Competitive Intramolecular Electron Transfer and SN2 Reactions of Radical Anions. Effects of Solvent Polarity on the Reaction Mechanism

1992 ◽  
Vol 65 (6) ◽  
pp. 1668-1671 ◽  
Author(s):  
Norio Kimura ◽  
Setsuo Takamuku
Keyword(s):  
Electron Transfer ◽  
Reaction Mechanism ◽  
Solvent Polarity ◽  
Intramolecular Electron Transfer ◽  
Radical Anions ◽  
Sn2 Reactions

Intramolecular electron transfer and SN2 reactions in the radical anions of 1-(4-biphenylyl)-.omega.-haloalkane studied by pulse radiolysis

1981 ◽  
Vol 103 (17) ◽  
pp. 5176-5179 ◽  
Author(s):  
Hitoshi Kigawa ◽  
Setsuo Takamuku ◽  
Susumu Toki ◽  
Norio Kimura ◽  
Seishi Takeda ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Pulse Radiolysis ◽  
Intramolecular Electron Transfer ◽  
Radical Anions ◽  
Sn2 Reactions

Solvent polarity effects on intramolecular electron transfer: An estimate of activation entropies

1990 ◽  
Vol 168 (6) ◽  
pp. 598-604 ◽  
Author(s):  
H. Heitele ◽  
F. Pöllinger ◽  
S. Weeren ◽  
M.E. Michel-Beyerle
Keyword(s):  
Electron Transfer ◽  
Solvent Polarity ◽  
Intramolecular Electron Transfer ◽  
Polarity Effects

scholarly journals Low field photo-CIDNP in the intramolecular electron transfer of naproxen–pyrrolidine dyads

2016 ◽  
Vol 18 (2) ◽  
pp. 901-907 ◽  
Author(s):  
I. M. Magin ◽  
N. E. Polyakov ◽  
A. I. Kruppa ◽  
P. A. Purtov ◽  
T. V. Leshina ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Solvent Polarity ◽  
Intramolecular Electron Transfer ◽  
Low Field

Low field dyad 1H CIDNP in low and high solvent polarity.

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