NMR Relaxation Studies for Sodium and Potassium Ions and Water Molecules in Concentrated Aqueous Solutions of Dibutyl Phosphate

1992 ◽  
Vol 65 (3) ◽  
pp. 707-714 ◽  
Author(s):  
Masayasu Iida ◽  
Yukari Hata
Keyword(s):  
Aqueous Solutions ◽  
Nmr Relaxation ◽  
Water Molecules ◽  
Potassium Ions ◽  
Concentrated Aqueous Solutions ◽  
Relaxation Studies ◽  
Sodium And Potassium

NMR Relaxation Studies in Aqueous Solutions of Amino Acids

1994 ◽  
Vol 27 (4) ◽  
pp. 219-224
Author(s):  
V. Arulmozhi ◽  
A. Srinivasa Rao
Keyword(s):  
Amino Acids ◽  
Aqueous Solutions ◽  
Nmr Relaxation ◽  
Relaxation Studies

Addukte von Alkalimetallhexacyanoferraten mit Hexamethylentetramin: Die Kristallstrukturen von Na3[Fe(CN)6] · 2C6H12N4 · 5H20 und K3[Fe(CN)6] · 2C6H12N4 · 4H2O

1988 ◽  
Vol 43 (9) ◽  
pp. 1161-1166 ◽  
Author(s):  
Hans-Jürgen Meyer ◽  
Joachim Pickardt
Keyword(s):  
Hydrogen Bonds ◽  
Aqueous Solutions ◽  
Single Crystals ◽  
Three Dimensions ◽  
Water Molecules ◽  
Orthorhombic Space Group ◽  
Triclinic Space Group ◽  
Space Group ◽  
Sodium And Potassium ◽  
Coordination Water

Abstract By diffusion of methanolic solutions of hexamethylenetetramine into aqueous solutions of hexacyanoferrates(III) of sodium and potassium, resp., single crystals of the adducts were ob­tained. Na3[Fe(CN)6] · 2C6H12N4-5H2O, orthorhombic, space group Pca21. Z = 4, a = 14.122(4). b = 14.380(4), c = 14.381(4) Å, 3153 reflections, R = 0.044. K3[Fe(CN)6]•2C6H12N4-4H2O, triclinic, space group P1̄, Z = 4, a = 14.125(4), b = 17.808(4), c =14.116(4) Å, α = 114.14(5), β = 94.91(4), γ = 108.36(5)°. 5550 reflections, R = 0.042. Both structures may be regarded as Elpasolite-Iike arrangements of [Fe(CN)6]3- ions, C6H12N4 molecules and [M2(OH2)x]3+ units (M = Na, K; x = 5, 4), linked together unsymmetrically by M-N contacts of metal ions and nitrogen atoms with mean distances of Na-NHMT = 264 pm. Na-NCYan = 243 pm, K-NHMT = 293 pm and K-Ncyan = 290 pm. Stabilization of the crystal structures is obtained by N---H-O hydrogen bonds of coordination water molecules in three dimensions.

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