Phase-Transfer Nucleophilic Reactions Using Water-Insoluble Alcohols as Organic Solvents

1995 ◽  
Vol 68 (8) ◽  
pp. 2417-2423 ◽  
Author(s):  
Noritaka Ohtani ◽  
Yukihiko Inoue ◽  
Noriyuki Shinoki ◽  
Katsuhiro Nakayama
1993 ◽  
Vol 71 (1) ◽  
pp. 90-95 ◽  
Author(s):  
André Loupy ◽  
Alain Petit ◽  
Mohamed Ramdani ◽  
Celine Yvanaeff ◽  
Mustapha Majdoub ◽  
...  

Practical and simple techniques are described for using nonmodified domestic microwave ovens as safe and convenient laboratory devices to obtain numerous esters. High pressures are avoided by conducting reactions with reactants impregnated on solid mineral supports in "dry media" or by phase transfer catalysis (PTC) in the absence of organic solvents. Two kinds of microwave effects are involved: (1) displacement of the equilibrium by evaporation of volatile polar molecules (water or alcohols) in esterifications and transesterifications; (2) acceleration of ionic reactions in carboxylate alkylations. As solvents are avoided, there is no need for sealed vessels and water separators.


Langmuir ◽  
2007 ◽  
Vol 23 (3) ◽  
pp. 1414-1418 ◽  
Author(s):  
Jeffrey M. McMahon ◽  
Steven R. Emory

2014 ◽  
Vol 50 (68) ◽  
pp. 9700-9703 ◽  
Author(s):  
Shan Wang ◽  
Haolong Li ◽  
Liying Zhang ◽  
Bao Li ◽  
Xiao Cao ◽  
...  

Surfactant-encapsulated polyoxometalates (SEP) can act as cluster suprasurfactants to transfer reduced graphene oxide (RGO) from water to low polar organic solvents with single-layer RGO dispersion.


Tetrahedron ◽  
2008 ◽  
Vol 64 (51) ◽  
pp. 11625-11631 ◽  
Author(s):  
Paola Barraja ◽  
Patrizia Diana ◽  
Anna Carbone ◽  
Girolamo Cirrincione

Nano Letters ◽  
2002 ◽  
Vol 2 (8) ◽  
pp. 803-806 ◽  
Author(s):  
Nikolai Gaponik ◽  
Dmitri V. Talapin ◽  
Andrey L. Rogach ◽  
Alexander Eychmüller ◽  
Horst Weller

2013 ◽  
Vol 02 (02) ◽  
pp. 35-38 ◽  
Author(s):  
Koottil Muhammad Basheer ◽  
Joy Joseph ◽  
Thengumthanam D. R. Nair

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