Successive Chemical Reactions Accompanying a One-Electron Oxidation of a {MNO}6-Type Nitrosyl Complex, Pentachloro(nitrosyl)ruthenate(2−), and a Characterization of the Product Species

1995 ◽  
Vol 68 (10) ◽  
pp. 2897-2904 ◽  
Author(s):  
Dai Ooyama ◽  
Noriharu Nagao ◽  
F. Scott Howell ◽  
Masao Mukaida ◽  
Hirotaka Nagao ◽  
...  
Keyword(s):  
Chemical Reactions ◽  
Nitrosyl Complex ◽  
Product Species

THE CHARACTERIZATION OF COMPLEX SYSTEMS OF CHEMICAL REACTIONS

1989 ◽  
Vol 83 (1) ◽  
pp. 221-240 ◽  
Author(s):  
JOHN HAPPEL ◽  
PETER H. SELLERS
Keyword(s):  
Complex Systems ◽  
Chemical Reactions

Structural Characterization of a Copper Nitrosyl Complex with a {CuNO}10Configuration

2010 ◽  
Vol 132 (41) ◽  
pp. 14336-14337 ◽  
Author(s):  
Ashley M. Wright ◽  
Guang Wu ◽  
Trevor W. Hayton
Keyword(s):  
Structural Characterization ◽  
Nitrosyl Complex

Interface Characterization of Different Apatite Coatings

1998 ◽  
Author(s):  
N. Antolotti ◽  
S. Bertini ◽  
A. Scrivani ◽  
C. Fanara ◽  
F. Rustichelli ◽  
...  
Keyword(s):  
Metal Surface ◽  
Calcium Oxide ◽  
Chemical Reactions ◽  
Metallic Substrate ◽  
Metal Interface ◽  
Interface Characterization ◽  
Hydroxyapatite Coatings ◽  
Plasma Sprayed

Abstract The decomposition of bioactive plasma sprayed apatite layers and the weakness of their interface with the metallic substrate limit the longevity of orthopaedic prostheses. Analysis of the coating and of the metal-apatite different techniques (EDS, XPS, IR) indicates alterations of the apatite composition which can be related to several chemical reactions occurring either in the plasma or on the surface of the implant. EDS shows a calcium-rich layer on the apatite side of the interface whereas after dissolution of the apatite, XPS indicates that phosphorus atoms are incorporated in the metal surface. Depending on the rate of decomposition, calcium oxide may possibly form and weaken the apatite-metal interface. Fluorohydroxyapatite coating, have proven to decompose less and differently and to be more effective than hydroxyapatite coatings.

Synthesis and structural characterization of a mononuclear copper nitrosyl complex

1992 ◽  
Vol 114 (11) ◽  
pp. 4407-4408 ◽  
Author(s):  
Susan M. Carrier ◽  
Christy E. Ruggiero ◽  
William B. Tolman ◽  
Geoffrey B. Jameson
Keyword(s):  
Structural Characterization ◽  
Nitrosyl Complex
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