19F and 1H NMR Study of Intermolecular Hydrogen Bond between Phenols and a Fluoroalkane in Solution.

1993 ◽  
Vol 66 (1) ◽  
pp. 315-316 ◽  
Author(s):  
Motonari Shibakami ◽  
Akira Sekiya
Keyword(s):  
Hydrogen Bond ◽  
1H Nmr ◽  
Intermolecular Hydrogen Bond ◽  
Nmr Study

Synthesis and Crystal Structures of 3,6-diacetylated C24 epimeric 20(R)-Ocotillol-Type Saponins

2019 ◽  
Vol 41 (3) ◽  
pp. 452-452
Author(s):  
Juan Liu Juan Liu ◽  
Wen Zhi Wang Wen Zhi Wang ◽  
Jia Zhen Wang Jia Zhen Wang ◽  
Gui Ge Hou Gui Ge Hou ◽  
Qing Guo Meng Qing Guo Meng
Keyword(s):  
Hydrogen Bond ◽  
Single Crystal ◽  
Intramolecular Hydrogen Bond ◽  
1H Nmr ◽  
13C Nmr ◽  
Intermolecular Hydrogen Bond ◽  
Single Crystal Diffraction ◽  
X Ray ◽  
Intramolecular Hydrogen ◽  
Optically Pure

(20R,24R)-epoxy-dammar-3β,6α,12β,25-tetraol (1) and (20R,24S)-epoxy- dammar-3β, 6α,12β,25-tetraol (2) have been synthesized from 20(R)-protopanaxatriol with same polarity. In order to obtain optically pure 1 and 2, (20R,24R)-3,6-diacetyl- 20,24-epoxydammar-3β,6α,12β,25-tetraol (3) and (20R,24S)-3,6-diacetyl-20,24- epoxydammar-3β,6α,12β,25-tetraol (4) were designed and prepared to enhance the polarity difference of C24 epimers. Two suitable crystals of 3 and 4 were obtained and their structures were determined by 1H NMR, 13C NMR, HR-MS and X-ray single-crystal diffraction. The results indicated that the C-24 configuration of 3 and 4 are R-form and S-form, respectively. 3 has two intramolecular hydrogen bond. While there is only one in 4 and the crystal stacking displays that it generates a right-handed helically chiral channel viewing from the crystallographic b axis via classical O–H•••O intermolecular hydrogen bond.

1H-NMR study of Mott insulator κ -(ET)2Cu2(CN)3with isotropic triangular lattice

2004 ◽  
Vol 114 ◽  
pp. 377-378 ◽  
Author(s):  
Y. Shimizu ◽  
K. Miyagawa ◽  
K. Oda ◽  
K. Kanoda ◽  
M. Maesato ◽  
...  
Keyword(s):  
1H Nmr ◽  
Triangular Lattice ◽  
Mott Insulator ◽  
Nmr Study

A 15N, 13C, and 1H NMR study of reaction products from arylguanidines and chloroformate esters

1991 ◽  
Vol 56 (7) ◽  
pp. 1505-1511 ◽  
Author(s):  
Antonín Lyčka ◽  
Karel Palát
Keyword(s):  
1H Nmr ◽  
Nmr Spectra ◽  
Reaction Products ◽  
H Nmr ◽  
Nmr Study

The 15N, 13C, and 1H NMR spectra of the reaction products from arylguanidines with two mols of chloroformate esters have been measured. With application of the corresponding 15N isotopomer it has been proved that the reaction products have the structures IIIa-IIIc.

Synthesis and characterization of photothermal antibacterial hydrogel with enhanced mechanical properties

2021 ◽  
Author(s):  
Shu bin Li ◽  
Xiao Wang ◽  
Jiang Zhu ◽  
Zhenyu Wang ◽  
Lu Wang
Keyword(s):  
Mechanical Properties ◽  
Hydrogen Bond ◽  
Fe3o4 Nanoparticles ◽  
Intermolecular Hydrogen Bond ◽  
Amide Bond ◽  
Synthesis And Characterization

In this work, using carboxyl-modified Fe3O4 nanoparticles as a photothermal agent, combining the chemical amide bond and intermolecular hydrogen bond crosslinking force, a photothermal hydrogel with enhanced mechanical properties was...

scholarly journals 1H NMR study of [d(GCGATCGC)]2 and its interaction with minor groove binding 4',6-diamidino-2-phenylindole.

1993 ◽  
Vol 268 (6) ◽  
pp. 3944-3951
Author(s):  
E. Trotta ◽  
E. D'Ambrosio ◽  
N. Del Grosso ◽  
G. Ravagnan ◽  
M. Cirilli ◽  
...  
Keyword(s):  
1H Nmr ◽  
Minor Groove ◽  
Minor Groove Binding ◽  
Groove Binding ◽  
Nmr Study
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