit the transformation to more layered and disordered polymorphs.


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